Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I)
Crystallization of the title compound, fac-[ReBr(ppt-OMe)(CO)3] (ppt-OMe = C15H12N2OS), from CH2Cl2/n-pentane (1:5 v/v) at room temperature gave two polymorphs, which crystallize in monoclinic (P21/c; α form) and orthorhombic (Pna21; β form) space groups. The ReI complex molecules in either polymorp...
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International Union of Crystallography
2024-12-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989024010727 |
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| author | Yuki Matsuda Ryota Nakamura Yoshiki Ozawa Masaaki Abe |
| author_facet | Yuki Matsuda Ryota Nakamura Yoshiki Ozawa Masaaki Abe |
| author_sort | Yuki Matsuda |
| collection | DOAJ |
| description | Crystallization of the title compound, fac-[ReBr(ppt-OMe)(CO)3] (ppt-OMe = C15H12N2OS), from CH2Cl2/n-pentane (1:5 v/v) at room temperature gave two polymorphs, which crystallize in monoclinic (P21/c; α form) and orthorhombic (Pna21; β form) space groups. The ReI complex molecules in either polymorph adopt a six-coordinate octahedral geometry with three facially-oriented carbonyl ligands, one bromido ligand, and two nitrogen atoms from one chelating ligand ppt-OMe. In the crystal, both polymorph α and β form di-periodic sheet-like architectures supported by multiple hydrogen bonds. In polymorph α, two types of hydrogen bonds (C—H...O) are found while, in polymorph β, four types of hydrogen bonds (C—H...O and C—H...Br) exist. |
| format | Article |
| id | doaj-art-5e33d2efda80461390c634b85e655048 |
| institution | OA Journals |
| issn | 2056-9890 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-5e33d2efda80461390c634b85e6550482025-08-20T02:19:08ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902024-12-0180121283128710.1107/S2056989024010727jp2014Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I)Yuki Matsuda0Ryota Nakamura1Yoshiki Ozawa2Masaaki Abe3Graduate School of Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo, 678-1297, JapanGraduate School of Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo, 678-1297, JapanGraduate School of Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo, 678-1297, JapanGraduate School of Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo, 678-1297, JapanCrystallization of the title compound, fac-[ReBr(ppt-OMe)(CO)3] (ppt-OMe = C15H12N2OS), from CH2Cl2/n-pentane (1:5 v/v) at room temperature gave two polymorphs, which crystallize in monoclinic (P21/c; α form) and orthorhombic (Pna21; β form) space groups. The ReI complex molecules in either polymorph adopt a six-coordinate octahedral geometry with three facially-oriented carbonyl ligands, one bromido ligand, and two nitrogen atoms from one chelating ligand ppt-OMe. In the crystal, both polymorph α and β form di-periodic sheet-like architectures supported by multiple hydrogen bonds. In polymorph α, two types of hydrogen bonds (C—H...O) are found while, in polymorph β, four types of hydrogen bonds (C—H...O and C—H...Br) exist.https://journals.iucr.org/paper?S2056989024010727crystal structurepolymorphrhenium(i) complexchelating ligandhydrogen bondphotoluminescence |
| spellingShingle | Yuki Matsuda Ryota Nakamura Yoshiki Ozawa Masaaki Abe Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I) Acta Crystallographica Section E: Crystallographic Communications crystal structure polymorph rhenium(i) complex chelating ligand hydrogen bond photoluminescence |
| title | Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I) |
| title_full | Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I) |
| title_fullStr | Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I) |
| title_full_unstemmed | Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I) |
| title_short | Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N′]rhenium(I) |
| title_sort | crystal structures of two polymorphs for fac bromidotricarbonyl 4 4 methoxyphenyl 2 pyridin 2 yl thiazole κ2n n rhenium i |
| topic | crystal structure polymorph rhenium(i) complex chelating ligand hydrogen bond photoluminescence |
| url | https://journals.iucr.org/paper?S2056989024010727 |
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