Organophosphate Nerve Agent Detection with Europium Complexes

We explore the detection of paraoxon, a model compound for nonvolatile organophosphate nerve agents such as VX. The detection utilizes europium complexes with 1,10 phenanthroline and thenoyltrifluoroacetone as sensitizing ligands. Both europium luminescence quenching and luminescence enhancement mod...

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Main Authors: Jake R. Schwierking, Laird W. Menzel, E. Roland Menzel
Format: Article
Language:English
Published: Wiley 2004-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1100/tsw.2004.194
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author Jake R. Schwierking
Laird W. Menzel
E. Roland Menzel
author_facet Jake R. Schwierking
Laird W. Menzel
E. Roland Menzel
author_sort Jake R. Schwierking
collection DOAJ
description We explore the detection of paraoxon, a model compound for nonvolatile organophosphate nerve agents such as VX. The detection utilizes europium complexes with 1,10 phenanthroline and thenoyltrifluoroacetone as sensitizing ligands. Both europium luminescence quenching and luminescence enhancement modalities are involved in the detection, which is simple, rapid, and sensitive. It is adaptable as well to the more volatile fluorophosphate nerve agents. It involves nothing more than visual luminescence observation under sample illumination by an ordinary hand-held ultraviolet lamp.
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issn 1537-744X
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spelling doaj-art-61425cc1fd8747298ea4a6abb61fefb92025-02-03T06:44:38ZengWileyThe Scientific World Journal1537-744X2004-01-01494895510.1100/tsw.2004.194Organophosphate Nerve Agent Detection with Europium ComplexesJake R. Schwierking0Laird W. Menzel1E. Roland Menzel2Center for Forensic Studies, Physics Department, Texas Tech University, Lubbock, TX 79409-1051, USACenter for Forensic Studies, Physics Department, Texas Tech University, Lubbock, TX 79409-1051, USACenter for Forensic Studies, Physics Department, Texas Tech University, Lubbock, TX 79409-1051, USAWe explore the detection of paraoxon, a model compound for nonvolatile organophosphate nerve agents such as VX. The detection utilizes europium complexes with 1,10 phenanthroline and thenoyltrifluoroacetone as sensitizing ligands. Both europium luminescence quenching and luminescence enhancement modalities are involved in the detection, which is simple, rapid, and sensitive. It is adaptable as well to the more volatile fluorophosphate nerve agents. It involves nothing more than visual luminescence observation under sample illumination by an ordinary hand-held ultraviolet lamp.http://dx.doi.org/10.1100/tsw.2004.194
spellingShingle Jake R. Schwierking
Laird W. Menzel
E. Roland Menzel
Organophosphate Nerve Agent Detection with Europium Complexes
The Scientific World Journal
title Organophosphate Nerve Agent Detection with Europium Complexes
title_full Organophosphate Nerve Agent Detection with Europium Complexes
title_fullStr Organophosphate Nerve Agent Detection with Europium Complexes
title_full_unstemmed Organophosphate Nerve Agent Detection with Europium Complexes
title_short Organophosphate Nerve Agent Detection with Europium Complexes
title_sort organophosphate nerve agent detection with europium complexes
url http://dx.doi.org/10.1100/tsw.2004.194
work_keys_str_mv AT jakerschwierking organophosphatenerveagentdetectionwitheuropiumcomplexes
AT lairdwmenzel organophosphatenerveagentdetectionwitheuropiumcomplexes
AT erolandmenzel organophosphatenerveagentdetectionwitheuropiumcomplexes