DED Powder Modification for Single-Layer Coatings on High-Strength Steels

In the design of L-DED (laser-directed energy deposition) cladding processes, the chemical composition of the metallic powders is typically assumed to match that of the intended coating. However, during the deposition of the first layer, dilution with the substrate alters the weld metal composition,...

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Main Authors: Unai Garate, Enara Mardaras, Jon Arruabarrena, Garikoitz Artola, Aitzol Lamikiz, Luis Norberto López de Lacalle
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Journal of Manufacturing and Materials Processing
Subjects:
Online Access:https://www.mdpi.com/2504-4494/9/5/152
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author Unai Garate
Enara Mardaras
Jon Arruabarrena
Garikoitz Artola
Aitzol Lamikiz
Luis Norberto López de Lacalle
author_facet Unai Garate
Enara Mardaras
Jon Arruabarrena
Garikoitz Artola
Aitzol Lamikiz
Luis Norberto López de Lacalle
author_sort Unai Garate
collection DOAJ
description In the design of L-DED (laser-directed energy deposition) cladding processes, the chemical composition of the metallic powders is typically assumed to match that of the intended coating. However, during the deposition of the first layer, dilution with the substrate alters the weld metal composition, deviating from the nominal powder chemistry. Although the application of multiple layers can gradually reduce this dilution effect, it introduces additional complexity and processing time. This study proposes an alternative strategy to counteract substrate dilution from the very first deposited layer, eliminating the need for multilayer coatings. Specifically, to achieve a corrosion-resistant monolayer of AISI 316L stainless steel on a high-strength, quenched-and-tempered AISI 4140 steel substrate, a dilution-compensating alloy powder is added to the standard AISI 316L feedstock. Single-layer coatings, both with and without compensation, were evaluated in terms of chemical composition, microstructure, and corrosion resistance. The results show that unmodified coatings suffered a chromium depletion of approximately 2 wt.%, leading to a reduced pitting potential of Ep = 725 ± 6 mV in synthetic seawater. In contrast, the use of the compensation alloy preserved chromium content and significantly improved corrosion resistance, achieving a pitting potential of Ep = 890 ± 9 mV.
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spelling doaj-art-5e0eb3a7cf784e3ca2e361816cb92d9b2025-08-20T01:56:31ZengMDPI AGJournal of Manufacturing and Materials Processing2504-44942025-05-019515210.3390/jmmp9050152DED Powder Modification for Single-Layer Coatings on High-Strength SteelsUnai Garate0Enara Mardaras1Jon Arruabarrena2Garikoitz Artola3Aitzol Lamikiz4Luis Norberto López de Lacalle5MESHIND, Aliendalde 5, 48200 Durango, SpainAZTERLAN, Basque Research and Technology Alliance (BRTA), 48200 Durango, SpainAZTERLAN, Basque Research and Technology Alliance (BRTA), 48200 Durango, SpainAZTERLAN, Basque Research and Technology Alliance (BRTA), 48200 Durango, SpainAeronautics Advanced Manufacturing Centre, Department of Mechanical Engineering, University of the Basque Country, 48013 Bilbao, SpainAeronautics Advanced Manufacturing Centre, Department of Mechanical Engineering, University of the Basque Country, 48013 Bilbao, SpainIn the design of L-DED (laser-directed energy deposition) cladding processes, the chemical composition of the metallic powders is typically assumed to match that of the intended coating. However, during the deposition of the first layer, dilution with the substrate alters the weld metal composition, deviating from the nominal powder chemistry. Although the application of multiple layers can gradually reduce this dilution effect, it introduces additional complexity and processing time. This study proposes an alternative strategy to counteract substrate dilution from the very first deposited layer, eliminating the need for multilayer coatings. Specifically, to achieve a corrosion-resistant monolayer of AISI 316L stainless steel on a high-strength, quenched-and-tempered AISI 4140 steel substrate, a dilution-compensating alloy powder is added to the standard AISI 316L feedstock. Single-layer coatings, both with and without compensation, were evaluated in terms of chemical composition, microstructure, and corrosion resistance. The results show that unmodified coatings suffered a chromium depletion of approximately 2 wt.%, leading to a reduced pitting potential of Ep = 725 ± 6 mV in synthetic seawater. In contrast, the use of the compensation alloy preserved chromium content and significantly improved corrosion resistance, achieving a pitting potential of Ep = 890 ± 9 mV.https://www.mdpi.com/2504-4494/9/5/152L-DEDdilutioncompensation alloycorrosionpitting potentialAISI 316L
spellingShingle Unai Garate
Enara Mardaras
Jon Arruabarrena
Garikoitz Artola
Aitzol Lamikiz
Luis Norberto López de Lacalle
DED Powder Modification for Single-Layer Coatings on High-Strength Steels
Journal of Manufacturing and Materials Processing
L-DED
dilution
compensation alloy
corrosion
pitting potential
AISI 316L
title DED Powder Modification for Single-Layer Coatings on High-Strength Steels
title_full DED Powder Modification for Single-Layer Coatings on High-Strength Steels
title_fullStr DED Powder Modification for Single-Layer Coatings on High-Strength Steels
title_full_unstemmed DED Powder Modification for Single-Layer Coatings on High-Strength Steels
title_short DED Powder Modification for Single-Layer Coatings on High-Strength Steels
title_sort ded powder modification for single layer coatings on high strength steels
topic L-DED
dilution
compensation alloy
corrosion
pitting potential
AISI 316L
url https://www.mdpi.com/2504-4494/9/5/152
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AT enaramardaras dedpowdermodificationforsinglelayercoatingsonhighstrengthsteels
AT jonarruabarrena dedpowdermodificationforsinglelayercoatingsonhighstrengthsteels
AT garikoitzartola dedpowdermodificationforsinglelayercoatingsonhighstrengthsteels
AT aitzollamikiz dedpowdermodificationforsinglelayercoatingsonhighstrengthsteels
AT luisnorbertolopezdelacalle dedpowdermodificationforsinglelayercoatingsonhighstrengthsteels