Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques

Near-infrared spectroscopy and multivariate analysis techniques were employed to nondestructively evaluate the rancidity of perilla seed oil by developing prediction models for the acid and peroxide values. The acid, peroxide value, and transmittance spectra of perilla seed oil stored in two differe...

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Main Authors: Suk-Ju Hong, Shin-Joung Rho, Ah-Yeong Lee, Heesoo Park, Jinshi Cui, Jongmin Park, Soon-Jung Hong, Yong-Ro Kim, Ghiseok Kim
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Spectroscopy
Online Access:http://dx.doi.org/10.1155/2017/1082612
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author Suk-Ju Hong
Shin-Joung Rho
Ah-Yeong Lee
Heesoo Park
Jinshi Cui
Jongmin Park
Soon-Jung Hong
Yong-Ro Kim
Ghiseok Kim
author_facet Suk-Ju Hong
Shin-Joung Rho
Ah-Yeong Lee
Heesoo Park
Jinshi Cui
Jongmin Park
Soon-Jung Hong
Yong-Ro Kim
Ghiseok Kim
author_sort Suk-Ju Hong
collection DOAJ
description Near-infrared spectroscopy and multivariate analysis techniques were employed to nondestructively evaluate the rancidity of perilla seed oil by developing prediction models for the acid and peroxide values. The acid, peroxide value, and transmittance spectra of perilla seed oil stored in two different environments for 96 and 144 h were obtained and used to develop prediction models for different storage conditions and time periods. Preprocessing methods were applied to the transmittance spectra of perilla seed oil, and multivariate analysis techniques, such as principal component regression (PCR), partial least squares regression (PLSR), and artificial neural network (ANN) modeling, were employed to develop the models. Titration analysis shows that the free fatty acids in an oil oxidation process were more affected by relative humidity than temperature, whereas peroxides in an oil oxidation process were more significantly affected by temperature than relative humidity for the two different environments in this study. Also, the prediction results of ANN models for both acid and peroxide values were the highest among the developed models. These results suggest that the proposed near-infrared spectroscopy technique with multivariate analysis can be used for the nondestructive evaluation of the rancidity of perilla seed oil, especially the acid and peroxide values.
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spelling doaj-art-629a7c3a64ee40ed9db37ab15e5660212025-02-03T01:33:28ZengWileyJournal of Spectroscopy2314-49202314-49392017-01-01201710.1155/2017/10826121082612Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis TechniquesSuk-Ju Hong0Shin-Joung Rho1Ah-Yeong Lee2Heesoo Park3Jinshi Cui4Jongmin Park5Soon-Jung Hong6Yong-Ro Kim7Ghiseok Kim8Department of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaDepartment of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaDepartment of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaDepartment of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaDepartment of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaDepartment of Bio-Industrial Machinery Engineering, Pusan National University, 1268-50 Samnangjin-ro, Cheonghak-ri, Samnangjin-eup, Miryang-si 50463, Republic of KoreaRural Human Resource Development Center, Rural Development Administration, 420 Nongsaengmyeong-ro, Wansan-gu, Jeonju-si 54874, Republic of KoreaDepartment of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaDepartment of Biosystems and Biomaterials Science and Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of KoreaNear-infrared spectroscopy and multivariate analysis techniques were employed to nondestructively evaluate the rancidity of perilla seed oil by developing prediction models for the acid and peroxide values. The acid, peroxide value, and transmittance spectra of perilla seed oil stored in two different environments for 96 and 144 h were obtained and used to develop prediction models for different storage conditions and time periods. Preprocessing methods were applied to the transmittance spectra of perilla seed oil, and multivariate analysis techniques, such as principal component regression (PCR), partial least squares regression (PLSR), and artificial neural network (ANN) modeling, were employed to develop the models. Titration analysis shows that the free fatty acids in an oil oxidation process were more affected by relative humidity than temperature, whereas peroxides in an oil oxidation process were more significantly affected by temperature than relative humidity for the two different environments in this study. Also, the prediction results of ANN models for both acid and peroxide values were the highest among the developed models. These results suggest that the proposed near-infrared spectroscopy technique with multivariate analysis can be used for the nondestructive evaluation of the rancidity of perilla seed oil, especially the acid and peroxide values.http://dx.doi.org/10.1155/2017/1082612
spellingShingle Suk-Ju Hong
Shin-Joung Rho
Ah-Yeong Lee
Heesoo Park
Jinshi Cui
Jongmin Park
Soon-Jung Hong
Yong-Ro Kim
Ghiseok Kim
Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques
Journal of Spectroscopy
title Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques
title_full Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques
title_fullStr Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques
title_full_unstemmed Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques
title_short Rancidity Estimation of Perilla Seed Oil by Using Near-Infrared Spectroscopy and Multivariate Analysis Techniques
title_sort rancidity estimation of perilla seed oil by using near infrared spectroscopy and multivariate analysis techniques
url http://dx.doi.org/10.1155/2017/1082612
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