Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine
Condensation of (CF3)2C=NLi with Cl3S3N3 in boiling CCl4 gives presumably the intermediate (CF3)2C=N–SN, which forms with excess (CF3)2C=NLi in the presence of moisture by a [2 + 4]-cycloaddition the isolated thiatriazine. A X-ray structure determination of the new compound as well as IR, NMR, and...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
1986-03-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9723 |
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| _version_ | 1850170613462728704 |
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| author | David J. Brauer Alois Haas Keith E. Peterman Matthias Rieland |
| author_facet | David J. Brauer Alois Haas Keith E. Peterman Matthias Rieland |
| author_sort | David J. Brauer |
| collection | DOAJ |
| description |
Condensation of (CF3)2C=NLi with Cl3S3N3 in boiling CCl4 gives presumably the intermediate (CF3)2C=N–SN, which forms with excess (CF3)2C=NLi in the presence of moisture by a [2 + 4]-cycloaddition the isolated thiatriazine. A X-ray structure determination of the new compound as well as IR, NMR, and mass spectra are provided.
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| format | Article |
| id | doaj-art-5ddc1020fdee4dbb81bb1b6cc82d3844 |
| institution | OA Journals |
| issn | 0009-4293 2673-2424 |
| language | deu |
| publishDate | 1986-03-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj-art-5ddc1020fdee4dbb81bb1b6cc82d38442025-08-20T02:20:26ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241986-03-0140310.2533/chimia.1986.99Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazineDavid J. Brauer0Alois Haas1Keith E. Peterman2Matthias Rieland3Fachbereich 9, Anorganische Chemie, Universität/Gesamthochschule, D-5600 Wuppertal 1Lehrstuhl für Anorganische Chemie II Ruhr-Universität Bochum Postfach 10 2148, D - 4630 Bochum 1 (Bundesrepublik Deutschland)York College of Pennsylvania, York, PA 17405 (USA)Lehrstuhl für Anorganische Chemie II Ruhr-Universität Bochum Postfach 10 2148, D - 4630 Bochum 1 (Bundesrepublik Deutschland) Condensation of (CF3)2C=NLi with Cl3S3N3 in boiling CCl4 gives presumably the intermediate (CF3)2C=N–SN, which forms with excess (CF3)2C=NLi in the presence of moisture by a [2 + 4]-cycloaddition the isolated thiatriazine. A X-ray structure determination of the new compound as well as IR, NMR, and mass spectra are provided. https://www.chimia.ch/chimia/article/view/9723 |
| spellingShingle | David J. Brauer Alois Haas Keith E. Peterman Matthias Rieland Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine CHIMIA |
| title | Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine |
| title_full | Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine |
| title_fullStr | Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine |
| title_full_unstemmed | Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine |
| title_short | Preparation, Structure, and Properties of 3,3,5,5-Tetrakis(trifluoromethyl)-4H-1λ4,2,4,6-thiatriazine |
| title_sort | preparation structure and properties of 3 3 5 5 tetrakis trifluoromethyl 4h 1λ4 2 4 6 thiatriazine |
| url | https://www.chimia.ch/chimia/article/view/9723 |
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