Effect of ionic liquids on kinetic parameters of dicyanate ester polycyclotrimerization and on thermal and viscoelastic properties of resulting cyanate ester resins

Effect of ionic liquids on kinetic parameters of dicyanate ester polycyclotrimerization and on thermal and viscoelastic properties of resulting cyanate ester resins

A strong catalytic effect of 1.0 wt% ionic liquids (ILs) on kinetic parameters of dicyanate ester of bisphenol E(DCBE) polycyclotrimerization was evidenced, and structure-property relationships of resulting densely cross-linked cyanate ester resins (CERs) were investigated. Three different ILs with...

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Bibliographic Details
Main Authors: A. Fainleib, O. Grigoryeva, A. Vashchuk, O. Starostenko, S. Rogalsky, A. Rios de Anda, T-T-T. Nguyen, D. Grande
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2019-05-01
Series:eXPRESS Polymer Letters
Subjects:
Thermosetting resins
ionic liquids
catalytic effect
thermal stability
viscoelastic properties
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0009715&mi=cd
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Summary:A strong catalytic effect of 1.0 wt% ionic liquids (ILs) on kinetic parameters of dicyanate ester of bisphenol E(DCBE) polycyclotrimerization was evidenced, and structure-property relationships of resulting densely cross-linked cyanate ester resins (CERs) were investigated. Three different ILs with contrasted reactivity were employed as a catalysts: an aprotic IL, i.e. 1-octyl-3-methyl imidazolium tetrafluoroborate ([OMIm][BF4]), a protic IL, i.e. 2-(hydroxyethylamino) imidazolinium chloride ([HEAIm][Cl]), and a protic polymeric IL, i.e. poly(hexamethylene guanidine) toluene sulfonate ([PHMG][TS]). Both [HEAIm][Cl] and [PHMG][TS] were reactive towards DCBE monomer, whereas [OMIm][BF4] was chemically inert, as confirmed by Fourier Transform Infrared (FTIR) spectroscopy. Noticeably, the conversion (αc) of cyanate groups in the presence of ILs dramatically increased, and a significant dependence of αc values on IL chemical structure was found. The corresponding mechanisms of DCBE polycyclotrimerization in the presence of different ILs were proposed. All the CER/IL networks exhibited a high thermal stability inherent to neat CER, as shown by TGA, whereas unexpected significant changes of the viscoelastic characteristics for CER/IL networks compared to pure CER analogue were observed using DMTA.
ISSN:1788-618X

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