Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels

The effect of storage temperature and duration on the stability of oleogels produced from sunflower wax, polyglycerol behenic acid ester, and fully hydrogenated palm-based monoacylglycerols in relation to their physical and microstructure properties was investigated. The oleogel kept at 5 °C exhibi...

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Main Authors: M.H. Saw, W.H. Lim, C.B. Yeoh, E. Hishamuddin, S. Kanagaratnam, N.A. Mohd Hassim, N.H. Ismail, C.P. Tan
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 2024-12-01
Series:Grasas y Aceites
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Online Access:https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/2198
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author M.H. Saw
W.H. Lim
C.B. Yeoh
E. Hishamuddin
S. Kanagaratnam
N.A. Mohd Hassim
N.H. Ismail
C.P. Tan
author_facet M.H. Saw
W.H. Lim
C.B. Yeoh
E. Hishamuddin
S. Kanagaratnam
N.A. Mohd Hassim
N.H. Ismail
C.P. Tan
author_sort M.H. Saw
collection DOAJ
description The effect of storage temperature and duration on the stability of oleogels produced from sunflower wax, polyglycerol behenic acid ester, and fully hydrogenated palm-based monoacylglycerols in relation to their physical and microstructure properties was investigated. The oleogel kept at 5 °C exhibited the highest hardness due to the formation of more crystals. Polyglycerol behenic acid ester oleogels showed phase separation and amorphous peaks at high temperatures, indicating instability and lack of crystalline structure. sunflower wax oleogels remained stable and exhibited βʹ polymorphs with needle-like crystal structures. The palm-based monoacylglycerol oleogels displayed a complex pattern of crystalline and amorphous behavior, with large crystals and voids, resulting in lower stability despite their high hardness. The findings from microscopy and XRD observations highlight the critical role of a gelator type in determining the properties and stability of oleogels. This knowledge enhances our understanding of the behavior of superolein oleogels, which is essential for their application in various industries.
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1988-4214
language English
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publisher Consejo Superior de Investigaciones Científicas
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spelling doaj-art-5a2e5eb82d0c45d5b0d786f51dbd9ef82025-08-20T02:26:24ZengConsejo Superior de Investigaciones CientíficasGrasas y Aceites0017-34951988-42142024-12-0175410.3989/gya.1200232.2198Effects of storage temperature and duration on physical and microstructure properties of superolein oleogelsM.H. Saw0W.H. Lim1C.B. Yeoh2E. Hishamuddin3S. Kanagaratnam4N.A. Mohd Hassim5N.H. Ismail6C.P. Tan7Malaysian Palm Oil BoardMalaysian Palm Oil BoardMalaysian Palm Oil BoardMalaysian Palm Oil BoardMalaysian Palm Oil BoardMalaysian Palm Oil Board Malaysian Palm Oil BoardUniversiti Putra Malaysia The effect of storage temperature and duration on the stability of oleogels produced from sunflower wax, polyglycerol behenic acid ester, and fully hydrogenated palm-based monoacylglycerols in relation to their physical and microstructure properties was investigated. The oleogel kept at 5 °C exhibited the highest hardness due to the formation of more crystals. Polyglycerol behenic acid ester oleogels showed phase separation and amorphous peaks at high temperatures, indicating instability and lack of crystalline structure. sunflower wax oleogels remained stable and exhibited βʹ polymorphs with needle-like crystal structures. The palm-based monoacylglycerol oleogels displayed a complex pattern of crystalline and amorphous behavior, with large crystals and voids, resulting in lower stability despite their high hardness. The findings from microscopy and XRD observations highlight the critical role of a gelator type in determining the properties and stability of oleogels. This knowledge enhances our understanding of the behavior of superolein oleogels, which is essential for their application in various industries. https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/2198MonoacylglycerolPolyglycerol esterSunflower waxSuperolein oleogel
spellingShingle M.H. Saw
W.H. Lim
C.B. Yeoh
E. Hishamuddin
S. Kanagaratnam
N.A. Mohd Hassim
N.H. Ismail
C.P. Tan
Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
Grasas y Aceites
Monoacylglycerol
Polyglycerol ester
Sunflower wax
Superolein oleogel
title Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
title_full Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
title_fullStr Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
title_full_unstemmed Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
title_short Effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
title_sort effects of storage temperature and duration on physical and microstructure properties of superolein oleogels
topic Monoacylglycerol
Polyglycerol ester
Sunflower wax
Superolein oleogel
url https://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/2198
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