Programmable protein stabilization with language model-derived peptide guides

Abstract Dysregulated protein degradation via the ubiquitin-proteasomal pathway can induce numerous disease phenotypes, including cancer, neurodegeneration, and diabetes. While small molecule-based targeted protein degradation (TPD) and targeted protein stabilization (TPS) platforms can address this...

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Main Authors: Lauren Hong, Tianzheng Ye, Tian Z. Wang, Divya Srijay, Howard Liu, Lin Zhao, Rio Watson, Sophia Vincoff, Tianlai Chen, Kseniia Kholina, Shrey Goel, Matthew P. DeLisa, Pranam Chatterjee
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-58872-6
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author Lauren Hong
Tianzheng Ye
Tian Z. Wang
Divya Srijay
Howard Liu
Lin Zhao
Rio Watson
Sophia Vincoff
Tianlai Chen
Kseniia Kholina
Shrey Goel
Matthew P. DeLisa
Pranam Chatterjee
author_facet Lauren Hong
Tianzheng Ye
Tian Z. Wang
Divya Srijay
Howard Liu
Lin Zhao
Rio Watson
Sophia Vincoff
Tianlai Chen
Kseniia Kholina
Shrey Goel
Matthew P. DeLisa
Pranam Chatterjee
author_sort Lauren Hong
collection DOAJ
description Abstract Dysregulated protein degradation via the ubiquitin-proteasomal pathway can induce numerous disease phenotypes, including cancer, neurodegeneration, and diabetes. While small molecule-based targeted protein degradation (TPD) and targeted protein stabilization (TPS) platforms can address this dysregulation, they rely on structured and stable binding pockets, which do not exist to classically “undruggable” targets. Here, we expand the TPS target space by engineering “deubiquibodies” (duAbs) via fusion of computationally-designed peptide binders to the catalytic domain of the potent OTUB1 deubiquitinase. In human cells, duAbs effectively stabilize exogenous and endogenous proteins in a DUB-dependent manner. Using protein language models to generate target-binding peptides, we engineer duAbs to conformationally diverse target proteins, including key tumor suppressor proteins p53 and WEE1, and heavily-disordered fusion oncoproteins, such as PAX3::FOXO1. We further encapsulate p53-targeting duAbs as mRNA in lipid nanoparticles and demonstrate effective intracellular delivery, p53 stabilization, and apoptosis activation, motivating further in vivo translation.
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spelling doaj-art-5f511d12c5fa4aaf81c0ed756ca76c4f2025-08-20T03:18:42ZengNature PortfolioNature Communications2041-17232025-04-0116111010.1038/s41467-025-58872-6Programmable protein stabilization with language model-derived peptide guidesLauren Hong0Tianzheng Ye1Tian Z. Wang2Divya Srijay3Howard Liu4Lin Zhao5Rio Watson6Sophia Vincoff7Tianlai Chen8Kseniia Kholina9Shrey Goel10Matthew P. DeLisa11Pranam Chatterjee12Department of Biomedical Engineering, Duke UniversityRobert F. Smith School of Chemical and Biomolecular Engineering, Cornell UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityDepartment of Biomedical Engineering, Duke UniversityRobert F. Smith School of Chemical and Biomolecular Engineering, Cornell UniversityDepartment of Biomedical Engineering, Duke UniversityAbstract Dysregulated protein degradation via the ubiquitin-proteasomal pathway can induce numerous disease phenotypes, including cancer, neurodegeneration, and diabetes. While small molecule-based targeted protein degradation (TPD) and targeted protein stabilization (TPS) platforms can address this dysregulation, they rely on structured and stable binding pockets, which do not exist to classically “undruggable” targets. Here, we expand the TPS target space by engineering “deubiquibodies” (duAbs) via fusion of computationally-designed peptide binders to the catalytic domain of the potent OTUB1 deubiquitinase. In human cells, duAbs effectively stabilize exogenous and endogenous proteins in a DUB-dependent manner. Using protein language models to generate target-binding peptides, we engineer duAbs to conformationally diverse target proteins, including key tumor suppressor proteins p53 and WEE1, and heavily-disordered fusion oncoproteins, such as PAX3::FOXO1. We further encapsulate p53-targeting duAbs as mRNA in lipid nanoparticles and demonstrate effective intracellular delivery, p53 stabilization, and apoptosis activation, motivating further in vivo translation.https://doi.org/10.1038/s41467-025-58872-6
spellingShingle Lauren Hong
Tianzheng Ye
Tian Z. Wang
Divya Srijay
Howard Liu
Lin Zhao
Rio Watson
Sophia Vincoff
Tianlai Chen
Kseniia Kholina
Shrey Goel
Matthew P. DeLisa
Pranam Chatterjee
Programmable protein stabilization with language model-derived peptide guides
Nature Communications
title Programmable protein stabilization with language model-derived peptide guides
title_full Programmable protein stabilization with language model-derived peptide guides
title_fullStr Programmable protein stabilization with language model-derived peptide guides
title_full_unstemmed Programmable protein stabilization with language model-derived peptide guides
title_short Programmable protein stabilization with language model-derived peptide guides
title_sort programmable protein stabilization with language model derived peptide guides
url https://doi.org/10.1038/s41467-025-58872-6
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