Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance

Hot stamping steels are extensively used in the production of lightweight automobile bodies, which are crucial for reducing carbon emissions. Although significant advancements have been made in the development of Si–Cr alloyed uncoated hot stamping steels to mitigate high-temperature oxidation, a ga...

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Main Authors: Zhaoqi Song, Kaixun Wang, Haitao Zhao, Long Ma, Junheng Gao, Honghui Wu, Yuhe Huang, Chaolei Zhang, Jun Lu, Shuize Wang, Xinping Mao
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425001735
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author Zhaoqi Song
Kaixun Wang
Haitao Zhao
Long Ma
Junheng Gao
Honghui Wu
Yuhe Huang
Chaolei Zhang
Jun Lu
Shuize Wang
Xinping Mao
author_facet Zhaoqi Song
Kaixun Wang
Haitao Zhao
Long Ma
Junheng Gao
Honghui Wu
Yuhe Huang
Chaolei Zhang
Jun Lu
Shuize Wang
Xinping Mao
author_sort Zhaoqi Song
collection DOAJ
description Hot stamping steels are extensively used in the production of lightweight automobile bodies, which are crucial for reducing carbon emissions. Although significant advancements have been made in the development of Si–Cr alloyed uncoated hot stamping steels to mitigate high-temperature oxidation, a gap remains in the literature regarding Al–Si alloyed uncoated steels. Specifically, there is a need for systematic investigation into their oxidation resistance. In this study, we designed Al–Si alloyed uncoated hot stamping steels based on the 22MnB5 composition system and characterized the scales formed under a simulated hot stamping thermal cycle. Our results indicate that the formation of dense Al2O3, SiO2, and Fe2SiO4 phases, driven by the presence of Al and Si, inhibits FeO formation, thereby enhancing oxidation resistance. Notably, the scale thickness decreases with increasing Al content, reaching just 3.5 μm at 0.48% Al, which is substantially lower than the 46 μm observed in 22MnB5 steel. However, due to compressive stress in the scale during its growth process, oxide ridges form when the Al content exceeds approximately 0.1%. Therefore, maintaining an optimal Al content of around 0.1% is recommended to prevent the formation of oxide ridges and prolong the lifespan of hot stamping moulds. This research not only addresses a critical gap in the literature but also offers a cost-effective strategy for enhancing the oxidation resistance of hot stamping steels, contributing to the broader goals of lightweight vehicle design and carbon emission reduction.
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spelling doaj-art-62a6e302543a46c2aef2c52e1f8c1c292025-01-30T05:14:20ZengElsevierJournal of Materials Research and Technology2238-78542025-03-013522422252Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistanceZhaoqi Song0Kaixun Wang1Haitao Zhao2Long Ma3Junheng Gao4Honghui Wu5Yuhe Huang6Chaolei Zhang7Jun Lu8Shuize Wang9Xinping Mao10State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaState Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaInstitute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR China; Corresponding author. Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China.Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaInstitute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR China; Corresponding author. Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China.Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaInstitute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaInstitute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaInstitute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaInstitute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR China; Corresponding author. Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China.State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing, 100083, PR China; Institute for Steel Sustainable Technology, Liaoning Academy of Materials, Shenyang, 110004, PR ChinaHot stamping steels are extensively used in the production of lightweight automobile bodies, which are crucial for reducing carbon emissions. Although significant advancements have been made in the development of Si–Cr alloyed uncoated hot stamping steels to mitigate high-temperature oxidation, a gap remains in the literature regarding Al–Si alloyed uncoated steels. Specifically, there is a need for systematic investigation into their oxidation resistance. In this study, we designed Al–Si alloyed uncoated hot stamping steels based on the 22MnB5 composition system and characterized the scales formed under a simulated hot stamping thermal cycle. Our results indicate that the formation of dense Al2O3, SiO2, and Fe2SiO4 phases, driven by the presence of Al and Si, inhibits FeO formation, thereby enhancing oxidation resistance. Notably, the scale thickness decreases with increasing Al content, reaching just 3.5 μm at 0.48% Al, which is substantially lower than the 46 μm observed in 22MnB5 steel. However, due to compressive stress in the scale during its growth process, oxide ridges form when the Al content exceeds approximately 0.1%. Therefore, maintaining an optimal Al content of around 0.1% is recommended to prevent the formation of oxide ridges and prolong the lifespan of hot stamping moulds. This research not only addresses a critical gap in the literature but also offers a cost-effective strategy for enhancing the oxidation resistance of hot stamping steels, contributing to the broader goals of lightweight vehicle design and carbon emission reduction.http://www.sciencedirect.com/science/article/pii/S2238785425001735Hot stamping steelOxidation resistanceAl–Si alloyedVehicles lightweightingCarbon neutrality
spellingShingle Zhaoqi Song
Kaixun Wang
Haitao Zhao
Long Ma
Junheng Gao
Honghui Wu
Yuhe Huang
Chaolei Zhang
Jun Lu
Shuize Wang
Xinping Mao
Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance
Journal of Materials Research and Technology
Hot stamping steel
Oxidation resistance
Al–Si alloyed
Vehicles lightweighting
Carbon neutrality
title Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance
title_full Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance
title_fullStr Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance
title_full_unstemmed Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance
title_short Al–Si alloyed uncoated hot stamping steels for enhanced oxidation resistance
title_sort al si alloyed uncoated hot stamping steels for enhanced oxidation resistance
topic Hot stamping steel
Oxidation resistance
Al–Si alloyed
Vehicles lightweighting
Carbon neutrality
url http://www.sciencedirect.com/science/article/pii/S2238785425001735
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