Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites

Adding heterogeneous fillers with high thermal conductivity (TC) to polymer has been recognized as an effective way to increase the effective thermal conductivity (ETC) of polymer composites. Extensive researches have been conducted on the ETC of composites with heterogeneous fillers. However, the h...

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Main Authors: Yuanyuan Zhang, Xiaojian Wang, Honghong Li, Xinru Fu, Simin Huang, Hao Zhou
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2024-11-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0013046&mi=cd
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author Yuanyuan Zhang
Xiaojian Wang
Honghong Li
Xinru Fu
Simin Huang
Hao Zhou
author_facet Yuanyuan Zhang
Xiaojian Wang
Honghong Li
Xinru Fu
Simin Huang
Hao Zhou
author_sort Yuanyuan Zhang
collection DOAJ
description Adding heterogeneous fillers with high thermal conductivity (TC) to polymer has been recognized as an effective way to increase the effective thermal conductivity (ETC) of polymer composites. Extensive researches have been conducted on the ETC of composites with heterogeneous fillers. However, the heat transfer enhancement mechanism of heterogeneous fillers remains unknown, and the combined effects of filler size, filler contact, interface thermal resistance (Rc) and other parameters on the ETC have not been explored. In this study, above combined effects are investigated. The results show that the filler contact and Rc are the key factors determining the ETC. The ETC of composite with filler contacts reaches 2.35 at filler content of 25%, which is 11.9% higher than that without filler contacts. The ETC also strongly depends on the R*c (dimensionless form of Rc) ratio (R*c1/R*c2) between two fillers, with it becoming asymmetrical when the amount of R*c(R*c1 + R*c2) is larger. The ETCs decrease with the increase of R*c1/R*c2 when the R*c1/R*c2<1, while they increase with R*c1/R*c2 when the R*c1/R*c2>1. When R*c1 + R*c2 is a constant, the ETC increases with the competing effects of R*c. The models with filler contacts exhibit higher accuracy than other classical models in calculating the ETC across the entire range of filler content.
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series eXPRESS Polymer Letters
spelling doaj-art-5e4b7bee06924db6af6f45c7b580bb092025-08-20T03:33:03ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2024-11-0118111065107610.3144/expresspolymlett.2024.82Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler compositesYuanyuan ZhangXiaojian WangHonghong LiXinru FuSimin HuangHao ZhouAdding heterogeneous fillers with high thermal conductivity (TC) to polymer has been recognized as an effective way to increase the effective thermal conductivity (ETC) of polymer composites. Extensive researches have been conducted on the ETC of composites with heterogeneous fillers. However, the heat transfer enhancement mechanism of heterogeneous fillers remains unknown, and the combined effects of filler size, filler contact, interface thermal resistance (Rc) and other parameters on the ETC have not been explored. In this study, above combined effects are investigated. The results show that the filler contact and Rc are the key factors determining the ETC. The ETC of composite with filler contacts reaches 2.35 at filler content of 25%, which is 11.9% higher than that without filler contacts. The ETC also strongly depends on the R*c (dimensionless form of Rc) ratio (R*c1/R*c2) between two fillers, with it becoming asymmetrical when the amount of R*c(R*c1 + R*c2) is larger. The ETCs decrease with the increase of R*c1/R*c2 when the R*c1/R*c2<1, while they increase with R*c1/R*c2 when the R*c1/R*c2>1. When R*c1 + R*c2 is a constant, the ETC increases with the competing effects of R*c. The models with filler contacts exhibit higher accuracy than other classical models in calculating the ETC across the entire range of filler content.http://www.expresspolymlett.com/letolt.php?file=EPL-0013046&mi=cd particle-reinforced composites conducting polymer analytical modeling finite element modeling validation interface
spellingShingle Yuanyuan Zhang
Xiaojian Wang
Honghong Li
Xinru Fu
Simin Huang
Hao Zhou
Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
eXPRESS Polymer Letters
particle-reinforced composites
conducting polymer
analytical modeling
finite element modeling
validation
interface
title Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
title_full Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
title_fullStr Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
title_full_unstemmed Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
title_short Effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
title_sort effects of filler contacts and interface thermal resistance on the thermal conductivity of heterogeneous spherical filler composites
topic particle-reinforced composites
conducting polymer
analytical modeling
finite element modeling
validation
interface
url http://www.expresspolymlett.com/letolt.php?file=EPL-0013046&mi=cd
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AT xiaojianwang effectsoffillercontactsandinterfacethermalresistanceonthethermalconductivityofheterogeneoussphericalfillercomposites
AT honghongli effectsoffillercontactsandinterfacethermalresistanceonthethermalconductivityofheterogeneoussphericalfillercomposites
AT xinrufu effectsoffillercontactsandinterfacethermalresistanceonthethermalconductivityofheterogeneoussphericalfillercomposites
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