Distinguishing Ideal and Non-Ideal Chemical Systems Based on Kinetic Behavior
This paper focuses on differentiating between ideal and non-ideal chemical systems based on their kinetic behavior within a closed isothermal chemical environment. Non-ideality is examined using the non-ideal Marcelin–de Donde model. The analysis primarily addresses ‘soft’ non-ideality, where the eq...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-01-01
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| Series: | Entropy |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1099-4300/27/1/77 |
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| Summary: | This paper focuses on differentiating between ideal and non-ideal chemical systems based on their kinetic behavior within a closed isothermal chemical environment. Non-ideality is examined using the non-ideal Marcelin–de Donde model. The analysis primarily addresses ‘soft’ non-ideality, where the equilibrium composition for a reversible non-ideal chemical system is identical to the corresponding composition for the ideal chemical system. Our approach in distinguishing the ideal and non-ideal systems is based on the properties of the special event, i.e., event, the time of which is well-defined. For the single-step first-order reaction in the ideal system, this event is the half-time-decay point, or the intersection point. For the two consecutive reversible reactions in the ideal system, A ↔ B ↔ C, this event is the extremum obtained within the conservatively perturbed equilibrium (CPE) procedure. For the non-ideal correspondent models, the times of chosen events significantly depend on the initial concentrations. The obtained difference in the behavior of the times of these events (intersection point and CPE-extremum point) between the ideal and non-ideal systems is proposed as the kinetic fingerprint for distinguishing these systems. |
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| ISSN: | 1099-4300 |