Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices

Nanocomposite based on tungsten oxide (WO3), graphene oxide (GO), and poly (anthranilic acid) were synthesized and doped into epoxy resin film. Nanocomposite with varying WO3 content (GO-10 %WO3, GO-20 %WO3, and GO-30 %WO3) were blended with epoxy-PANA to produce hybrid films. The structural and mor...

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Main Authors: Abdulwahhab H. Majeed, Wasan Abdulfatah Hussen, Ahmed Najem Abd, Zaid H. Mahmoud, Ehsan kianfar
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:South African Journal of Chemical Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1026918525000642
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author Abdulwahhab H. Majeed
Wasan Abdulfatah Hussen
Ahmed Najem Abd
Zaid H. Mahmoud
Ehsan kianfar
author_facet Abdulwahhab H. Majeed
Wasan Abdulfatah Hussen
Ahmed Najem Abd
Zaid H. Mahmoud
Ehsan kianfar
author_sort Abdulwahhab H. Majeed
collection DOAJ
description Nanocomposite based on tungsten oxide (WO3), graphene oxide (GO), and poly (anthranilic acid) were synthesized and doped into epoxy resin film. Nanocomposite with varying WO3 content (GO-10 %WO3, GO-20 %WO3, and GO-30 %WO3) were blended with epoxy-PANA to produce hybrid films. The structural and morphological features were investigated by FTIR, XRD, EDX, and SEM. The dielectric properties including (real dielectric constant (real permittivity) (ε′), imaginary dielectric constant (imaginary permittivity) (ε″), loss factor (tanδ), and electrical conductivity (σ ac)) were evaluated across frequency of 100 kHz to 5 MHz. All prepared films appeared reducing in ε′, ε″ and tan δ with increasing frequency, while (σ ac) increased. Notably, higher WO3 loading improvement both permittivity and conductivity, with GO-30 %WO3/epoxy-PANA appearing the most significant improvement. These results highlight the potential of prepared composite in dielectric and conductive applications.
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issn 1026-9185
language English
publishDate 2025-07-01
publisher Elsevier
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series South African Journal of Chemical Engineering
spelling doaj-art-6211c4bf8b9e4a37bb4cdf3086f578ef2025-08-20T03:51:09ZengElsevierSouth African Journal of Chemical Engineering1026-91852025-07-015330331810.1016/j.sajce.2025.05.009Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matricesAbdulwahhab H. Majeed0Wasan Abdulfatah Hussen1Ahmed Najem Abd2Zaid H. Mahmoud3Ehsan kianfar4Department of Chemistry, College of Science, University of Diyala, Diyala, IraqDepartment of Chemistry, College of Science, University of Diyala, Diyala, IraqDepartment of Chemistry, College of Science, University of Diyala, Diyala, IraqDepartment of Chemistry, College of Science, University of Diyala, Diyala, Iraq; Corresponding authors.Young Researchers and Elite Club, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran; Corresponding authors.Nanocomposite based on tungsten oxide (WO3), graphene oxide (GO), and poly (anthranilic acid) were synthesized and doped into epoxy resin film. Nanocomposite with varying WO3 content (GO-10 %WO3, GO-20 %WO3, and GO-30 %WO3) were blended with epoxy-PANA to produce hybrid films. The structural and morphological features were investigated by FTIR, XRD, EDX, and SEM. The dielectric properties including (real dielectric constant (real permittivity) (ε′), imaginary dielectric constant (imaginary permittivity) (ε″), loss factor (tanδ), and electrical conductivity (σ ac)) were evaluated across frequency of 100 kHz to 5 MHz. All prepared films appeared reducing in ε′, ε″ and tan δ with increasing frequency, while (σ ac) increased. Notably, higher WO3 loading improvement both permittivity and conductivity, with GO-30 %WO3/epoxy-PANA appearing the most significant improvement. These results highlight the potential of prepared composite in dielectric and conductive applications.http://www.sciencedirect.com/science/article/pii/S1026918525000642Graphene oxideTungsten oxideNanocompositeElectrical conductivityDielectric constant
spellingShingle Abdulwahhab H. Majeed
Wasan Abdulfatah Hussen
Ahmed Najem Abd
Zaid H. Mahmoud
Ehsan kianfar
Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices
South African Journal of Chemical Engineering
Graphene oxide
Tungsten oxide
Nanocomposite
Electrical conductivity
Dielectric constant
title Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices
title_full Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices
title_fullStr Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices
title_full_unstemmed Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices
title_short Graphene–tungsten oxide hybrid nanocomposites for high-performance dielectric films in conductive polymer matrices
title_sort graphene tungsten oxide hybrid nanocomposites for high performance dielectric films in conductive polymer matrices
topic Graphene oxide
Tungsten oxide
Nanocomposite
Electrical conductivity
Dielectric constant
url http://www.sciencedirect.com/science/article/pii/S1026918525000642
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