Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions

A covalent complex of okra seed protein (OSP) and rutin was prepared using the alkali-induced method and characterized. Its application in nanoemulsions was also evaluated. Multi-spectral analysis confirmed the formation of the covalent complex, with OSP as the main body. With an increasing rutin do...

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Main Authors: Chengyun He, Lu Bai, Yingxuan Zhou, Benguo Liu, Sheng Geng
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/10/1672
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author Chengyun He
Lu Bai
Yingxuan Zhou
Benguo Liu
Sheng Geng
author_facet Chengyun He
Lu Bai
Yingxuan Zhou
Benguo Liu
Sheng Geng
author_sort Chengyun He
collection DOAJ
description A covalent complex of okra seed protein (OSP) and rutin was prepared using the alkali-induced method and characterized. Its application in nanoemulsions was also evaluated. Multi-spectral analysis confirmed the formation of the covalent complex, with OSP as the main body. With an increasing rutin dosage during the preparation process, the amount of rutin in the complex progressively ascended, and the α-helix structure and surface hydrophobicity of the complex gradually declined. The complex exhibited remarkable ABTS radical scavenging capacity and reducing power, which were proportional to the total phenolic content. The OSP/rutin complex could be utilized for the fabrication of O/W nanoemulsions, which remained stable in terms of droplet size and appearance after 28 days of storage at both 4 °C and 25 °C. Furthermore, lipid oxidation in the nanoemulsion stabilized by the OSP/rutin covalent complex could be effectively inhibited, and the emulsion could enhance the UV irradiation resistance of lutein loaded in the oil phase. Our results can provide a reference for the development of protein–polyphenol covalent complexes.
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issn 2304-8158
language English
publishDate 2025-05-01
publisher MDPI AG
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series Foods
spelling doaj-art-63e7b83be14f47ac9169c4b05fc99e532025-08-20T03:14:35ZengMDPI AGFoods2304-81582025-05-011410167210.3390/foods14101672Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in NanoemulsionsChengyun He0Lu Bai1Yingxuan Zhou2Benguo Liu3Sheng Geng4School of Food Science, Henan Institute of Science and Technology, Xinxiang 453003, ChinaSchool of Food Science, Henan Institute of Science and Technology, Xinxiang 453003, ChinaSchool of Food Science, Henan Institute of Science and Technology, Xinxiang 453003, ChinaSchool of Food Science, Henan Institute of Science and Technology, Xinxiang 453003, ChinaSchool of Food Science, Henan Institute of Science and Technology, Xinxiang 453003, ChinaA covalent complex of okra seed protein (OSP) and rutin was prepared using the alkali-induced method and characterized. Its application in nanoemulsions was also evaluated. Multi-spectral analysis confirmed the formation of the covalent complex, with OSP as the main body. With an increasing rutin dosage during the preparation process, the amount of rutin in the complex progressively ascended, and the α-helix structure and surface hydrophobicity of the complex gradually declined. The complex exhibited remarkable ABTS radical scavenging capacity and reducing power, which were proportional to the total phenolic content. The OSP/rutin complex could be utilized for the fabrication of O/W nanoemulsions, which remained stable in terms of droplet size and appearance after 28 days of storage at both 4 °C and 25 °C. Furthermore, lipid oxidation in the nanoemulsion stabilized by the OSP/rutin covalent complex could be effectively inhibited, and the emulsion could enhance the UV irradiation resistance of lutein loaded in the oil phase. Our results can provide a reference for the development of protein–polyphenol covalent complexes.https://www.mdpi.com/2304-8158/14/10/1672okra seed proteinrutincovalent complexnanoemulsion
spellingShingle Chengyun He
Lu Bai
Yingxuan Zhou
Benguo Liu
Sheng Geng
Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions
Foods
okra seed protein
rutin
covalent complex
nanoemulsion
title Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions
title_full Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions
title_fullStr Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions
title_full_unstemmed Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions
title_short Characterization of Okra Seed Protein/Rutin Covalent Complex and Its Application in Nanoemulsions
title_sort characterization of okra seed protein rutin covalent complex and its application in nanoemulsions
topic okra seed protein
rutin
covalent complex
nanoemulsion
url https://www.mdpi.com/2304-8158/14/10/1672
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AT lubai characterizationofokraseedproteinrutincovalentcomplexanditsapplicationinnanoemulsions
AT yingxuanzhou characterizationofokraseedproteinrutincovalentcomplexanditsapplicationinnanoemulsions
AT benguoliu characterizationofokraseedproteinrutincovalentcomplexanditsapplicationinnanoemulsions
AT shenggeng characterizationofokraseedproteinrutincovalentcomplexanditsapplicationinnanoemulsions