Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite

Abstract Pyrite and calcium sulfite were used to remove iron and manganese from an acidic aqueous solution. The concentration of Fe was decreased to be smaller than 0.05 g/L in 60 min when pyrite and air were added into the acidic aqueous solution, but the concentration of Mn in the solution remaine...

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Main Authors: Xu Zhang, Yajing Wang, Gesang Nima, Ziqian Wang, Caifeng Huang
Format: Article
Language:English
Published: Nature Portfolio 2025-02-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-88448-9
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author Xu Zhang
Yajing Wang
Gesang Nima
Ziqian Wang
Caifeng Huang
author_facet Xu Zhang
Yajing Wang
Gesang Nima
Ziqian Wang
Caifeng Huang
author_sort Xu Zhang
collection DOAJ
description Abstract Pyrite and calcium sulfite were used to remove iron and manganese from an acidic aqueous solution. The concentration of Fe was decreased to be smaller than 0.05 g/L in 60 min when pyrite and air were added into the acidic aqueous solution, but the concentration of Mn in the solution remained unchanged. After the process of iron removal, calcium sulfite and air were used to remove manganese ions from the solution, and the efficiency of manganese ion removal was larger than 75% in 240 min (with less than 0.05 g/L Fe and 0.5 g/L Mn in the solution). Meanwhile, experiments were conducted to simultaneously remove iron and manganese from artificially simulated acidic leaching solution of laterite nickel ore. When the proposed method was used to purify the leaching solution of laterite nickel ore, Fe3+ and Mn2+ ions were effectively removed from the acidic solution, and the recovery efficiency of nickel and cobalt was greater than 98%.
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institution Kabale University
issn 2045-2322
language English
publishDate 2025-02-01
publisher Nature Portfolio
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series Scientific Reports
spelling doaj-art-63cef3294ff94b0c8fc8f251ac87304e2025-02-09T12:37:07ZengNature PortfolioScientific Reports2045-23222025-02-0115111210.1038/s41598-025-88448-9Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfiteXu Zhang0Yajing Wang1Gesang Nima2Ziqian Wang3Caifeng Huang4School of Gemology and Materials Technology, Hebei GEO UniversitySchool of Gemology and Materials Technology, Hebei GEO UniversityTibet Bureau of Geology and Mineral Exploration and Development, Geothermal Geological Survey PartySchool of Gemology and Materials Technology, Hebei GEO UniversitySchool of Gemology and Materials Technology, Hebei GEO UniversityAbstract Pyrite and calcium sulfite were used to remove iron and manganese from an acidic aqueous solution. The concentration of Fe was decreased to be smaller than 0.05 g/L in 60 min when pyrite and air were added into the acidic aqueous solution, but the concentration of Mn in the solution remained unchanged. After the process of iron removal, calcium sulfite and air were used to remove manganese ions from the solution, and the efficiency of manganese ion removal was larger than 75% in 240 min (with less than 0.05 g/L Fe and 0.5 g/L Mn in the solution). Meanwhile, experiments were conducted to simultaneously remove iron and manganese from artificially simulated acidic leaching solution of laterite nickel ore. When the proposed method was used to purify the leaching solution of laterite nickel ore, Fe3+ and Mn2+ ions were effectively removed from the acidic solution, and the recovery efficiency of nickel and cobalt was greater than 98%.https://doi.org/10.1038/s41598-025-88448-9Iron removalManganese removalPyriteGoethiteLaterite nickel ore
spellingShingle Xu Zhang
Yajing Wang
Gesang Nima
Ziqian Wang
Caifeng Huang
Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite
Scientific Reports
Iron removal
Manganese removal
Pyrite
Goethite
Laterite nickel ore
title Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite
title_full Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite
title_fullStr Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite
title_full_unstemmed Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite
title_short Removal of iron and manganese from acidic aqueous solution by pyrite and pyrite-calcium sulfite
title_sort removal of iron and manganese from acidic aqueous solution by pyrite and pyrite calcium sulfite
topic Iron removal
Manganese removal
Pyrite
Goethite
Laterite nickel ore
url https://doi.org/10.1038/s41598-025-88448-9
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AT yajingwang removalofironandmanganesefromacidicaqueoussolutionbypyriteandpyritecalciumsulfite
AT gesangnima removalofironandmanganesefromacidicaqueoussolutionbypyriteandpyritecalciumsulfite
AT ziqianwang removalofironandmanganesefromacidicaqueoussolutionbypyriteandpyritecalciumsulfite
AT caifenghuang removalofironandmanganesefromacidicaqueoussolutionbypyriteandpyritecalciumsulfite