Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing

Abstract The problem of ice accumulation causes huge inconvenience in daily life and industrial application. Although superhydrophobic surfaces are promising for preventing ice formation, they may become ineffective in extreme environments. Here, a durable photothermal superhydrophobic surface on al...

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Main Authors: Lu Wang, Jingxing Li, Zhaochuan Chen, Zitao Song, Xin Meng, Xuemei Chen
Format: Article
Language:English
Published: Wiley-VCH 2022-12-01
Series:Advanced Materials Interfaces
Subjects:
Online Access:https://doi.org/10.1002/admi.202201758
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author Lu Wang
Jingxing Li
Zhaochuan Chen
Zitao Song
Xin Meng
Xuemei Chen
author_facet Lu Wang
Jingxing Li
Zhaochuan Chen
Zitao Song
Xin Meng
Xuemei Chen
author_sort Lu Wang
collection DOAJ
description Abstract The problem of ice accumulation causes huge inconvenience in daily life and industrial application. Although superhydrophobic surfaces are promising for preventing ice formation, they may become ineffective in extreme environments. Here, a durable photothermal superhydrophobic surface on aluminum substrate (SHPo‐LIG@Al) is prepared through laser‐induced graphene (LIG) technology of polyimide (PI). Owing to the photothermal effect of graphene, the surface exhibits high light absorption rate (≈98%) and efficient photothermal conversion (surface temperature rises to 65 °C within 15 min under 1 sun). Compared to the conventional superhydrophobic surface (SHPo‐Al), ultra‐long droplet freezing time or even droplet un‐frozen is achieved on SHPo‐LIG@Al surface by varying the sunlight intensity. Moreover, it is interesting to find that satellite condensate droplets are formed around the three‐phase contact line of deposited droplet under 1 sun or 2 sun; the satellite condensate droplets would gradually evaporate till disappear and then bubbles start to nucleate on solid surface underneath the deposited droplet under 2 sun. Furthermore, the SHPo‐LIG@Al surface exhibits retarded frost formation and remarkable de‐icing/de‐frosting durability under sunlight irradiation, as well as self‐cleaning, chemical stability and corrosion resistance. This study may provide important insights for the development of photothermal superhydrophobic surface for anti‐icing/de‐icing applications.
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id doaj-art-6221d4e6a75646f99a6ae8bf4c38bc8b
institution Kabale University
issn 2196-7350
language English
publishDate 2022-12-01
publisher Wiley-VCH
record_format Article
series Advanced Materials Interfaces
spelling doaj-art-6221d4e6a75646f99a6ae8bf4c38bc8b2025-08-20T03:31:36ZengWiley-VCHAdvanced Materials Interfaces2196-73502022-12-01935n/an/a10.1002/admi.202201758Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐IcingLu Wang0Jingxing Li1Zhaochuan Chen2Zitao Song3Xin Meng4Xuemei Chen5MIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power Engineering Nanjing University of Science and Technology Nanjing 210094 ChinaNanjing Jinling High School International Department Cambridge Class 12 Grade 169 Zhongshan Road Nanjing 210005 ChinaMIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power Engineering Nanjing University of Science and Technology Nanjing 210094 ChinaMIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power Engineering Nanjing University of Science and Technology Nanjing 210094 ChinaMIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power Engineering Nanjing University of Science and Technology Nanjing 210094 ChinaMIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power Engineering Nanjing University of Science and Technology Nanjing 210094 ChinaAbstract The problem of ice accumulation causes huge inconvenience in daily life and industrial application. Although superhydrophobic surfaces are promising for preventing ice formation, they may become ineffective in extreme environments. Here, a durable photothermal superhydrophobic surface on aluminum substrate (SHPo‐LIG@Al) is prepared through laser‐induced graphene (LIG) technology of polyimide (PI). Owing to the photothermal effect of graphene, the surface exhibits high light absorption rate (≈98%) and efficient photothermal conversion (surface temperature rises to 65 °C within 15 min under 1 sun). Compared to the conventional superhydrophobic surface (SHPo‐Al), ultra‐long droplet freezing time or even droplet un‐frozen is achieved on SHPo‐LIG@Al surface by varying the sunlight intensity. Moreover, it is interesting to find that satellite condensate droplets are formed around the three‐phase contact line of deposited droplet under 1 sun or 2 sun; the satellite condensate droplets would gradually evaporate till disappear and then bubbles start to nucleate on solid surface underneath the deposited droplet under 2 sun. Furthermore, the SHPo‐LIG@Al surface exhibits retarded frost formation and remarkable de‐icing/de‐frosting durability under sunlight irradiation, as well as self‐cleaning, chemical stability and corrosion resistance. This study may provide important insights for the development of photothermal superhydrophobic surface for anti‐icing/de‐icing applications.https://doi.org/10.1002/admi.202201758anti‐icing/anti‐frostinggraphene materialsphotothermal de‐icing/de‐frostingself‐cleaningsuperhydrophobic
spellingShingle Lu Wang
Jingxing Li
Zhaochuan Chen
Zitao Song
Xin Meng
Xuemei Chen
Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing
Advanced Materials Interfaces
anti‐icing/anti‐frosting
graphene materials
photothermal de‐icing/de‐frosting
self‐cleaning
superhydrophobic
title Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing
title_full Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing
title_fullStr Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing
title_full_unstemmed Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing
title_short Porous Graphene‐Based Photothermal Superhydrophobic Surface for Robust Anti‐Icing and Efficient De‐Icing
title_sort porous graphene based photothermal superhydrophobic surface for robust anti icing and efficient de icing
topic anti‐icing/anti‐frosting
graphene materials
photothermal de‐icing/de‐frosting
self‐cleaning
superhydrophobic
url https://doi.org/10.1002/admi.202201758
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AT zhaochuanchen porousgraphenebasedphotothermalsuperhydrophobicsurfaceforrobustantiicingandefficientdeicing
AT zitaosong porousgraphenebasedphotothermalsuperhydrophobicsurfaceforrobustantiicingandefficientdeicing
AT xinmeng porousgraphenebasedphotothermalsuperhydrophobicsurfaceforrobustantiicingandefficientdeicing
AT xuemeichen porousgraphenebasedphotothermalsuperhydrophobicsurfaceforrobustantiicingandefficientdeicing