Alkali cation-π interactions in aqueous systems, modulating supramolecular stereoisomerism of nanoscopic metal-organic capsules
Abstract Contrary to common chemical intuition, cation-π interactions can persist in polar, aqueous reaction solutions, rather than in dry non-coordinative solvent systems. This account highlights how alkali ion-π interactions impart distinctive structure-influencing supramolecular forces that can b...
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| Main Authors: | Paul Wix, Swetanshu Tandon, Sebastien Vaesen, Kadri Karimu, Jennifer S. Mathieson, Kane Esien, Solveig Felton, Graeme W. Watson, Wolfgang Schmitt |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2024-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-024-54426-4 |
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