Update of the risk assessment of brominated phenols and their derivatives in food

Abstract The European Commission asked EFSA to update its 2012 risk assessment on brominated phenols and their derivatives in food, focusing on five bromophenols and one derivative: 2,4,6‐tribromophenol (2,4,6‐TBP), 2,4‐dibromophenol (2,4‐DBP), 4‐bromophenol (4‐BP), 2,6‐dibromophenol (2,6‐DBP), tetr...

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Main Authors: EFSA Panel on Contaminants in the Food Chain (CONTAM), Helle Katrine Knutsen, Agneta Åkesson, Vasileios Bampidis, Margherita Bignami, Laurent Bodin, James Kevin Chipman, Gisela Degen, Antonio Hernández‐Jerez, Tim Hofer, Stefano Landi, Jean‐Charles Leblanc, Kyriaki Machera, Evangelia Ntzani, Guido Rychen, Salomon Sand, Tanja Schwerdtle, Katharina Vejdovszky, Barbara Viviani, Diane Benford, Andy Hart, Martin Rose, Henri Schroeder, Christiane Vleminckx, Martine Vrijheid, Eleni Gkimprixi, Eirini Kouloura, Francesca Riolo, Luisa Ramos Bordajandi, Christer Hogstrand
Format: Article
Language:English
Published: Wiley 2024-10-01
Series:EFSA Journal
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Online Access:https://doi.org/10.2903/j.efsa.2024.9034
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author EFSA Panel on Contaminants in the Food Chain (CONTAM)
Helle Katrine Knutsen
Agneta Åkesson
Vasileios Bampidis
Margherita Bignami
Laurent Bodin
James Kevin Chipman
Gisela Degen
Antonio Hernández‐Jerez
Tim Hofer
Stefano Landi
Jean‐Charles Leblanc
Kyriaki Machera
Evangelia Ntzani
Guido Rychen
Salomon Sand
Tanja Schwerdtle
Katharina Vejdovszky
Barbara Viviani
Diane Benford
Andy Hart
Martin Rose
Henri Schroeder
Christiane Vleminckx
Martine Vrijheid
Eleni Gkimprixi
Eirini Kouloura
Francesca Riolo
Luisa Ramos Bordajandi
Christer Hogstrand
author_facet EFSA Panel on Contaminants in the Food Chain (CONTAM)
Helle Katrine Knutsen
Agneta Åkesson
Vasileios Bampidis
Margherita Bignami
Laurent Bodin
James Kevin Chipman
Gisela Degen
Antonio Hernández‐Jerez
Tim Hofer
Stefano Landi
Jean‐Charles Leblanc
Kyriaki Machera
Evangelia Ntzani
Guido Rychen
Salomon Sand
Tanja Schwerdtle
Katharina Vejdovszky
Barbara Viviani
Diane Benford
Andy Hart
Martin Rose
Henri Schroeder
Christiane Vleminckx
Martine Vrijheid
Eleni Gkimprixi
Eirini Kouloura
Francesca Riolo
Luisa Ramos Bordajandi
Christer Hogstrand
author_sort EFSA Panel on Contaminants in the Food Chain (CONTAM)
collection DOAJ
description Abstract The European Commission asked EFSA to update its 2012 risk assessment on brominated phenols and their derivatives in food, focusing on five bromophenols and one derivative: 2,4,6‐tribromophenol (2,4,6‐TBP), 2,4‐dibromophenol (2,4‐DBP), 4‐bromophenol (4‐BP), 2,6‐dibromophenol (2,6‐DBP), tetrabrominated bisphenol S (TBBPS), tetrabromobisphenol S bismethyl ether (TBBPS‐BME). Based on the overall evidence, the CONTAM Panel considered in vivo genotoxicity of 2,4,6‐TBP to be unlikely. Effects in liver and kidney were considered as the critical effects of 2,4,6‐tribromophenol (2,4,6‐TBP) in studies in rats. A BMDL10 of 353 mg/kg body weight (bw) per day for kidney papillary necrosis in male rats was identified and was selected as the reference point for the risk characterisation. The derivation of a health‐based guidance value was not considered appropriate due to major limitations in the toxicological database. Instead, the margin of exposure (MOE) approach was applied to assess possible health concerns. Around 78,200 analytical results for 2,4,6‐TBP in food were used to estimate dietary exposure for the European population. Considering the resulting MOE values, all far above an MOE of 6000 that does not raise a health concern, and accounting for the uncertainties affecting the exposure and hazard assessments, the CONTAM Panel concluded with at least 95% probability that the current dietary exposure to 2,4,6‐TBP does not raise a health concern. Due to lack of occurrence data, no risk assessment could be performed for breastfed or formula‐fed infants. No risk characterisation could be performed for any of the other brominated phenols and derivatives included in the assessment, due to lack of data both on the toxicity and occurrence.
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spelling doaj-art-5ee2fd2252eb48fb9a5e2c34c1bd4d962025-08-20T01:58:45ZengWileyEFSA Journal1831-47322024-10-012210n/an/a10.2903/j.efsa.2024.9034Update of the risk assessment of brominated phenols and their derivatives in foodEFSA Panel on Contaminants in the Food Chain (CONTAM)Helle Katrine KnutsenAgneta ÅkessonVasileios BampidisMargherita BignamiLaurent BodinJames Kevin ChipmanGisela DegenAntonio Hernández‐JerezTim HoferStefano LandiJean‐Charles LeblancKyriaki MacheraEvangelia NtzaniGuido RychenSalomon SandTanja SchwerdtleKatharina VejdovszkyBarbara VivianiDiane BenfordAndy HartMartin RoseHenri SchroederChristiane VleminckxMartine VrijheidEleni GkimprixiEirini KoulouraFrancesca RioloLuisa Ramos BordajandiChrister HogstrandAbstract The European Commission asked EFSA to update its 2012 risk assessment on brominated phenols and their derivatives in food, focusing on five bromophenols and one derivative: 2,4,6‐tribromophenol (2,4,6‐TBP), 2,4‐dibromophenol (2,4‐DBP), 4‐bromophenol (4‐BP), 2,6‐dibromophenol (2,6‐DBP), tetrabrominated bisphenol S (TBBPS), tetrabromobisphenol S bismethyl ether (TBBPS‐BME). Based on the overall evidence, the CONTAM Panel considered in vivo genotoxicity of 2,4,6‐TBP to be unlikely. Effects in liver and kidney were considered as the critical effects of 2,4,6‐tribromophenol (2,4,6‐TBP) in studies in rats. A BMDL10 of 353 mg/kg body weight (bw) per day for kidney papillary necrosis in male rats was identified and was selected as the reference point for the risk characterisation. The derivation of a health‐based guidance value was not considered appropriate due to major limitations in the toxicological database. Instead, the margin of exposure (MOE) approach was applied to assess possible health concerns. Around 78,200 analytical results for 2,4,6‐TBP in food were used to estimate dietary exposure for the European population. Considering the resulting MOE values, all far above an MOE of 6000 that does not raise a health concern, and accounting for the uncertainties affecting the exposure and hazard assessments, the CONTAM Panel concluded with at least 95% probability that the current dietary exposure to 2,4,6‐TBP does not raise a health concern. Due to lack of occurrence data, no risk assessment could be performed for breastfed or formula‐fed infants. No risk characterisation could be performed for any of the other brominated phenols and derivatives included in the assessment, due to lack of data both on the toxicity and occurrence.https://doi.org/10.2903/j.efsa.2024.90342,4,6‐TBPbrominated phenolsfoodhuman exposureoccurrencerisk assessment
spellingShingle EFSA Panel on Contaminants in the Food Chain (CONTAM)
Helle Katrine Knutsen
Agneta Åkesson
Vasileios Bampidis
Margherita Bignami
Laurent Bodin
James Kevin Chipman
Gisela Degen
Antonio Hernández‐Jerez
Tim Hofer
Stefano Landi
Jean‐Charles Leblanc
Kyriaki Machera
Evangelia Ntzani
Guido Rychen
Salomon Sand
Tanja Schwerdtle
Katharina Vejdovszky
Barbara Viviani
Diane Benford
Andy Hart
Martin Rose
Henri Schroeder
Christiane Vleminckx
Martine Vrijheid
Eleni Gkimprixi
Eirini Kouloura
Francesca Riolo
Luisa Ramos Bordajandi
Christer Hogstrand
Update of the risk assessment of brominated phenols and their derivatives in food
EFSA Journal
2,4,6‐TBP
brominated phenols
food
human exposure
occurrence
risk assessment
title Update of the risk assessment of brominated phenols and their derivatives in food
title_full Update of the risk assessment of brominated phenols and their derivatives in food
title_fullStr Update of the risk assessment of brominated phenols and their derivatives in food
title_full_unstemmed Update of the risk assessment of brominated phenols and their derivatives in food
title_short Update of the risk assessment of brominated phenols and their derivatives in food
title_sort update of the risk assessment of brominated phenols and their derivatives in food
topic 2,4,6‐TBP
brominated phenols
food
human exposure
occurrence
risk assessment
url https://doi.org/10.2903/j.efsa.2024.9034
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