Analysis of Slow-Released Fertilisers as a Source of Microplastics

One of the main strategies for improving the efficiency of agricultural production is the use of fertilisers with slow or controlled release of nutrients, in which the granules of mineral fertilisers are covered with polymeric shells. The composition of the polymer coatings of mineral fertiliser gra...

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Main Authors: Vladimir Isakov, Elena Vlasova, Vladislav Forer, Jose Kenny, Sergey Lyulin
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Land
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Online Access:https://www.mdpi.com/2073-445X/14/1/38
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author Vladimir Isakov
Elena Vlasova
Vladislav Forer
Jose Kenny
Sergey Lyulin
author_facet Vladimir Isakov
Elena Vlasova
Vladislav Forer
Jose Kenny
Sergey Lyulin
author_sort Vladimir Isakov
collection DOAJ
description One of the main strategies for improving the efficiency of agricultural production is the use of fertilisers with slow or controlled release of nutrients, in which the granules of mineral fertilisers are covered with polymeric shells. The composition of the polymer coatings of mineral fertiliser granules with slow or controlled release of two widespread manufacturers and their ability to adsorb some heavy metal ions on their surface were examined in this study. It was found that the base polymers used to encapsulate the fertilisers studied are the co-polymer polyethylene–polyacrylic acid in the Brand A, and polyacrylamide, polyacrylic acid, and its esters in the Brand B fertiliser coating. The maximum adsorption rate of heavy metal ions on the surface of the polymer coatings with the rest of the mineral filler of Brand A and Brand B fertilisers was 54.64 and 28.90 mg/g for Cd(II) ions, 30.77 and 14.03 mg/g for Pb(II) ions, respectively. Therefore, the solution to the problem of increasing the efficiency of agricultural production through the use of fertilisers with slow or controlled release of nutrients leads to environmental pollution by microplastics remaining in the soil after fertiliser application, which are also capable of adsorbing from the soil various toxic pollutants.
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spelling doaj-art-5ce49802fa864ed08887eb87214d31bc2025-01-24T13:37:38ZengMDPI AGLand2073-445X2024-12-011413810.3390/land14010038Analysis of Slow-Released Fertilisers as a Source of MicroplasticsVladimir Isakov0Elena Vlasova1Vladislav Forer2Jose Kenny3Sergey Lyulin4Microplastics Research Center, Yaroslav-the-Wise Novgorod State University, Veliky Novgorod 173003, RussiaLaboratory № 21 of Polymer Spectroscopy, Branch of Petersburg Nuclear Physics Institute named by B. P. Konstantinov of National Research Centre «Kurchatov Institute»—Institute of Macromolecular Compounds, Saint Petersburg 199004, RussiaMicroplastics Research Center, Yaroslav-the-Wise Novgorod State University, Veliky Novgorod 173003, RussiaMicroplastics Research Center, Yaroslav-the-Wise Novgorod State University, Veliky Novgorod 173003, RussiaMicroplastics Research Center, Yaroslav-the-Wise Novgorod State University, Veliky Novgorod 173003, RussiaOne of the main strategies for improving the efficiency of agricultural production is the use of fertilisers with slow or controlled release of nutrients, in which the granules of mineral fertilisers are covered with polymeric shells. The composition of the polymer coatings of mineral fertiliser granules with slow or controlled release of two widespread manufacturers and their ability to adsorb some heavy metal ions on their surface were examined in this study. It was found that the base polymers used to encapsulate the fertilisers studied are the co-polymer polyethylene–polyacrylic acid in the Brand A, and polyacrylamide, polyacrylic acid, and its esters in the Brand B fertiliser coating. The maximum adsorption rate of heavy metal ions on the surface of the polymer coatings with the rest of the mineral filler of Brand A and Brand B fertilisers was 54.64 and 28.90 mg/g for Cd(II) ions, 30.77 and 14.03 mg/g for Pb(II) ions, respectively. Therefore, the solution to the problem of increasing the efficiency of agricultural production through the use of fertilisers with slow or controlled release of nutrients leads to environmental pollution by microplastics remaining in the soil after fertiliser application, which are also capable of adsorbing from the soil various toxic pollutants.https://www.mdpi.com/2073-445X/14/1/38microplasticsslow- or controlled-release fertiliserspolymeric coatingCd(II) ionsPb(II) ionssustainable agriculture
spellingShingle Vladimir Isakov
Elena Vlasova
Vladislav Forer
Jose Kenny
Sergey Lyulin
Analysis of Slow-Released Fertilisers as a Source of Microplastics
Land
microplastics
slow- or controlled-release fertilisers
polymeric coating
Cd(II) ions
Pb(II) ions
sustainable agriculture
title Analysis of Slow-Released Fertilisers as a Source of Microplastics
title_full Analysis of Slow-Released Fertilisers as a Source of Microplastics
title_fullStr Analysis of Slow-Released Fertilisers as a Source of Microplastics
title_full_unstemmed Analysis of Slow-Released Fertilisers as a Source of Microplastics
title_short Analysis of Slow-Released Fertilisers as a Source of Microplastics
title_sort analysis of slow released fertilisers as a source of microplastics
topic microplastics
slow- or controlled-release fertilisers
polymeric coating
Cd(II) ions
Pb(II) ions
sustainable agriculture
url https://www.mdpi.com/2073-445X/14/1/38
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AT elenavlasova analysisofslowreleasedfertilisersasasourceofmicroplastics
AT vladislavforer analysisofslowreleasedfertilisersasasourceofmicroplastics
AT josekenny analysisofslowreleasedfertilisersasasourceofmicroplastics
AT sergeylyulin analysisofslowreleasedfertilisersasasourceofmicroplastics