The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar

The purpose of the study was to determine the mechanical and ecotoxicological properties of mortars with differently shaped recycled PET plastics as a partial natural aggregate replacement and assess its environmental impact. Different methods were used for determining mechanical properties, while e...

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Main Authors: Maša Legan, Petra Štukovnik, Klementina Zupan, Andreja Žgajnar Gotvajn
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Recycling
Subjects:
Online Access:https://www.mdpi.com/2313-4321/10/1/8
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author Maša Legan
Petra Štukovnik
Klementina Zupan
Andreja Žgajnar Gotvajn
author_facet Maša Legan
Petra Štukovnik
Klementina Zupan
Andreja Žgajnar Gotvajn
author_sort Maša Legan
collection DOAJ
description The purpose of the study was to determine the mechanical and ecotoxicological properties of mortars with differently shaped recycled PET plastics as a partial natural aggregate replacement and assess its environmental impact. Different methods were used for determining mechanical properties, while ecotoxicity tests with two types of plants were performed for the assessment of the ecotoxicological potential of mortars. Results of strength tests revealed that PET in mortars increased 28-day compressive strength by up to 3% and decreased flexural strength by up to 14% compared to conventional mortar. Ultrasonic pulse velocity and dynamic modulus of elasticity were lower in PET mortars, while XRD and SEM-EDS showed fewer hydration products in PET mortars. Duckweed ecotoxicity test results revealed that frond growth inhibition values in PETS and conventional mortar leachate (100 g L<sup>−1</sup>) were around 50%, while root growth inhibition values did not exceed 40%. Mustard seed germination test results revealed root growth inhibition values in both mortar leachates were lower than 20%. Ecotoxicity tests showed that conventional and PET mortar were non-toxic to duckweed in aquatic environments and non-toxic to mustard seeds in terrestrial environments. Characterization of mortar leachates showed a significant increase in chloride, Ca, Si, and Ba content as potential causes for growth inhibition of both plants. Plastic waste reduction due to the potential use of PET in mortars confirmed that plastic waste could be completely eliminated and the global consumption of primary natural resources for concrete production reduced up to 4%. Such an approach could increase mortar sustainability.
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spelling doaj-art-5e73e451028f4abc9245ad2aec6e3e052025-08-20T02:03:32ZengMDPI AGRecycling2313-43212025-01-01101810.3390/recycling10010008The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of MortarMaša Legan0Petra Štukovnik1Klementina Zupan2Andreja Žgajnar Gotvajn3Faculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000 Ljubljana, SloveniaFaculty of Civil and Geodetic Engineering, University of Ljubljana, Jamova 2, 1000 Ljubljana, SloveniaFaculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000 Ljubljana, SloveniaFaculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000 Ljubljana, SloveniaThe purpose of the study was to determine the mechanical and ecotoxicological properties of mortars with differently shaped recycled PET plastics as a partial natural aggregate replacement and assess its environmental impact. Different methods were used for determining mechanical properties, while ecotoxicity tests with two types of plants were performed for the assessment of the ecotoxicological potential of mortars. Results of strength tests revealed that PET in mortars increased 28-day compressive strength by up to 3% and decreased flexural strength by up to 14% compared to conventional mortar. Ultrasonic pulse velocity and dynamic modulus of elasticity were lower in PET mortars, while XRD and SEM-EDS showed fewer hydration products in PET mortars. Duckweed ecotoxicity test results revealed that frond growth inhibition values in PETS and conventional mortar leachate (100 g L<sup>−1</sup>) were around 50%, while root growth inhibition values did not exceed 40%. Mustard seed germination test results revealed root growth inhibition values in both mortar leachates were lower than 20%. Ecotoxicity tests showed that conventional and PET mortar were non-toxic to duckweed in aquatic environments and non-toxic to mustard seeds in terrestrial environments. Characterization of mortar leachates showed a significant increase in chloride, Ca, Si, and Ba content as potential causes for growth inhibition of both plants. Plastic waste reduction due to the potential use of PET in mortars confirmed that plastic waste could be completely eliminated and the global consumption of primary natural resources for concrete production reduced up to 4%. Such an approach could increase mortar sustainability.https://www.mdpi.com/2313-4321/10/1/8cement mortarecotoxicological propertiesmechanical propertiesnatural aggregaterecycled PET plasticplastic waste reduction
spellingShingle Maša Legan
Petra Štukovnik
Klementina Zupan
Andreja Žgajnar Gotvajn
The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar
Recycling
cement mortar
ecotoxicological properties
mechanical properties
natural aggregate
recycled PET plastic
plastic waste reduction
title The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar
title_full The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar
title_fullStr The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar
title_full_unstemmed The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar
title_short The Impact of Recycled Polyethylene Terephthalate as Aggregate Replacement on Mechanical and Ecotoxicological Properties of Mortar
title_sort impact of recycled polyethylene terephthalate as aggregate replacement on mechanical and ecotoxicological properties of mortar
topic cement mortar
ecotoxicological properties
mechanical properties
natural aggregate
recycled PET plastic
plastic waste reduction
url https://www.mdpi.com/2313-4321/10/1/8
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