4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one
An aldol condensation reaction between [2-(O=CH)C<sub>6</sub>H<sub>4</sub>]SnPh<sub>2</sub>Cl and acetone gave [2-{CH<sub>3</sub>C(=O)CH<sub>2</sub>(OH)CH}C<sub>6</sub>H<sub>4</sub>]SnPh<sub>2</sub>Cl (&l...
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MDPI AG
2025-04-01
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| author | Adrian-Alexandru Someșan Richard A. Varga |
| author_facet | Adrian-Alexandru Someșan Richard A. Varga |
| author_sort | Adrian-Alexandru Someșan |
| collection | DOAJ |
| description | An aldol condensation reaction between [2-(O=CH)C<sub>6</sub>H<sub>4</sub>]SnPh<sub>2</sub>Cl and acetone gave [2-{CH<sub>3</sub>C(=O)CH<sub>2</sub>(OH)CH}C<sub>6</sub>H<sub>4</sub>]SnPh<sub>2</sub>Cl (<b>1</b>). The compound was characterized in a solution using multinuclear NMR spectroscopy and HR-MS spectrometry and in a solid state using IR spectroscopy and single-crystal X-ray diffraction. The molecular structure revealed the presence of both enantiomers in the crystal. |
| format | Article |
| id | doaj-art-61a31e569f5d46aa8dafc0e71d81d68a |
| institution | Kabale University |
| issn | 1422-8599 |
| language | English |
| publishDate | 2025-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj-art-61a31e569f5d46aa8dafc0e71d81d68a2025-08-20T03:27:32ZengMDPI AGMolbank1422-85992025-04-0120252M199110.3390/M19914-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-oneAdrian-Alexandru Someșan0Richard A. Varga1Department of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC), Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, 11 Arany Janos, 400028 Cluj-Napoca, RomaniaDepartment of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC), Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, 11 Arany Janos, 400028 Cluj-Napoca, RomaniaAn aldol condensation reaction between [2-(O=CH)C<sub>6</sub>H<sub>4</sub>]SnPh<sub>2</sub>Cl and acetone gave [2-{CH<sub>3</sub>C(=O)CH<sub>2</sub>(OH)CH}C<sub>6</sub>H<sub>4</sub>]SnPh<sub>2</sub>Cl (<b>1</b>). The compound was characterized in a solution using multinuclear NMR spectroscopy and HR-MS spectrometry and in a solid state using IR spectroscopy and single-crystal X-ray diffraction. The molecular structure revealed the presence of both enantiomers in the crystal.https://www.mdpi.com/1422-8599/2025/2/M1991organotin(IV)(<i>C</i>,<i>O</i>)-aryl ligandaldol condensation |
| spellingShingle | Adrian-Alexandru Someșan Richard A. Varga 4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one Molbank organotin(IV) (<i>C</i>,<i>O</i>)-aryl ligand aldol condensation |
| title | 4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one |
| title_full | 4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one |
| title_fullStr | 4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one |
| title_full_unstemmed | 4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one |
| title_short | 4-[2-(Chlorodiphenylstannyl)phenyl]-4-hydroxybutan-2-one |
| title_sort | 4 2 chlorodiphenylstannyl phenyl 4 hydroxybutan 2 one |
| topic | organotin(IV) (<i>C</i>,<i>O</i>)-aryl ligand aldol condensation |
| url | https://www.mdpi.com/1422-8599/2025/2/M1991 |
| work_keys_str_mv | AT adrianalexandrusomesan 42chlorodiphenylstannylphenyl4hydroxybutan2one AT richardavarga 42chlorodiphenylstannylphenyl4hydroxybutan2one |