Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo

IntroductionHydroxychloroquine (HCQ) has been demonstrated to be potential to enhance the therapeutic efficacy of methotrexate (MTX) for rheumatoid arthritis (RA) patients. However, the pharmacokinetics (PK) alterations and underlying mechanisms differentiating MTX-HCQ combination therapy from MTX m...

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Main Authors: Guijie Zhang, Rui Wang, Geping Chen, Simin Liu, Hongyu Jie, Wenying Chen, Qiang Li
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-04-01
Series:Frontiers in Pharmacology
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Online Access:https://www.frontiersin.org/articles/10.3389/fphar.2025.1561001/full
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author Guijie Zhang
Rui Wang
Geping Chen
Simin Liu
Hongyu Jie
Wenying Chen
Qiang Li
author_facet Guijie Zhang
Rui Wang
Geping Chen
Simin Liu
Hongyu Jie
Wenying Chen
Qiang Li
author_sort Guijie Zhang
collection DOAJ
description IntroductionHydroxychloroquine (HCQ) has been demonstrated to be potential to enhance the therapeutic efficacy of methotrexate (MTX) for rheumatoid arthritis (RA) patients. However, the pharmacokinetics (PK) alterations and underlying mechanisms differentiating MTX-HCQ combination therapy from MTX monotherapy remain uncharted.MethodsThirty-three Sprague-Dawley rats were divided into single-dose and multiple-dose groups, with each group further randomized into an MTX monotherapy group an Hydroxychloroquine monotherapy group (HTG), and an MTX-HCQ combination therapy group Blood samples were collected at various time points before and after dosing to determine drug concentrations in plasma and red blood cells (RBC). The area under the concentration-time curve (AUC) for each compound was calculated, and pharmacokinetics models were established to analyze parameter variations across groups.ResultsIn the single-dose group, the CTG exhibited a significant increase in the RBC MTX Cmax compared to the MTG (P = 0.023), whereas the AUC of RBC MTX showed an increasing trend (P = 0.056). In the multiple-dose group, the CTG demonstrated significant increases in plasma MTX Cmax and AUC (P = 0.023, P = 0.028, respectively) as well as RBC MTX Cmax and AUC (P = 0.010, P = 0.003, respectively). The RBC MTX polyglutamates (MTXPG2 and MTXPG3) also showed an increasing trend in Cmax and AUC for the CTG. Additionally, the CTG displayed a significant reduction in clearance rate (CLe) (P = 0.001). No significant differences were observed in the Cmax or AUC of HCQ or desethylhydroxychloroquine (DHCQ) in plasma or RBC across dosing groups.ConclusionThese findings provide insights into the enhanced efficacy, faster onset, and prolonged effect of MTX-HCQ combination therapy compared to MTX monotherapy. The observed increases in MTX Cmax and AUC suggest the need for careful monitoring of MTX-related adverse effects, particularly in patients with renal insufficiency, during combination treatment with HCQ.
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spelling doaj-art-64d1cbda0976471186c592f3a7abbd5e2025-08-20T02:24:49ZengFrontiers Media S.A.Frontiers in Pharmacology1663-98122025-04-011610.3389/fphar.2025.15610011561001Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivoGuijie Zhang0Rui Wang1Geping Chen2Simin Liu3Hongyu Jie4Wenying Chen5Qiang Li6Department of Pharmacy, The Third Affiliated Hospital of Southern Medical University, Guangzhou, Guangdong, ChinaDepartment of Pharmacy, The Third Affiliated Hospital of Southern Medical University, Guangzhou, Guangdong, ChinaDepartment of Pharmacy, The Third Affiliated Hospital of Southern Medical University, Guangzhou, Guangdong, ChinaSchool of Pharmaceutical Sciences, Southern Medical University, Guangzhou, Guangdong, ChinaDepartment of Rheumatology and Immunology, The Third Affiliated Hospital of Southern Medical University, Guangzhou, Guangdong, ChinaDepartment of Pharmacy, The Third Affiliated Hospital of Southern Medical University, Guangzhou, Guangdong, ChinaDepartment of Pharmacy, The Third Affiliated Hospital of Southern Medical University, Guangzhou, Guangdong, ChinaIntroductionHydroxychloroquine (HCQ) has been demonstrated to be potential to enhance the therapeutic efficacy of methotrexate (MTX) for rheumatoid arthritis (RA) patients. However, the pharmacokinetics (PK) alterations and underlying mechanisms differentiating MTX-HCQ combination therapy from MTX monotherapy remain uncharted.MethodsThirty-three Sprague-Dawley rats were divided into single-dose and multiple-dose groups, with each group further randomized into an MTX monotherapy group an Hydroxychloroquine monotherapy group (HTG), and an MTX-HCQ combination therapy group Blood samples were collected at various time points before and after dosing to determine drug concentrations in plasma and red blood cells (RBC). The area under the concentration-time curve (AUC) for each compound was calculated, and pharmacokinetics models were established to analyze parameter variations across groups.ResultsIn the single-dose group, the CTG exhibited a significant increase in the RBC MTX Cmax compared to the MTG (P = 0.023), whereas the AUC of RBC MTX showed an increasing trend (P = 0.056). In the multiple-dose group, the CTG demonstrated significant increases in plasma MTX Cmax and AUC (P = 0.023, P = 0.028, respectively) as well as RBC MTX Cmax and AUC (P = 0.010, P = 0.003, respectively). The RBC MTX polyglutamates (MTXPG2 and MTXPG3) also showed an increasing trend in Cmax and AUC for the CTG. Additionally, the CTG displayed a significant reduction in clearance rate (CLe) (P = 0.001). No significant differences were observed in the Cmax or AUC of HCQ or desethylhydroxychloroquine (DHCQ) in plasma or RBC across dosing groups.ConclusionThese findings provide insights into the enhanced efficacy, faster onset, and prolonged effect of MTX-HCQ combination therapy compared to MTX monotherapy. The observed increases in MTX Cmax and AUC suggest the need for careful monitoring of MTX-related adverse effects, particularly in patients with renal insufficiency, during combination treatment with HCQ.https://www.frontiersin.org/articles/10.3389/fphar.2025.1561001/fullmethotrexatemethotrexate polyglutamateshydroxychloroquinerheumatoid arthritispharmacokinetics
spellingShingle Guijie Zhang
Rui Wang
Geping Chen
Simin Liu
Hongyu Jie
Wenying Chen
Qiang Li
Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo
Frontiers in Pharmacology
methotrexate
methotrexate polyglutamates
hydroxychloroquine
rheumatoid arthritis
pharmacokinetics
title Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo
title_full Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo
title_fullStr Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo
title_full_unstemmed Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo
title_short Hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells: a pharmacokinetic interaction study in rats in vivo
title_sort hydroxychloroquine increases the exposure of methotrexate in plasma and red blood cells a pharmacokinetic interaction study in rats in vivo
topic methotrexate
methotrexate polyglutamates
hydroxychloroquine
rheumatoid arthritis
pharmacokinetics
url https://www.frontiersin.org/articles/10.3389/fphar.2025.1561001/full
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