Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures
In the present work, the electrical conductivity of chloramphenicol was measured in water and methanol at different temperature degrees 293-313 K. The parameters of conductivity equivalent conductance at infinite dilution ( Λ0), the association constant (KA) and distance parameter (R) were all rec...
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University of Baghdad, College of Science for Women
2024-07-01
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| Series: | مجلة بغداد للعلوم |
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| Online Access: | https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8239 |
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| author | Amel G. Abed |
| author_facet | Amel G. Abed |
| author_sort | Amel G. Abed |
| collection | DOAJ |
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In the present work, the electrical conductivity of chloramphenicol was measured in water and methanol at different temperature degrees 293-313 K. The parameters of conductivity equivalent conductance at infinite dilution ( Λ0), the association constant (KA) and distance parameter (R) were all recorded by using Lee-Wheaton equation and the thermodynamic parameters (ΔH, ΔG, and ΔS) were calculated as well. The behavior of a compound can be predicted through computational calculations; taking 2,2-dichloro-N-[(1R,2S)-1,3-dihydroxy-1-(4-nitrophenyl) propan-2-yl] acetamide, for example. There is an abundance of theoretical information available about how this compound behaves in different solvents, such as water and methanol. The secret lies in analyzing the compound's HOMO and LUMO energies, which can be determined through advanced computational calculations using methods like AM1, PM3, and HF. The potential of the compound was different when changing the solvent and this is due to the value of energy and other theoretical factors like the molecular volume and Connolly parameters.
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| format | Article |
| id | doaj-art-64959978682b45e8a6deaa49e1ab392e |
| institution | Kabale University |
| issn | 2078-8665 2411-7986 |
| language | English |
| publishDate | 2024-07-01 |
| publisher | University of Baghdad, College of Science for Women |
| record_format | Article |
| series | مجلة بغداد للعلوم |
| spelling | doaj-art-64959978682b45e8a6deaa49e1ab392e2025-08-20T03:56:18ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862024-07-0121710.21123/bsj.2023.8239Conductometric and Computational Study of Chloramphenicol at Different Solvents and TemperaturesAmel G. Abed 0Department of Chemistry, College of Science, University of Mosul, Mosul, Iraq. In the present work, the electrical conductivity of chloramphenicol was measured in water and methanol at different temperature degrees 293-313 K. The parameters of conductivity equivalent conductance at infinite dilution ( Λ0), the association constant (KA) and distance parameter (R) were all recorded by using Lee-Wheaton equation and the thermodynamic parameters (ΔH, ΔG, and ΔS) were calculated as well. The behavior of a compound can be predicted through computational calculations; taking 2,2-dichloro-N-[(1R,2S)-1,3-dihydroxy-1-(4-nitrophenyl) propan-2-yl] acetamide, for example. There is an abundance of theoretical information available about how this compound behaves in different solvents, such as water and methanol. The secret lies in analyzing the compound's HOMO and LUMO energies, which can be determined through advanced computational calculations using methods like AM1, PM3, and HF. The potential of the compound was different when changing the solvent and this is due to the value of energy and other theoretical factors like the molecular volume and Connolly parameters. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8239Austin Model, Chloramphenicol, Electrical Conductivity, Hartree-Fock, Parametric Method |
| spellingShingle | Amel G. Abed Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures مجلة بغداد للعلوم Austin Model, Chloramphenicol, Electrical Conductivity, Hartree-Fock, Parametric Method |
| title | Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures |
| title_full | Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures |
| title_fullStr | Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures |
| title_full_unstemmed | Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures |
| title_short | Conductometric and Computational Study of Chloramphenicol at Different Solvents and Temperatures |
| title_sort | conductometric and computational study of chloramphenicol at different solvents and temperatures |
| topic | Austin Model, Chloramphenicol, Electrical Conductivity, Hartree-Fock, Parametric Method |
| url | https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8239 |
| work_keys_str_mv | AT amelgabed conductometricandcomputationalstudyofchloramphenicolatdifferentsolventsandtemperatures |