Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)

Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incor...

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Main Authors: Vakkoottil Sivadasan Abhisha, Krishanagegham Sidharathan Sisanth, Sabu Thomas, Ranimol Stephen
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2023-10-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0012569&mi=cd
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author Vakkoottil Sivadasan Abhisha
Krishanagegham Sidharathan Sisanth
Sabu Thomas
Ranimol Stephen
author_facet Vakkoottil Sivadasan Abhisha
Krishanagegham Sidharathan Sisanth
Sabu Thomas
Ranimol Stephen
author_sort Vakkoottil Sivadasan Abhisha
collection DOAJ
description Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equations
format Article
id doaj-art-5bcbab7085424130884b2ffcc1d7e83f
institution Kabale University
issn 1788-618X
language English
publishDate 2023-10-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-5bcbab7085424130884b2ffcc1d7e83f2025-08-20T03:56:18ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2023-10-0117101070108010.3144/expresspolymlett.2023.80Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)Vakkoottil Sivadasan AbhishaKrishanagegham Sidharathan SisanthSabu ThomasRanimol StephenConductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equationshttp://www.expresspolymlett.com/letolt.php?file=EPL-0012569&mi=cdrubberpolymer compositesnanomaterials crosslinking curing elastomer filler natural rubber vulcanizationcarbon black
spellingShingle Vakkoottil Sivadasan Abhisha
Krishanagegham Sidharathan Sisanth
Sabu Thomas
Ranimol Stephen
Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
eXPRESS Polymer Letters
rubber
polymer composites
nanomaterials
crosslinking
curing
elastomer
filler
natural rubber
vulcanization
carbon black
title Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
title_full Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
title_fullStr Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
title_full_unstemmed Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
title_short Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
title_sort kinetic studies on the transport behavior of hybrid filler incorporated natural rubber nr
topic rubber
polymer composites
nanomaterials
crosslinking
curing
elastomer
filler
natural rubber
vulcanization
carbon black
url http://www.expresspolymlett.com/letolt.php?file=EPL-0012569&mi=cd
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AT krishanageghamsidharathansisanth kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr
AT sabuthomas kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr
AT ranimolstephen kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr