Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS

As a zero-carbon fuel, ammonia can be directly employed in its liquid form. However, its unique physical and chemical properties pose challenges to its application in engines. The direct injection of liquid ammonia is considered a promising technique for internal combustion engines, yet its combusti...

Full description

Saved in:
Bibliographic Details
Main Authors: Ziwei Huang, Haiou Wang, Qian Meng, Kun Luo, Jianren Fan
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/18/9/2228
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849312828450668544
author Ziwei Huang
Haiou Wang
Qian Meng
Kun Luo
Jianren Fan
author_facet Ziwei Huang
Haiou Wang
Qian Meng
Kun Luo
Jianren Fan
author_sort Ziwei Huang
collection DOAJ
description As a zero-carbon fuel, ammonia can be directly employed in its liquid form. However, its unique physical and chemical properties pose challenges to its application in engines. The direct injection of liquid ammonia is considered a promising technique for internal combustion engines, yet its combustion behavior is still not well understood. In this work, the combustion characteristics of liquid ammonia direct injection under high-pressure conditions were investigated using direct numerical simulation (DNS) in a Eulerian–Lagrangian framework. The ammonia spray was injected via a circular nozzle and underwent combustion under high-temperature and high-pressure conditions, resulting in complex turbulent spray combustion. It was found that the peaks of mass fraction of important species, heat release rate, and gaseous temperature increase with increasing axial distance, and the peaks shifted to richer mixtures. The distribution of scalar dissipation rate at various locations is nearly log-normal. The budget analysis of species transport equations shows that the reaction term is much larger than the diffusion term, suggesting that auto-ignition plays a predominant role in turbulent ammonia spray flame stabilization. It can be observed that both non-premixed and premixed combustion modes co-exist in the ammonia spray combustion. Moreover, the contribution of premixed combustion becomes more significant as the axial distance increases.
format Article
id doaj-art-5b2d87db05004db6bc521873b1b89f6d
institution Kabale University
issn 1996-1073
language English
publishDate 2025-04-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj-art-5b2d87db05004db6bc521873b1b89f6d2025-08-20T03:52:57ZengMDPI AGEnergies1996-10732025-04-01189222810.3390/en18092228Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNSZiwei Huang0Haiou Wang1Qian Meng2Kun Luo3Jianren Fan4State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, ChinaState Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, ChinaState Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, ChinaState Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, ChinaState Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, ChinaAs a zero-carbon fuel, ammonia can be directly employed in its liquid form. However, its unique physical and chemical properties pose challenges to its application in engines. The direct injection of liquid ammonia is considered a promising technique for internal combustion engines, yet its combustion behavior is still not well understood. In this work, the combustion characteristics of liquid ammonia direct injection under high-pressure conditions were investigated using direct numerical simulation (DNS) in a Eulerian–Lagrangian framework. The ammonia spray was injected via a circular nozzle and underwent combustion under high-temperature and high-pressure conditions, resulting in complex turbulent spray combustion. It was found that the peaks of mass fraction of important species, heat release rate, and gaseous temperature increase with increasing axial distance, and the peaks shifted to richer mixtures. The distribution of scalar dissipation rate at various locations is nearly log-normal. The budget analysis of species transport equations shows that the reaction term is much larger than the diffusion term, suggesting that auto-ignition plays a predominant role in turbulent ammonia spray flame stabilization. It can be observed that both non-premixed and premixed combustion modes co-exist in the ammonia spray combustion. Moreover, the contribution of premixed combustion becomes more significant as the axial distance increases.https://www.mdpi.com/1996-1073/18/9/2228direct numerical simulationliquid ammoniaflame structurecombustion modes
spellingShingle Ziwei Huang
Haiou Wang
Qian Meng
Kun Luo
Jianren Fan
Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS
Energies
direct numerical simulation
liquid ammonia
flame structure
combustion modes
title Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS
title_full Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS
title_fullStr Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS
title_full_unstemmed Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS
title_short Combustion Characteristics of Liquid Ammonia Direct Injection Under High-Pressure Conditions Using DNS
title_sort combustion characteristics of liquid ammonia direct injection under high pressure conditions using dns
topic direct numerical simulation
liquid ammonia
flame structure
combustion modes
url https://www.mdpi.com/1996-1073/18/9/2228
work_keys_str_mv AT ziweihuang combustioncharacteristicsofliquidammoniadirectinjectionunderhighpressureconditionsusingdns
AT haiouwang combustioncharacteristicsofliquidammoniadirectinjectionunderhighpressureconditionsusingdns
AT qianmeng combustioncharacteristicsofliquidammoniadirectinjectionunderhighpressureconditionsusingdns
AT kunluo combustioncharacteristicsofliquidammoniadirectinjectionunderhighpressureconditionsusingdns
AT jianrenfan combustioncharacteristicsofliquidammoniadirectinjectionunderhighpressureconditionsusingdns