Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion

Magnesium ammonium phosphate (MgNH4PO4·6H2O) is a phosphorus-containing blockage commonly found in sewage treatment pipelines. In order to study its suppression effect on the methane/coal dust composite explosion, magnesium ammonium phosphate was subjected to mechanized chemical modification to prep...

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Main Authors: Li LIU, Xiangbao MENG, Jihe CHEN, Yansong ZHANG, Tong WANG, Lei SHI, Yang WU, Qiyan WU
Format: Article
Language:zho
Published: Editorial Office of Safety in Coal Mines 2025-03-01
Series:Meikuang Anquan
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Online Access:https://www.mkaqzz.com/cn/article/doi/10.13347/j.cnki.mkaq.20231627
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author Li LIU
Xiangbao MENG
Jihe CHEN
Yansong ZHANG
Tong WANG
Lei SHI
Yang WU
Qiyan WU
author_facet Li LIU
Xiangbao MENG
Jihe CHEN
Yansong ZHANG
Tong WANG
Lei SHI
Yang WU
Qiyan WU
author_sort Li LIU
collection DOAJ
description Magnesium ammonium phosphate (MgNH4PO4·6H2O) is a phosphorus-containing blockage commonly found in sewage treatment pipelines. In order to study its suppression effect on the methane/coal dust composite explosion, magnesium ammonium phosphate was subjected to mechanized chemical modification to prepare well-dispersed magnesium ammonium phosphate powder (S-MAP). The improved Hartmann flame propagation system was used to investigate the suppression effect of different mass fractions of S-MAP(20%, 40%, 60%, 80%)on the flame propagation of the methane/coal dust composite explosion. The experimental results indicate that the addition of S-MAP can significantly reduce flame propagation speed, height, and brightness. With the increase of S-MAP addition ratio, the flame propagation height decreased from over 900 mm to 134 mm, and the average flame propagation speed decreased from 8.76 mm/ms to 0.51 mm/s. When the S-MAP addition ratio reached 80%, the entire flame propagation process only presented small flames, which could suppress the propagation of flames; in terms of explosion suppression mechanism, S-MAP decomposition can absorb a large amount of heat, thereby exerting a cooling effect. The intermediate produced by thermal decomposition of S-MAP can adsorb explosion free radicals to block the explosion chain reaction, thereby exerting the effect of adsorbing explosive free radicals. The thermal decomposition products of S-MAP can dilute the concentration of oxygen and combustible gases in the explosion space, and at the same time, the thermal decomposition products can adsorb on the surface of coal dust to isolate the transfer of oxygen and heat, thereby exerting a suffocating effect. The coupling effect of the three suppresses the propagation process of methane/coal dust explosion flames.
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institution Kabale University
issn 1003-496X
language zho
publishDate 2025-03-01
publisher Editorial Office of Safety in Coal Mines
record_format Article
series Meikuang Anquan
spelling doaj-art-5b91b1d6d86649e2b707e2f7a42e03db2025-08-20T03:42:40ZzhoEditorial Office of Safety in Coal MinesMeikuang Anquan1003-496X2025-03-01563758310.13347/j.cnki.mkaq.20231627lyMKAQ20231627Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosionLi LIU0Xiangbao MENG1Jihe CHEN2Yansong ZHANG3Tong WANG4Lei SHI5Yang WU6Qiyan WU7College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaCollege of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaChina Academy of Safety Science and Technology, Beijing 100012, ChinaCollege of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaCollege of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaCollege of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaCollege of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaCollege of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, ChinaMagnesium ammonium phosphate (MgNH4PO4·6H2O) is a phosphorus-containing blockage commonly found in sewage treatment pipelines. In order to study its suppression effect on the methane/coal dust composite explosion, magnesium ammonium phosphate was subjected to mechanized chemical modification to prepare well-dispersed magnesium ammonium phosphate powder (S-MAP). The improved Hartmann flame propagation system was used to investigate the suppression effect of different mass fractions of S-MAP(20%, 40%, 60%, 80%)on the flame propagation of the methane/coal dust composite explosion. The experimental results indicate that the addition of S-MAP can significantly reduce flame propagation speed, height, and brightness. With the increase of S-MAP addition ratio, the flame propagation height decreased from over 900 mm to 134 mm, and the average flame propagation speed decreased from 8.76 mm/ms to 0.51 mm/s. When the S-MAP addition ratio reached 80%, the entire flame propagation process only presented small flames, which could suppress the propagation of flames; in terms of explosion suppression mechanism, S-MAP decomposition can absorb a large amount of heat, thereby exerting a cooling effect. The intermediate produced by thermal decomposition of S-MAP can adsorb explosion free radicals to block the explosion chain reaction, thereby exerting the effect of adsorbing explosive free radicals. The thermal decomposition products of S-MAP can dilute the concentration of oxygen and combustible gases in the explosion space, and at the same time, the thermal decomposition products can adsorb on the surface of coal dust to isolate the transfer of oxygen and heat, thereby exerting a suffocating effect. The coupling effect of the three suppresses the propagation process of methane/coal dust explosion flames.https://www.mkaqzz.com/cn/article/doi/10.13347/j.cnki.mkaq.20231627magnesium ammonium phosphatesilicamethane/coal dust composite explosionflame propagationsuppression mechanism
spellingShingle Li LIU
Xiangbao MENG
Jihe CHEN
Yansong ZHANG
Tong WANG
Lei SHI
Yang WU
Qiyan WU
Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion
Meikuang Anquan
magnesium ammonium phosphate
silica
methane/coal dust composite explosion
flame propagation
suppression mechanism
title Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion
title_full Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion
title_fullStr Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion
title_full_unstemmed Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion
title_short Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion
title_sort study on suppression effect and mechanisms of phosphorus containing recycling substance on flame propagation of methane coal dust composite explosion
topic magnesium ammonium phosphate
silica
methane/coal dust composite explosion
flame propagation
suppression mechanism
url https://www.mkaqzz.com/cn/article/doi/10.13347/j.cnki.mkaq.20231627
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