Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones
The electrochemical behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones has been investigated at dme and gc electrodes in buffer solutions of pH 2.0, 4.0, 6.0, 8.0 and 10.0 using dc polarography and cyclic voltammetry and coulometry. The compounds exhibit...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/598905 |
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| author | V. Nagaraju R. Sreenivasulu P. Venkata Ramana |
| author_facet | V. Nagaraju R. Sreenivasulu P. Venkata Ramana |
| author_sort | V. Nagaraju |
| collection | DOAJ |
| description | The electrochemical behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones has been investigated at dme and gc electrodes in buffer solutions of pH 2.0, 4.0, 6.0, 8.0 and 10.0 using dc polarography and cyclic voltammetry and coulometry. The compounds exhibit one well defined wave in the entire pH range of study. The process is irreversible and diffusion controlled. Controlled potential electrolysis indicates the involvement of four electrons in the reduction process. The effect of solvent, cations and anions, temperature and substitutents on the mechanism of reduction has been studied. Based on the results obtained the mechanism of reduction has been suggested. |
| format | Article |
| id | doaj-art-59e403c66055471f94b0473acc377e96 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-59e403c66055471f94b0473acc377e962025-02-03T05:48:09ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01941864187410.1155/2012/598905Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-onesV. Nagaraju0R. Sreenivasulu1P. Venkata Ramana2Department of Chemistry, Sri Krishnadevaraya University, Anantapur–515 003, Andhra Pradesh, IndiaDepartment of Chemistry, Sri Krishnadevaraya University, Anantapur–515 003, Andhra Pradesh, IndiaDepartment of Chemistry, Sri Krishnadevaraya University, Anantapur–515 003, Andhra Pradesh, IndiaThe electrochemical behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones has been investigated at dme and gc electrodes in buffer solutions of pH 2.0, 4.0, 6.0, 8.0 and 10.0 using dc polarography and cyclic voltammetry and coulometry. The compounds exhibit one well defined wave in the entire pH range of study. The process is irreversible and diffusion controlled. Controlled potential electrolysis indicates the involvement of four electrons in the reduction process. The effect of solvent, cations and anions, temperature and substitutents on the mechanism of reduction has been studied. Based on the results obtained the mechanism of reduction has been suggested.http://dx.doi.org/10.1155/2012/598905 |
| spellingShingle | V. Nagaraju R. Sreenivasulu P. Venkata Ramana Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones E-Journal of Chemistry |
| title | Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones |
| title_full | Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones |
| title_fullStr | Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones |
| title_full_unstemmed | Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones |
| title_short | Electrochemical Behaviour of N′-(p-toluenesulphonyl)-3-methyl-4-(4′-substituted arylhydrazono) pyrazolin-5-ones |
| title_sort | electrochemical behaviour of n p toluenesulphonyl 3 methyl 4 4 substituted arylhydrazono pyrazolin 5 ones |
| url | http://dx.doi.org/10.1155/2012/598905 |
| work_keys_str_mv | AT vnagaraju electrochemicalbehaviourofnptoluenesulphonyl3methyl44substitutedarylhydrazonopyrazolin5ones AT rsreenivasulu electrochemicalbehaviourofnptoluenesulphonyl3methyl44substitutedarylhydrazonopyrazolin5ones AT pvenkataramana electrochemicalbehaviourofnptoluenesulphonyl3methyl44substitutedarylhydrazonopyrazolin5ones |