SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES

Approaching a hypothetical thermodynamically reversible process is one of the main directions of energy saving in distillation. In practice, this is achieved by the use of systems with coupled thermal and material flows (STMP). Such systems have long been used in the separation of zeotropic mixtures...

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Main Authors: E. А. Anokhina, А. V. Timoshenko
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2017-12-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/124
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author E. А. Anokhina
А. V. Timoshenko
author_facet E. А. Anokhina
А. V. Timoshenko
author_sort E. А. Anokhina
collection DOAJ
description Approaching a hypothetical thermodynamically reversible process is one of the main directions of energy saving in distillation. In practice, this is achieved by the use of systems with coupled thermal and material flows (STMP). Such systems have long been used in the separation of zeotropic mixtures. As follows from the analysis of literature data, they save energy costs by up to 30%. Recently, it has been revealed that the use of such systems is possible, expedient and energetically advantageous for separating the close-boiling and azeotropic mixtures by extractive distillation (ED). The article considers the main approaches to the synthesis of distillation schemes, including systems with STMP: 1) a method based on the construction of a "superstructure"; 2) a method based on the concept of thermodynamically equivalent configurations; 3) an evolutionary algorithm; 4) a method based on the transformation of distillation scheme graphs. As the analysis of the literature has shown, the first three methods are sufficiently well developed only for the synthesis of distillation schemes with STMP to separate zeotropic mixtures. There are a relatively small number of publications that consider the generation of ED schemes with STMP based on the concept of thermodynamically equivalent configurations for distillation of specific binary mixtures. The only current system approach to the synthesis of ED schemes with coupled thermal and material flows for multicomponent mixtures is the method of graphs (algorithm 4). At present, the first step has been taken to implement it in the form of a computer program. Thus, the article presents the current state of the problem of synthesizing highly effective, energy-saving distillation technologies, including extractive distillation, based on the analysis of publications over the past 20-25 years.
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spelling doaj-art-600fa1f6cb284b8bae9dde92164507d82025-08-20T03:42:45ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752017-12-01126467010.32362/2410-6593-2017-12-6-46-70124SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCESE. А. Anokhina0А. V. Timoshenko1Moscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)Moscow Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)Approaching a hypothetical thermodynamically reversible process is one of the main directions of energy saving in distillation. In practice, this is achieved by the use of systems with coupled thermal and material flows (STMP). Such systems have long been used in the separation of zeotropic mixtures. As follows from the analysis of literature data, they save energy costs by up to 30%. Recently, it has been revealed that the use of such systems is possible, expedient and energetically advantageous for separating the close-boiling and azeotropic mixtures by extractive distillation (ED). The article considers the main approaches to the synthesis of distillation schemes, including systems with STMP: 1) a method based on the construction of a "superstructure"; 2) a method based on the concept of thermodynamically equivalent configurations; 3) an evolutionary algorithm; 4) a method based on the transformation of distillation scheme graphs. As the analysis of the literature has shown, the first three methods are sufficiently well developed only for the synthesis of distillation schemes with STMP to separate zeotropic mixtures. There are a relatively small number of publications that consider the generation of ED schemes with STMP based on the concept of thermodynamically equivalent configurations for distillation of specific binary mixtures. The only current system approach to the synthesis of ED schemes with coupled thermal and material flows for multicomponent mixtures is the method of graphs (algorithm 4). At present, the first step has been taken to implement it in the form of a computer program. Thus, the article presents the current state of the problem of synthesizing highly effective, energy-saving distillation technologies, including extractive distillation, based on the analysis of publications over the past 20-25 years.https://www.finechem-mirea.ru/jour/article/view/124distillationextractive distillationthermally coupled distillation columnssynthesis of distillation sequencesgraphsuperstructure
spellingShingle E. А. Anokhina
А. V. Timoshenko
SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES
Тонкие химические технологии
distillation
extractive distillation
thermally coupled distillation columns
synthesis of distillation sequences
graph
superstructure
title SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES
title_full SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES
title_fullStr SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES
title_full_unstemmed SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES
title_short SYNTHESIS OF THE THERMALLY COUPLED DISTILLATION SEQUENCES
title_sort synthesis of the thermally coupled distillation sequences
topic distillation
extractive distillation
thermally coupled distillation columns
synthesis of distillation sequences
graph
superstructure
url https://www.finechem-mirea.ru/jour/article/view/124
work_keys_str_mv AT eaanokhina synthesisofthethermallycoupleddistillationsequences
AT avtimoshenko synthesisofthethermallycoupleddistillationsequences