Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry

Nucleotide sugars, the activated forms of monosaccharides, are important intermediates of carbohydrate metabolism in all organisms. Here, we describe a method for the detection and quantification of UDP-glucose and UDP-galactose in maize in order to compare their metabolism in both wild-type and mut...

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Main Authors: Chen Lan, Bing Zhao, Lu Yang, Yusen Zhou, Siyi Guo, Xuebin Zhang, Junli Zhang
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Journal of Analytical Methods in Chemistry
Online Access:http://dx.doi.org/10.1155/2022/7015311
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author Chen Lan
Bing Zhao
Lu Yang
Yusen Zhou
Siyi Guo
Xuebin Zhang
Junli Zhang
author_facet Chen Lan
Bing Zhao
Lu Yang
Yusen Zhou
Siyi Guo
Xuebin Zhang
Junli Zhang
author_sort Chen Lan
collection DOAJ
description Nucleotide sugars, the activated forms of monosaccharides, are important intermediates of carbohydrate metabolism in all organisms. Here, we describe a method for the detection and quantification of UDP-glucose and UDP-galactose in maize in order to compare their metabolism in both wild-type and mutated plants. Triple quadrupole operating in a multiple reaction monitoring mode was used to quantify nucleotide sugars. The limits of detection for UDP-glucose and UDP-galactose were 0.50 and 0.70 ng·mL−1, respectively. The recoveries of the method ranged from 98.3% to 103.6% with the relative standard deviations less than 6.3%. To prove the applicability of this method, we analyzed several sets of maize extracts obtained from different cultivars grown under standardized greenhouse conditions. All the results demonstrated the suitability of the developed method to quantify UDP-glucose and UDP-galactose in maize extracts.
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id doaj-art-63fa1f8c4a0845189e3f8b4ba2fd9278
institution Kabale University
issn 2090-8873
language English
publishDate 2022-01-01
publisher Wiley
record_format Article
series Journal of Analytical Methods in Chemistry
spelling doaj-art-63fa1f8c4a0845189e3f8b4ba2fd92782025-08-20T03:34:25ZengWileyJournal of Analytical Methods in Chemistry2090-88732022-01-01202210.1155/2022/7015311Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass SpectrometryChen Lan0Bing Zhao1Lu Yang2Yusen Zhou3Siyi Guo4Xuebin Zhang5Junli Zhang6State Key Laboratory of Crop Stress Adaptation and ImprovementState Key Laboratory of Crop Stress Adaptation and ImprovementState Key Laboratory of Crop Stress Adaptation and ImprovementState Key Laboratory of Crop Stress Adaptation and ImprovementState Key Laboratory of Crop Stress Adaptation and ImprovementState Key Laboratory of Crop Stress Adaptation and ImprovementState Key Laboratory of Crop Stress Adaptation and ImprovementNucleotide sugars, the activated forms of monosaccharides, are important intermediates of carbohydrate metabolism in all organisms. Here, we describe a method for the detection and quantification of UDP-glucose and UDP-galactose in maize in order to compare their metabolism in both wild-type and mutated plants. Triple quadrupole operating in a multiple reaction monitoring mode was used to quantify nucleotide sugars. The limits of detection for UDP-glucose and UDP-galactose were 0.50 and 0.70 ng·mL−1, respectively. The recoveries of the method ranged from 98.3% to 103.6% with the relative standard deviations less than 6.3%. To prove the applicability of this method, we analyzed several sets of maize extracts obtained from different cultivars grown under standardized greenhouse conditions. All the results demonstrated the suitability of the developed method to quantify UDP-glucose and UDP-galactose in maize extracts.http://dx.doi.org/10.1155/2022/7015311
spellingShingle Chen Lan
Bing Zhao
Lu Yang
Yusen Zhou
Siyi Guo
Xuebin Zhang
Junli Zhang
Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
Journal of Analytical Methods in Chemistry
title Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
title_full Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
title_fullStr Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
title_full_unstemmed Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
title_short Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
title_sort determination of udp glucose and udp galactose in maize by hydrophilic interaction liquid chromatography and tandem mass spectrometry
url http://dx.doi.org/10.1155/2022/7015311
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