The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass

The relationship between pH and heavy metal ion sorption by the biomass of two algal species was studied under controlled experimental conditions. It was observed that increasing heavy metal ion sorption by algal biomass with pH mainly arose from a change in algal cell properties, provided that the...

Full description

Saved in:
Bibliographic Details
Main Authors: Ying-Zhong Tang, Karina Y.H. Gin, M.A. Aziz
Format: Article
Language:English
Published: SAGE Publishing 2003-07-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361703771953587
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832544683980488704
author Ying-Zhong Tang
Karina Y.H. Gin
M.A. Aziz
author_facet Ying-Zhong Tang
Karina Y.H. Gin
M.A. Aziz
author_sort Ying-Zhong Tang
collection DOAJ
description The relationship between pH and heavy metal ion sorption by the biomass of two algal species was studied under controlled experimental conditions. It was observed that increasing heavy metal ion sorption by algal biomass with pH mainly arose from a change in algal cell properties, provided that the pH was below the level where the heavy metal ions started to precipitate. A drastic increase in metal ion sorption capacity (‘inflection point’) was observed at pH 4.5 for the algal biomass used in the study. All the experimental observations on the mutual effects between pH and metal sorption for four heavy metal ions (Cd 2+ , Cu 2+ , Pb 2+ and Zn 2+ ) and two algal species suggested that the mutual effects between pH and heavy metal ion sorption can be explained in terms of ion exchange and coulombic attraction between the heavy metal ions and the algal biomass. A ‘positive feedback’ was also suggested for the mutual effects between pH and heavy metal ion removal at higher initial pH levels, where the sorption of heavy metal ions may enhance their hydrolysis.
format Article
id doaj-art-5a87e81db7cb48dab8932fb7c2597caf
institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2003-07-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-5a87e81db7cb48dab8932fb7c2597caf2025-02-03T10:07:35ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382003-07-012110.1260/026361703771953587The Relationship between pH and Heavy Metal Ion Sorption by Algal BiomassYing-Zhong Tang0Karina Y.H. Gin1M.A. Aziz2 Tropical Marine Science Institute, National University of Singapore, 14 Kent Ridge Road, Singapore 119223 Department of Civil Engineering, National University of Singapore, 1 Engineering Drive 2, Engineering Block E1A, #07-03, Singapore 117576 Department of Civil Engineering, National University of Singapore, 1 Engineering Drive 2, Engineering Block E1A, #07-03, Singapore 117576The relationship between pH and heavy metal ion sorption by the biomass of two algal species was studied under controlled experimental conditions. It was observed that increasing heavy metal ion sorption by algal biomass with pH mainly arose from a change in algal cell properties, provided that the pH was below the level where the heavy metal ions started to precipitate. A drastic increase in metal ion sorption capacity (‘inflection point’) was observed at pH 4.5 for the algal biomass used in the study. All the experimental observations on the mutual effects between pH and metal sorption for four heavy metal ions (Cd 2+ , Cu 2+ , Pb 2+ and Zn 2+ ) and two algal species suggested that the mutual effects between pH and heavy metal ion sorption can be explained in terms of ion exchange and coulombic attraction between the heavy metal ions and the algal biomass. A ‘positive feedback’ was also suggested for the mutual effects between pH and heavy metal ion removal at higher initial pH levels, where the sorption of heavy metal ions may enhance their hydrolysis.https://doi.org/10.1260/026361703771953587
spellingShingle Ying-Zhong Tang
Karina Y.H. Gin
M.A. Aziz
The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass
Adsorption Science & Technology
title The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass
title_full The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass
title_fullStr The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass
title_full_unstemmed The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass
title_short The Relationship between pH and Heavy Metal Ion Sorption by Algal Biomass
title_sort relationship between ph and heavy metal ion sorption by algal biomass
url https://doi.org/10.1260/026361703771953587
work_keys_str_mv AT yingzhongtang therelationshipbetweenphandheavymetalionsorptionbyalgalbiomass
AT karinayhgin therelationshipbetweenphandheavymetalionsorptionbyalgalbiomass
AT maaziz therelationshipbetweenphandheavymetalionsorptionbyalgalbiomass
AT yingzhongtang relationshipbetweenphandheavymetalionsorptionbyalgalbiomass
AT karinayhgin relationshipbetweenphandheavymetalionsorptionbyalgalbiomass
AT maaziz relationshipbetweenphandheavymetalionsorptionbyalgalbiomass