Organophosphate Nerve Agent Detection with Europium Complexes
We explore the detection of paraoxon, a model compound for nonvolatile organophosphate nerve agents such as VX. The detection utilizes europium complexes with 1,10 phenanthroline and thenoyltrifluoroacetone as sensitizing ligands. Both europium luminescence quenching and luminescence enhancement mod...
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Format: | Article |
Language: | English |
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Wiley
2004-01-01
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Series: | The Scientific World Journal |
Online Access: | http://dx.doi.org/10.1100/tsw.2004.194 |
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author | Jake R. Schwierking Laird W. Menzel E. Roland Menzel |
author_facet | Jake R. Schwierking Laird W. Menzel E. Roland Menzel |
author_sort | Jake R. Schwierking |
collection | DOAJ |
description | We explore the detection of paraoxon, a model compound for nonvolatile organophosphate nerve agents such as VX. The detection utilizes europium complexes with 1,10 phenanthroline and thenoyltrifluoroacetone as sensitizing ligands. Both europium luminescence quenching and luminescence enhancement modalities are involved in the detection, which is simple, rapid, and sensitive. It is adaptable as well to the more volatile fluorophosphate nerve agents. It involves nothing more than visual luminescence observation under sample illumination by an ordinary hand-held ultraviolet lamp. |
format | Article |
id | doaj-art-61425cc1fd8747298ea4a6abb61fefb9 |
institution | Kabale University |
issn | 1537-744X |
language | English |
publishDate | 2004-01-01 |
publisher | Wiley |
record_format | Article |
series | The Scientific World Journal |
spelling | doaj-art-61425cc1fd8747298ea4a6abb61fefb92025-02-03T06:44:38ZengWileyThe Scientific World Journal1537-744X2004-01-01494895510.1100/tsw.2004.194Organophosphate Nerve Agent Detection with Europium ComplexesJake R. Schwierking0Laird W. Menzel1E. Roland Menzel2Center for Forensic Studies, Physics Department, Texas Tech University, Lubbock, TX 79409-1051, USACenter for Forensic Studies, Physics Department, Texas Tech University, Lubbock, TX 79409-1051, USACenter for Forensic Studies, Physics Department, Texas Tech University, Lubbock, TX 79409-1051, USAWe explore the detection of paraoxon, a model compound for nonvolatile organophosphate nerve agents such as VX. The detection utilizes europium complexes with 1,10 phenanthroline and thenoyltrifluoroacetone as sensitizing ligands. Both europium luminescence quenching and luminescence enhancement modalities are involved in the detection, which is simple, rapid, and sensitive. It is adaptable as well to the more volatile fluorophosphate nerve agents. It involves nothing more than visual luminescence observation under sample illumination by an ordinary hand-held ultraviolet lamp.http://dx.doi.org/10.1100/tsw.2004.194 |
spellingShingle | Jake R. Schwierking Laird W. Menzel E. Roland Menzel Organophosphate Nerve Agent Detection with Europium Complexes The Scientific World Journal |
title | Organophosphate Nerve Agent Detection with Europium Complexes |
title_full | Organophosphate Nerve Agent Detection with Europium Complexes |
title_fullStr | Organophosphate Nerve Agent Detection with Europium Complexes |
title_full_unstemmed | Organophosphate Nerve Agent Detection with Europium Complexes |
title_short | Organophosphate Nerve Agent Detection with Europium Complexes |
title_sort | organophosphate nerve agent detection with europium complexes |
url | http://dx.doi.org/10.1100/tsw.2004.194 |
work_keys_str_mv | AT jakerschwierking organophosphatenerveagentdetectionwitheuropiumcomplexes AT lairdwmenzel organophosphatenerveagentdetectionwitheuropiumcomplexes AT erolandmenzel organophosphatenerveagentdetectionwitheuropiumcomplexes |