Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist

To address the durability issues of quartz schist (QS) on the slopes of open-pit mines under complex environmental conditions in high-cold regions, this study investigates the effects of freeze–thaw (F–T), dry–wet (D–W), and alternating (D–W–F–T) cycles on the macro and micro characteristics of QS u...

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Main Authors: Jiajian Jin, Daguo Wang, Jianguo Lu, Li Yin, Huan Xiao, Jinhe Li
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:Results in Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025018419
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author Jiajian Jin
Daguo Wang
Jianguo Lu
Li Yin
Huan Xiao
Jinhe Li
author_facet Jiajian Jin
Daguo Wang
Jianguo Lu
Li Yin
Huan Xiao
Jinhe Li
author_sort Jiajian Jin
collection DOAJ
description To address the durability issues of quartz schist (QS) on the slopes of open-pit mines under complex environmental conditions in high-cold regions, this study investigates the effects of freeze–thaw (F–T), dry–wet (D–W), and alternating (D–W–F–T) cycles on the macro and micro characteristics of QS using a multiscale test design. Changes in mechanical strength, mineral composition, and pore distribution were analyzed using triaxial compressive strength (TCS) tests, X-ray diffraction (XRD), and nuclear magnetic resonance (NMR). A study of pore structure was conducted via scanning electron microscopy (SEM), with quantitative analysis of pore roundness, orientation, and fractal dimension. Statistical correlations between macro- and micro-scale parameters were established. The results showed that, at the macro scale, the compressive strength of QS decreased from 115.78 MPa to 54.77 MPa, 41.68 MPa, and 43.91 MPa following F–T, D–W, and D–W-F–T cycles, respectively. At the micro scale, F–T cycles disrupted the cementation between mineral particles, enlarged pore sizes, and formed large pores and cracks. D–W cycles altered the internal mineral structure of the QS, affecting its physicochemical properties. The porosity of the F–T, D–W, and D–W–F–T group specimens increased from 0.22 % to 0.53 %, 0.43 %, and 0.54 %, respectively. Combining macro and micro analyses revealed that during the early stages of F–T and D–W cycles, continuous water-rock interactions dissolved hydrophilic minerals and disintegrated clay minerals, increasing weak points in the QS. Prolonged cycles led to pore structure deterioration due to ice extrusion and water-absorbing expansion of mineral components, ultimately reducing the macroscopic strength of the QS.
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spelling doaj-art-63ba22dded1e4c2689efd99957cd5ea62025-08-20T03:33:08ZengElsevierResults in Engineering2590-12302025-09-012710577010.1016/j.rineng.2025.105770Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schistJiajian Jin0Daguo Wang1Jianguo Lu2Li Yin3Huan Xiao4Jinhe Li5School of Civil Engineering and Geomatics, Southwest Petroleum University, Chengdu 610500, ChinaSchool of Civil Engineering and Geomatics, Southwest Petroleum University, Chengdu 610500, China; Corresponding author.School of Civil Engineering and Geomatics, Southwest Petroleum University, Chengdu 610500, ChinaSchool of Civil Engineering and Geomatics, Southwest Petroleum University, Chengdu 610500, ChinaSchool of Civil Engineering and Geomatics, Southwest Petroleum University, Chengdu 610500, ChinaGanzi Rongda Lithium Co., Ltd., Kangding 626000, ChinaTo address the durability issues of quartz schist (QS) on the slopes of open-pit mines under complex environmental conditions in high-cold regions, this study investigates the effects of freeze–thaw (F–T), dry–wet (D–W), and alternating (D–W–F–T) cycles on the macro and micro characteristics of QS using a multiscale test design. Changes in mechanical strength, mineral composition, and pore distribution were analyzed using triaxial compressive strength (TCS) tests, X-ray diffraction (XRD), and nuclear magnetic resonance (NMR). A study of pore structure was conducted via scanning electron microscopy (SEM), with quantitative analysis of pore roundness, orientation, and fractal dimension. Statistical correlations between macro- and micro-scale parameters were established. The results showed that, at the macro scale, the compressive strength of QS decreased from 115.78 MPa to 54.77 MPa, 41.68 MPa, and 43.91 MPa following F–T, D–W, and D–W-F–T cycles, respectively. At the micro scale, F–T cycles disrupted the cementation between mineral particles, enlarged pore sizes, and formed large pores and cracks. D–W cycles altered the internal mineral structure of the QS, affecting its physicochemical properties. The porosity of the F–T, D–W, and D–W–F–T group specimens increased from 0.22 % to 0.53 %, 0.43 %, and 0.54 %, respectively. Combining macro and micro analyses revealed that during the early stages of F–T and D–W cycles, continuous water-rock interactions dissolved hydrophilic minerals and disintegrated clay minerals, increasing weak points in the QS. Prolonged cycles led to pore structure deterioration due to ice extrusion and water-absorbing expansion of mineral components, ultimately reducing the macroscopic strength of the QS.http://www.sciencedirect.com/science/article/pii/S2590123025018419Dry–wet–freeze–thaw cycleQuartz schistMechanical propertyMicroscopic characteristicDeterioration mechanism
spellingShingle Jiajian Jin
Daguo Wang
Jianguo Lu
Li Yin
Huan Xiao
Jinhe Li
Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist
Results in Engineering
Dry–wet–freeze–thaw cycle
Quartz schist
Mechanical property
Microscopic characteristic
Deterioration mechanism
title Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist
title_full Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist
title_fullStr Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist
title_full_unstemmed Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist
title_short Effects of dry–wet and freeze–thaw cycles on the mechanical properties and microstructure of quartz schist
title_sort effects of dry wet and freeze thaw cycles on the mechanical properties and microstructure of quartz schist
topic Dry–wet–freeze–thaw cycle
Quartz schist
Mechanical property
Microscopic characteristic
Deterioration mechanism
url http://www.sciencedirect.com/science/article/pii/S2590123025018419
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