Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material

Potassium is one of the macro minerals necessary for the cellular functions, obtained from foods. Excessive amounts of potassium can cause health problems. Determination of potassium in various samples, especially food and drug samples, is an important task. In this study, we developed a new potenti...

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Main Authors: Oguz Özbek, Mehmet Alperen Şahin
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-03-01
Series:Resources Chemicals and Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772443324000321
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author Oguz Özbek
Mehmet Alperen Şahin
author_facet Oguz Özbek
Mehmet Alperen Şahin
author_sort Oguz Özbek
collection DOAJ
description Potassium is one of the macro minerals necessary for the cellular functions, obtained from foods. Excessive amounts of potassium can cause health problems. Determination of potassium in various samples, especially food and drug samples, is an important task. In this study, we developed a new potentiometric sensor selective to potassium ions. The sensor had a detection limit of 8.64 × 10-5 M in the concentration range of 1.0 × 10-1–1.0 × 10-4 M and a near–Nernstian behavior of 49.0 ± 4.32 mV/decade. The sensor exhibited a response time of 10 s, as well as good selectivity, good repeatability, and a wide pH working range (4.0–11.0). The developed sensor was successfully applied to a drug sample and different water samples with very high recoveries (>91.20 %).
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spelling doaj-art-617df8d87df14d5a97355ebf5ac9971e2025-08-20T01:55:11ZengKeAi Communications Co., Ltd.Resources Chemicals and Materials2772-44332025-03-014110007910.1016/j.recm.2024.07.003Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor materialOguz Özbek0Mehmet Alperen Şahin1Corresponding author.; Faculty of Science and Arts, Department of Molecular Biology and Genetics, Tokat Gaziosmanpaşa University, Tokat 60250, TurkeyFaculty of Science and Arts, Department of Molecular Biology and Genetics, Tokat Gaziosmanpaşa University, Tokat 60250, TurkeyPotassium is one of the macro minerals necessary for the cellular functions, obtained from foods. Excessive amounts of potassium can cause health problems. Determination of potassium in various samples, especially food and drug samples, is an important task. In this study, we developed a new potentiometric sensor selective to potassium ions. The sensor had a detection limit of 8.64 × 10-5 M in the concentration range of 1.0 × 10-1–1.0 × 10-4 M and a near–Nernstian behavior of 49.0 ± 4.32 mV/decade. The sensor exhibited a response time of 10 s, as well as good selectivity, good repeatability, and a wide pH working range (4.0–11.0). The developed sensor was successfully applied to a drug sample and different water samples with very high recoveries (>91.20 %).http://www.sciencedirect.com/science/article/pii/S2772443324000321PotassiumIon–selective sensorPotentiometryElectroanalytical methods
spellingShingle Oguz Özbek
Mehmet Alperen Şahin
Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
Resources Chemicals and Materials
Potassium
Ion–selective sensor
Potentiometry
Electroanalytical methods
title Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
title_full Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
title_fullStr Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
title_full_unstemmed Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
title_short Novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
title_sort novel electrochemical sensor for the determination of potassium ions based on silver diethyldithiocarbamate as sensor material
topic Potassium
Ion–selective sensor
Potentiometry
Electroanalytical methods
url http://www.sciencedirect.com/science/article/pii/S2772443324000321
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