The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO

Doping semiconductors with transition metals is a prominent strategy for modifying their magnetic properties, offering numerous innovative applications. This study explores the synergistic effect of iron oxide on the structural and magnetic properties of iron-doped zinc oxide (ZnO) nanoparticles. By...

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Main Authors: Adenilson F. dos Santos, Angela Marta da Silva, Thaís Karine de Lima, Noelio O. Dantas, Marcio A. Correa, Anielle Christine A. Silva
Format: Article
Language:English
Published: Elsevier 2025-10-01
Series:Next Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949822825005659
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author Adenilson F. dos Santos
Angela Marta da Silva
Thaís Karine de Lima
Noelio O. Dantas
Marcio A. Correa
Anielle Christine A. Silva
author_facet Adenilson F. dos Santos
Angela Marta da Silva
Thaís Karine de Lima
Noelio O. Dantas
Marcio A. Correa
Anielle Christine A. Silva
author_sort Adenilson F. dos Santos
collection DOAJ
description Doping semiconductors with transition metals is a prominent strategy for modifying their magnetic properties, offering numerous innovative applications. This study explores the synergistic effect of iron oxide on the structural and magnetic properties of iron-doped zinc oxide (ZnO) nanoparticles. By introducing high iron (Fe) ion concentrations, we reveal a remarkable interplay between the nanostructure and magnetism. The presence of iron significantly alters the crystalline structure, morphology, and magnetic characteristics of ZnO. Comprehensive analyses using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS) reveal that secondary magnetic phases, such as maghemite, form at specific iron concentrations, leading to a transition to a ferromagnetic state. This discovery highlights the synergistic effect of iron oxide, offering more profound insights into magnetic doping in semiconductors. It opens new avenues for applications in spintronic devices and nanoscale magnetic data storage. The findings mark a significant advancement in nanomagnetism, highlighting the potential of Fe-doped ZnO/Fe2O3 nanocomposites as a versatile platform for developing next-generation magnetic devices.
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spelling doaj-art-57effbf88dc24da5bfa18634d161c8372025-08-20T03:41:56ZengElsevierNext Materials2949-82282025-10-01910104710.1016/j.nxmate.2025.101047The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnOAdenilson F. dos Santos0Angela Marta da Silva1Thaís Karine de Lima2Noelio O. Dantas3Marcio A. Correa4Anielle Christine A. Silva5Programa de Pós-Graduação em Física, Physics Institute, Federal University of Alagoas, Maceió, Alagoas, Brazil; Strategic Materials Laboratory, Physics Institute, Federal University of Alagoas, Maceió, Alagoas, BrazilMagnetic and Semiconductor Nanostructures Group, Physics Institute, Federal University of Rio Grande do Norte, Natal, Rio Grande do Norte, BrazilChemistry Institute, Federal University of Uberlândia, Uberlândia, Minas Gerais, BrazilPrograma de Pós-Graduação em Física, Physics Institute, Federal University of Alagoas, Maceió, Alagoas, BrazilMagnetic and Semiconductor Nanostructures Group, Physics Institute, Federal University of Rio Grande do Norte, Natal, Rio Grande do Norte, BrazilPrograma de Pós-Graduação em Física, Physics Institute, Federal University of Alagoas, Maceió, Alagoas, Brazil; Strategic Materials Laboratory, Physics Institute, Federal University of Alagoas, Maceió, Alagoas, Brazil; Rede Nordeste de Biotecnologia (RENORBIO), Chemistry Institute, Federal University of Alagoas, Maceió, Alagoas 57072-900, Brazil; Physics Institute, Federal University of Uberlândia, Uberlândia, Minas Gerais, Brazil; Corresponding author at: Physics Institute, Federal University of Uberlândia, Uberlândia, Minas Gerais, Brazil.Doping semiconductors with transition metals is a prominent strategy for modifying their magnetic properties, offering numerous innovative applications. This study explores the synergistic effect of iron oxide on the structural and magnetic properties of iron-doped zinc oxide (ZnO) nanoparticles. By introducing high iron (Fe) ion concentrations, we reveal a remarkable interplay between the nanostructure and magnetism. The presence of iron significantly alters the crystalline structure, morphology, and magnetic characteristics of ZnO. Comprehensive analyses using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS) reveal that secondary magnetic phases, such as maghemite, form at specific iron concentrations, leading to a transition to a ferromagnetic state. This discovery highlights the synergistic effect of iron oxide, offering more profound insights into magnetic doping in semiconductors. It opens new avenues for applications in spintronic devices and nanoscale magnetic data storage. The findings mark a significant advancement in nanomagnetism, highlighting the potential of Fe-doped ZnO/Fe2O3 nanocomposites as a versatile platform for developing next-generation magnetic devices.http://www.sciencedirect.com/science/article/pii/S2949822825005659ZnODopingSaturationNanomagnetismNanocompositeFe-doped ZnO/Fe2O3
spellingShingle Adenilson F. dos Santos
Angela Marta da Silva
Thaís Karine de Lima
Noelio O. Dantas
Marcio A. Correa
Anielle Christine A. Silva
The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO
Next Materials
ZnO
Doping
Saturation
Nanomagnetism
Nanocomposite
Fe-doped ZnO/Fe2O3
title The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO
title_full The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO
title_fullStr The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO
title_full_unstemmed The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO
title_short The effect of iron oxide synergism on the structural and magnetic properties of iron-doped ZnO
title_sort effect of iron oxide synergism on the structural and magnetic properties of iron doped zno
topic ZnO
Doping
Saturation
Nanomagnetism
Nanocomposite
Fe-doped ZnO/Fe2O3
url http://www.sciencedirect.com/science/article/pii/S2949822825005659
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