Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation

In this work a new method for the fabrication of Ag@SiO2 nanoparticles have been proposed that is completely different from Stober method. Ag nanoparticles were synthesized using microwave irradiation. polyvinylpyrrolidone was used as stabilizer and capping agent, 3-Aminopropyltriethoxysilane as fun...

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Main Authors: M. Karimipour, S. Mostoufirad, M. Molaei, H. Rezvani Nikabadi, A. Ghasempour Nesheli
Format: Article
Language:English
Published: Sumy State University 2016-10-01
Series:Журнал нано- та електронної фізики
Subjects:
Online Access:http://jnep.sumdu.edu.ua/download/numbers/2016/3/articles/Proof_jnep_2016_V8_03020.pdf
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author M. Karimipour
S. Mostoufirad
M. Molaei
H. Rezvani Nikabadi
A. Ghasempour Nesheli
author_facet M. Karimipour
S. Mostoufirad
M. Molaei
H. Rezvani Nikabadi
A. Ghasempour Nesheli
author_sort M. Karimipour
collection DOAJ
description In this work a new method for the fabrication of Ag@SiO2 nanoparticles have been proposed that is completely different from Stober method. Ag nanoparticles were synthesized using microwave irradiation. polyvinylpyrrolidone was used as stabilizer and capping agent, 3-Aminopropyltriethoxysilane as functionalizer of silver particles in fully ethanol solution. The Ag nanoparticles were used subsequently without any subtraction and treatment in the preparation of Ag@SiO2 core-shell nanoparticles. UV-Vis spectroscopy shows a characteristic plasmon peak at 400 nm and 430 nm for Ag nanoparticles and Ag@SiO2 core-shells. Transmission electron microscope images show that Ag nanoparticles have the average size of 10 nm. It is also depicted that SiO2 shell structure was formed uniformly with the average size of 10 nm. The application of 3-Aminopropyltriethoxysilane in the preparation of core-shells yields single Ag core structure.
format Article
id doaj-art-5aa7e960e1f54e67bb1d5bc8520f3fae
institution OA Journals
issn 2077-6772
language English
publishDate 2016-10-01
publisher Sumy State University
record_format Article
series Журнал нано- та електронної фізики
spelling doaj-art-5aa7e960e1f54e67bb1d5bc8520f3fae2025-08-20T01:57:25ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722016-10-018303020-103020-410.21272/jnep.8(3).03020Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave IrradiationM. Karimipour0S. Mostoufirad1M. Molaei2H. Rezvani Nikabadi3A. Ghasempour Nesheli4Department of Physics, Vali-e-Asr University of Rafsanjan, 77139-36417 Rafsanjan, IranDepartment of Physics, Vali-e-Asr University of Rafsanjan, 77139-36417 Rafsanjan, IranDepartment of Physics, Vali-e-Asr University of Rafsanjan, 77139-36417 Rafsanjan, IranFaculty of science, International University of Imam Reza, Mashhad, IranDepartment of Physics, Shiraz Branch, Islamic Azad University, Shiraz, IranIn this work a new method for the fabrication of Ag@SiO2 nanoparticles have been proposed that is completely different from Stober method. Ag nanoparticles were synthesized using microwave irradiation. polyvinylpyrrolidone was used as stabilizer and capping agent, 3-Aminopropyltriethoxysilane as functionalizer of silver particles in fully ethanol solution. The Ag nanoparticles were used subsequently without any subtraction and treatment in the preparation of Ag@SiO2 core-shell nanoparticles. UV-Vis spectroscopy shows a characteristic plasmon peak at 400 nm and 430 nm for Ag nanoparticles and Ag@SiO2 core-shells. Transmission electron microscope images show that Ag nanoparticles have the average size of 10 nm. It is also depicted that SiO2 shell structure was formed uniformly with the average size of 10 nm. The application of 3-Aminopropyltriethoxysilane in the preparation of core-shells yields single Ag core structure.http://jnep.sumdu.edu.ua/download/numbers/2016/3/articles/Proof_jnep_2016_V8_03020.pdfAg@SiO2MicrowaveAPTSPolyvinylpyrrolidonePlasmo
spellingShingle M. Karimipour
S. Mostoufirad
M. Molaei
H. Rezvani Nikabadi
A. Ghasempour Nesheli
Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation
Журнал нано- та електронної фізики
Ag@SiO2
Microwave
APTS
Polyvinylpyrrolidone
Plasmo
title Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation
title_full Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation
title_fullStr Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation
title_full_unstemmed Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation
title_short Free Reducing Agent, One Pot, and Two Steps Synthesis of Ag@SiO2 Core-shells using Microwave Irradiation
title_sort free reducing agent one pot and two steps synthesis of ag sio2 core shells using microwave irradiation
topic Ag@SiO2
Microwave
APTS
Polyvinylpyrrolidone
Plasmo
url http://jnep.sumdu.edu.ua/download/numbers/2016/3/articles/Proof_jnep_2016_V8_03020.pdf
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AT mmolaei freereducingagentonepotandtwostepssynthesisofagsio2coreshellsusingmicrowaveirradiation
AT hrezvaninikabadi freereducingagentonepotandtwostepssynthesisofagsio2coreshellsusingmicrowaveirradiation
AT aghasempournesheli freereducingagentonepotandtwostepssynthesisofagsio2coreshellsusingmicrowaveirradiation