On modification of eutectic cast iron graphite

It has been shown that elementary crystalline cells of graphite and basic products of iron modification do not correspond to the principle of structural and dimensional correspondence of Dankov –Konobeevsky. Modifying elements Al, Ca, Mg, Ba, Ce increase the phase tension melt‑graphite by binding su...

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Main Authors: E. I. Marukovich, V. Yu. Stetsenko, A. V. Stetsenko
Format: Article
Language:English
Published: Belarusian National Technical University 2023-01-01
Series:Литьë и металлургия
Subjects:
Online Access:https://lim.bntu.by/jour/article/view/3504
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author E. I. Marukovich
V. Yu. Stetsenko
A. V. Stetsenko
author_facet E. I. Marukovich
V. Yu. Stetsenko
A. V. Stetsenko
author_sort E. I. Marukovich
collection DOAJ
description It has been shown that elementary crystalline cells of graphite and basic products of iron modification do not correspond to the principle of structural and dimensional correspondence of Dankov –Konobeevsky. Modifying elements Al, Ca, Mg, Ba, Ce increase the phase tension melt‑graphite by binding surface‑active oxygen and sulfur. Modifying cast iron eutectic graphite is a nanostructured process in which modifying elements refine elemental graphite nanocrystals from adsorbed oxygen and sulfur atoms. This contributes to an increase in the concentration of graphite nuclei upon solidification of the cast iron melt. The modification reduces the concentration of dissolved hydrogen, which increases the effectiveness of the modifying effect. Reduced concentrations of demodifying surface‑active elements, melt degassing, increased heat removal contribute to increasing the degree of branching and compactness of graphite dendrites during iron crystallization. The strongest modifying element of eutectic cast iron graphite is magnesium.
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publisher Belarusian National Technical University
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series Литьë и металлургия
spelling doaj-art-5998d8a63d1645a1b8cbebf748ff8a302025-08-20T03:59:49ZengBelarusian National Technical UniversityЛитьë и металлургия1683-60652414-04062023-01-0104192310.21122/1683-6065-2022-4-19-233387On modification of eutectic cast iron graphiteE. I. Marukovich0V. Yu. Stetsenko1A. V. Stetsenko2Association of Foundrymen and Metallurgists of BelarusAssociation of Foundrymen and Metallurgists of BelarusBelarusian‑Russian UniversityIt has been shown that elementary crystalline cells of graphite and basic products of iron modification do not correspond to the principle of structural and dimensional correspondence of Dankov –Konobeevsky. Modifying elements Al, Ca, Mg, Ba, Ce increase the phase tension melt‑graphite by binding surface‑active oxygen and sulfur. Modifying cast iron eutectic graphite is a nanostructured process in which modifying elements refine elemental graphite nanocrystals from adsorbed oxygen and sulfur atoms. This contributes to an increase in the concentration of graphite nuclei upon solidification of the cast iron melt. The modification reduces the concentration of dissolved hydrogen, which increases the effectiveness of the modifying effect. Reduced concentrations of demodifying surface‑active elements, melt degassing, increased heat removal contribute to increasing the degree of branching and compactness of graphite dendrites during iron crystallization. The strongest modifying element of eutectic cast iron graphite is magnesium.https://lim.bntu.by/jour/article/view/3504modificationcast ironmagnesiumeutectic graphitenanocrystalsoxygensulfurhydrogenadsorption
spellingShingle E. I. Marukovich
V. Yu. Stetsenko
A. V. Stetsenko
On modification of eutectic cast iron graphite
Литьë и металлургия
modification
cast iron
magnesium
eutectic graphite
nanocrystals
oxygen
sulfur
hydrogen
adsorption
title On modification of eutectic cast iron graphite
title_full On modification of eutectic cast iron graphite
title_fullStr On modification of eutectic cast iron graphite
title_full_unstemmed On modification of eutectic cast iron graphite
title_short On modification of eutectic cast iron graphite
title_sort on modification of eutectic cast iron graphite
topic modification
cast iron
magnesium
eutectic graphite
nanocrystals
oxygen
sulfur
hydrogen
adsorption
url https://lim.bntu.by/jour/article/view/3504
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AT vyustetsenko onmodificationofeutecticcastirongraphite
AT avstetsenko onmodificationofeutecticcastirongraphite