Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks

In this study, CNTs networks were formed on the foam and quartz sand based on the self-assembly of deoxyribonucleic acid (DNA), which propose two organic-inorganic hybrid materials (CNTs-sand and CNTs-foam) for reinforcing foam concrete. DNA can not only disperse CNTs by π-π stacking but also form i...

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Main Authors: Tianye Luo, Xingu Zhong, Yi Zhou, Xinke Zhang, Qianxi Li, Chao Zhao, Xiong Peng, Hongxin Sun
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Case Studies in Construction Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2214509525005467
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author Tianye Luo
Xingu Zhong
Yi Zhou
Xinke Zhang
Qianxi Li
Chao Zhao
Xiong Peng
Hongxin Sun
author_facet Tianye Luo
Xingu Zhong
Yi Zhou
Xinke Zhang
Qianxi Li
Chao Zhao
Xiong Peng
Hongxin Sun
author_sort Tianye Luo
collection DOAJ
description In this study, CNTs networks were formed on the foam and quartz sand based on the self-assembly of deoxyribonucleic acid (DNA), which propose two organic-inorganic hybrid materials (CNTs-sand and CNTs-foam) for reinforcing foam concrete. DNA can not only disperse CNTs by π-π stacking but also form ionic-hydrogen bond with KOH modified quartz sand. On the other hand, a three-phase foam stabilized by DNA/CNTs was prepared. The test results of mechanical properties indicated that the compressive, splitting tensile and bending strength are impressively increased by 2 times, 3 times and 2 times compared to control group. CNTs-foam and CNTs-sand did not promote the hydration reaction, according to XRD and TG test results. The enhancement of mechanical properties is predominantly driven by the optimization of pore structure and interfacial transition zone (ITZ), as evidenced by SEM, X-CT and nanoindentation. This paper provides an innovative strategy for CNTs dispersion in foam concrete and contributes to designing high-performance foam concrete.
format Article
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institution DOAJ
issn 2214-5095
language English
publishDate 2025-07-01
publisher Elsevier
record_format Article
series Case Studies in Construction Materials
spelling doaj-art-64ba269a887940d8b7a0352a475dfcff2025-08-20T03:09:12ZengElsevierCase Studies in Construction Materials2214-50952025-07-0122e0474810.1016/j.cscm.2025.e04748Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networksTianye Luo0Xingu Zhong1Yi Zhou2Xinke Zhang3Qianxi Li4Chao Zhao5Xiong Peng6Hongxin Sun7Department of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR ChinaDepartment of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR China; Corresponding authors.Department of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR China; Corresponding authors.Department of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR ChinaDepartment of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR ChinaDepartment of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR ChinaDepartment of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, PR ChinaHunan Provincial Key Laboratory of Structures for Wind Resistance and Vibration Control & School of Civil Engineering, PR ChinaIn this study, CNTs networks were formed on the foam and quartz sand based on the self-assembly of deoxyribonucleic acid (DNA), which propose two organic-inorganic hybrid materials (CNTs-sand and CNTs-foam) for reinforcing foam concrete. DNA can not only disperse CNTs by π-π stacking but also form ionic-hydrogen bond with KOH modified quartz sand. On the other hand, a three-phase foam stabilized by DNA/CNTs was prepared. The test results of mechanical properties indicated that the compressive, splitting tensile and bending strength are impressively increased by 2 times, 3 times and 2 times compared to control group. CNTs-foam and CNTs-sand did not promote the hydration reaction, according to XRD and TG test results. The enhancement of mechanical properties is predominantly driven by the optimization of pore structure and interfacial transition zone (ITZ), as evidenced by SEM, X-CT and nanoindentation. This paper provides an innovative strategy for CNTs dispersion in foam concrete and contributes to designing high-performance foam concrete.http://www.sciencedirect.com/science/article/pii/S2214509525005467Foam concreteDeoxyribonucleic acid (DNA)/carbon nanotubes (CNTs)CNTs-sandCNTs-foamInterfacial transition zone (ITZ)
spellingShingle Tianye Luo
Xingu Zhong
Yi Zhou
Xinke Zhang
Qianxi Li
Chao Zhao
Xiong Peng
Hongxin Sun
Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks
Case Studies in Construction Materials
Foam concrete
Deoxyribonucleic acid (DNA)/carbon nanotubes (CNTs)
CNTs-sand
CNTs-foam
Interfacial transition zone (ITZ)
title Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks
title_full Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks
title_fullStr Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks
title_full_unstemmed Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks
title_short Reinforcing pore structure and ITZ of foam concrete enabled by DNA self-assembled CNTs networks
title_sort reinforcing pore structure and itz of foam concrete enabled by dna self assembled cnts networks
topic Foam concrete
Deoxyribonucleic acid (DNA)/carbon nanotubes (CNTs)
CNTs-sand
CNTs-foam
Interfacial transition zone (ITZ)
url http://www.sciencedirect.com/science/article/pii/S2214509525005467
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