INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY
The interactions of benzoic or salycilic acids salts with di-, trihalides or SnPh3OH have yielded four new complexes and adducts studied by infrared.The suggested structures are discrete or of infinite chain type, the anion behaving as monodentate and hydrogen bonding involved, or bidentate, the en...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-03-01
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Series: | Journal of Engineering Studies and Research |
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Online Access: | https://jesr.ub.ro/index.php/1/article/view/91 |
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author | ASSANE TOURE LIBASSE DIOP |
author_facet | ASSANE TOURE LIBASSE DIOP |
author_sort | ASSANE TOURE |
collection | DOAJ |
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The interactions of benzoic or salycilic acids salts with di-, trihalides or SnPh3OH have yielded four new complexes and adducts studied by infrared.The suggested structures are discrete or of infinite chain type, the anion behaving as monodentate and hydrogen bonding involved, or bidentate, the environments around the metallic centres being tetrahedral, octahedral or trigonal bipyramidal. When N-H groups are involved in extra hydrogen bonding, a supramolecular architecture may be obtained.
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format | Article |
id | doaj-art-614c631c866c4367977728f6f19d3735 |
institution | Kabale University |
issn | 2068-7559 2344-4932 |
language | English |
publishDate | 2017-03-01 |
publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
record_format | Article |
series | Journal of Engineering Studies and Research |
spelling | doaj-art-614c631c866c4367977728f6f19d37352025-02-09T11:38:06ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-03-01231INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDYASSANE TOURE0LIBASSE DIOP1 Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal The interactions of benzoic or salycilic acids salts with di-, trihalides or SnPh3OH have yielded four new complexes and adducts studied by infrared.The suggested structures are discrete or of infinite chain type, the anion behaving as monodentate and hydrogen bonding involved, or bidentate, the environments around the metallic centres being tetrahedral, octahedral or trigonal bipyramidal. When N-H groups are involved in extra hydrogen bonding, a supramolecular architecture may be obtained. https://jesr.ub.ro/index.php/1/article/view/91complexes and adductdiscrete structuresmono- and bidentate benzoatemonochelating and monodentatemonochelating benzoatemonochelating or only hydrogen bonding involved salycilate |
spellingShingle | ASSANE TOURE LIBASSE DIOP INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY Journal of Engineering Studies and Research complexes and adduct discrete structures mono- and bidentate benzoate monochelating and monodentate monochelating benzoate monochelating or only hydrogen bonding involved salycilate |
title | INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY |
title_full | INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY |
title_fullStr | INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY |
title_full_unstemmed | INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY |
title_short | INTERACTIONS BETWEEN C6H4(CH2NH3)2[PhCO2]2, Et2NH2[Ph(OH)CO2] AND CuCl2, ErCl3 or SnPh3OH: AN INFRARED STUDY |
title_sort | interactions between c6h4 ch2nh3 2 phco2 2 et2nh2 ph oh co2 and cucl2 ercl3 or snph3oh an infrared study |
topic | complexes and adduct discrete structures mono- and bidentate benzoate monochelating and monodentate monochelating benzoate monochelating or only hydrogen bonding involved salycilate |
url | https://jesr.ub.ro/index.php/1/article/view/91 |
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