CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS
The co-crystal of succinic acid with imidazolidin-2-one was mechanochemically prepared and its structure was studied by powder and single-crystal X-ray diffraction. This compound crystallizes in the triclinic system with space group P-1. The molecular structure and crystal packing are stabilized...
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| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020-06-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=202002&vol=2&aid=5104 |
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| author | Gerzon E. Delgado Jines E. Contreras Gustavo Marroquin Joazaizulfazli Jamalis Hernando A. Camargo José A. Henao |
| author_facet | Gerzon E. Delgado Jines E. Contreras Gustavo Marroquin Joazaizulfazli Jamalis Hernando A. Camargo José A. Henao |
| author_sort | Gerzon E. Delgado |
| collection | DOAJ |
| description | The co-crystal of succinic acid with imidazolidin-2-one
was mechanochemically prepared and its structure was studied by powder
and single-crystal X-ray diffraction. This compound crystallizes in the
triclinic system with space group P-1. The molecular structure and crystal
packing are stabilized mainly by intermolecular O--H···O and N--H···O
hydrogen bonds interactions, forming a supramolecular assembly with bidimensional hydrogen bond networks along the [110] diagonal joined by
C
4
4(22) chains and R2
2(8) amide-acid dimers which running along the ba
plane. These hydrogen bonds contribute to the stabilization of the crystal
structure that packs with an efficiency of 69.1 % in a planar sheet structure
similarly to the even diacid co-crystals containing imidazolidin-2-one.
Hirshfeld surface analysis was used for visually analyzing intermolecular
interactions in the crystal structure. |
| format | Article |
| id | doaj-art-5d6ca07de7774d738b9a7994e2e4d392 |
| institution | OA Journals |
| issn | 1582-540X 1582-540X |
| language | English |
| publishDate | 2020-06-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-5d6ca07de7774d738b9a7994e2e4d3922025-08-20T02:13:19ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2020-06-01212195206CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSISGerzon E. Delgado0Jines E. Contreras1Gustavo Marroquin2Joazaizulfazli Jamalis3 Hernando A. Camargo4José A. Henao5University of the Andes, Faculty of Science, Department of Chemistry, Crystallography Laboratory, Mérida 5101, Venezuela University of the Andes, Faculty of Science, Department of Chemistry, Crystallography Laboratory, Mérida 5101, Venezuela Politecnic National Institute, Higher School of Chemical Engineering and Extractive Industries, Zacatenco 07738, México City, MéxicoUniversity of Technology Malaysia, Faculty of Science, Department of Chemistry, 81310 Johor Bahru, Johor, Malaysia Santo Tomás University, Faculty of Environmental Chemistry, Bucaramanga, ColombiaIndustrial University of Santander, Faculty of Sciences, School of Chemistry, Bucaramanga, Colombia The co-crystal of succinic acid with imidazolidin-2-one was mechanochemically prepared and its structure was studied by powder and single-crystal X-ray diffraction. This compound crystallizes in the triclinic system with space group P-1. The molecular structure and crystal packing are stabilized mainly by intermolecular O--H···O and N--H···O hydrogen bonds interactions, forming a supramolecular assembly with bidimensional hydrogen bond networks along the [110] diagonal joined by C 4 4(22) chains and R2 2(8) amide-acid dimers which running along the ba plane. These hydrogen bonds contribute to the stabilization of the crystal structure that packs with an efficiency of 69.1 % in a planar sheet structure similarly to the even diacid co-crystals containing imidazolidin-2-one. Hirshfeld surface analysis was used for visually analyzing intermolecular interactions in the crystal structure.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=202002&vol=2&aid=5104co-crystalshydrogen bonding patternsx-ray diffractionhirshfeld surface analysis |
| spellingShingle | Gerzon E. Delgado Jines E. Contreras Gustavo Marroquin Joazaizulfazli Jamalis Hernando A. Camargo José A. Henao CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry co-crystals hydrogen bonding patterns x-ray diffraction hirshfeld surface analysis |
| title | CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS |
| title_full | CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS |
| title_fullStr | CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS |
| title_full_unstemmed | CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS |
| title_short | CO-CRYSTAL OF SUCCINIC ACID WITH IMIDAZOLIDIN-2-ONE: CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS |
| title_sort | co crystal of succinic acid with imidazolidin 2 one crystal structure and hirshfeld surface analysis |
| topic | co-crystals hydrogen bonding patterns x-ray diffraction hirshfeld surface analysis |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=202002&vol=2&aid=5104 |
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