Flexible fuel cells: A prospective review

With the widespread of wearable electronics in healthcare, military and entertainment sectors, flexible power sources have attracted great attention, among which flexible fuel cells are relatively young compared with flexible batteries, supercapacitors and energy harvesters. Fuel cell is well known...

Full description

Saved in:
Bibliographic Details
Main Authors: Yifei Wang, Xinhai Xu, Guangzhong Dong, Mingming Zhang, Kui Jiao, Dennis Y.C. Leung
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Energy Reviews
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772970224000324
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850256797871374336
author Yifei Wang
Xinhai Xu
Guangzhong Dong
Mingming Zhang
Kui Jiao
Dennis Y.C. Leung
author_facet Yifei Wang
Xinhai Xu
Guangzhong Dong
Mingming Zhang
Kui Jiao
Dennis Y.C. Leung
author_sort Yifei Wang
collection DOAJ
description With the widespread of wearable electronics in healthcare, military and entertainment sectors, flexible power sources have attracted great attention, among which flexible fuel cells are relatively young compared with flexible batteries, supercapacitors and energy harvesters. Fuel cell is well known for its uninterrupted operation, high energy density and instant refueling ability, which is especially advantageous for long-term and outdoor missions. To date, existing flexible fuel cell studies can be classified into three major types based on their electrolyte and catalyst material, namely the flexible polymer electrolyte membrane fuel cell (PEMFC), membraneless fuel cell (MFC) and biofuel cell (BFC). The flexible PEMFC generally employs hydrogen as fuel so that a power density of hundreds of mW cm−2 can be achieved. Relevant research efforts are mainly paid to the replacement of conventional rigid cell components with flexible substitutes. Moreover, novel cell structures such as ultrathin cell and tubular cell have also been proposed. However, the flexible hydrogen storage is still a research gap. The flexible MFC has a much wider choice of fuel such as methanol, ethanol and formate, but the power output is limited to dozens of mW cm−2 due to more sluggish fuel oxidation. To circumvent the demand of pumping, porous materials with capillary action are preferred as cell substrate, such as cellulose paper and cotton thread, which can absorb electrolyte solution passively. Nevertheless, the capillary flow rate is not controllable at the moment. As for the flexible BFC, it is primarily targeted for epidermal applications in order to utilize natural organic materials in human body fluid. Benefited from this, the flexible BFC can have the simplest cell structure of two bioelectrodes only, which can be integrated onto contact lenses, tattoos, clothes, etc. However, the complex organic fuel oxidation as well as the mild electrolyte pH have greatly restricted its power density to μW cm−2 level. In this work, a comprehensive review on existing flexible fuel cell studies is provided, including cell structure, material, performance together with their advantages and disadvantages. Based on this, solid conclusions are made on their development trend and future perspectives are presented as well.
format Article
id doaj-art-5941cbde734d4729ac626e2a3fd1f8e1
institution OA Journals
issn 2772-9702
language English
publishDate 2024-12-01
publisher Elsevier
record_format Article
series Energy Reviews
spelling doaj-art-5941cbde734d4729ac626e2a3fd1f8e12025-08-20T01:56:34ZengElsevierEnergy Reviews2772-97022024-12-013410009910.1016/j.enrev.2024.100099Flexible fuel cells: A prospective reviewYifei Wang0Xinhai Xu1Guangzhong Dong2Mingming Zhang3Kui Jiao4Dennis Y.C. Leung5School of Mechanical Engineering and Automation, Harbin Institute of Technology, Shenzhen, ChinaSchool of Mechanical Engineering and Automation, Harbin Institute of Technology, Shenzhen, ChinaSchool of Mechanical Engineering and Automation, Harbin Institute of Technology, Shenzhen, ChinaSchool of Mechanical Engineering and Automation, Harbin Institute of Technology, Shenzhen, China; Corresponding author.State Key Laboratory of Engines, Tianjin University, Tianjin, China; Corresponding author.Department of Mechanical Engineering, The University of Hong Kong, Hong Kong, China; Corresponding author.With the widespread of wearable electronics in healthcare, military and entertainment sectors, flexible power sources have attracted great attention, among which flexible fuel cells are relatively young compared with flexible batteries, supercapacitors and energy harvesters. Fuel cell is well known for its uninterrupted operation, high energy density and instant refueling ability, which is especially advantageous for long-term and outdoor missions. To date, existing flexible fuel cell studies can be classified into three major types based on their electrolyte and catalyst material, namely the flexible polymer electrolyte membrane fuel cell (PEMFC), membraneless fuel cell (MFC) and biofuel cell (BFC). The flexible PEMFC generally employs hydrogen as fuel so that a power density of hundreds of mW cm−2 can be achieved. Relevant research efforts are mainly paid to the replacement of conventional rigid cell components with flexible substitutes. Moreover, novel cell structures such as ultrathin cell and tubular cell have also been proposed. However, the flexible hydrogen storage is still a research gap. The flexible MFC has a much wider choice of fuel such as methanol, ethanol and formate, but the power output is limited to dozens of mW cm−2 due to more sluggish fuel oxidation. To circumvent the demand of pumping, porous materials with capillary action are preferred as cell substrate, such as cellulose paper and cotton thread, which can absorb electrolyte solution passively. Nevertheless, the capillary flow rate is not controllable at the moment. As for the flexible BFC, it is primarily targeted for epidermal applications in order to utilize natural organic materials in human body fluid. Benefited from this, the flexible BFC can have the simplest cell structure of two bioelectrodes only, which can be integrated onto contact lenses, tattoos, clothes, etc. However, the complex organic fuel oxidation as well as the mild electrolyte pH have greatly restricted its power density to μW cm−2 level. In this work, a comprehensive review on existing flexible fuel cell studies is provided, including cell structure, material, performance together with their advantages and disadvantages. Based on this, solid conclusions are made on their development trend and future perspectives are presented as well.http://www.sciencedirect.com/science/article/pii/S2772970224000324Flexible fuel cellPolymer electrolyte membrane fuel cellMembraneless fuel cellBiofuel cellWearable electronics
spellingShingle Yifei Wang
Xinhai Xu
Guangzhong Dong
Mingming Zhang
Kui Jiao
Dennis Y.C. Leung
Flexible fuel cells: A prospective review
Energy Reviews
Flexible fuel cell
Polymer electrolyte membrane fuel cell
Membraneless fuel cell
Biofuel cell
Wearable electronics
title Flexible fuel cells: A prospective review
title_full Flexible fuel cells: A prospective review
title_fullStr Flexible fuel cells: A prospective review
title_full_unstemmed Flexible fuel cells: A prospective review
title_short Flexible fuel cells: A prospective review
title_sort flexible fuel cells a prospective review
topic Flexible fuel cell
Polymer electrolyte membrane fuel cell
Membraneless fuel cell
Biofuel cell
Wearable electronics
url http://www.sciencedirect.com/science/article/pii/S2772970224000324
work_keys_str_mv AT yifeiwang flexiblefuelcellsaprospectivereview
AT xinhaixu flexiblefuelcellsaprospectivereview
AT guangzhongdong flexiblefuelcellsaprospectivereview
AT mingmingzhang flexiblefuelcellsaprospectivereview
AT kuijiao flexiblefuelcellsaprospectivereview
AT dennisycleung flexiblefuelcellsaprospectivereview