Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden
The autoxidation of cuprous complexes with monodentate nitrogeneous bases (L) has been studied spectrophotometric-ally and by following the O2-consumption with an oxygen sensor. The proposed mechanism includes two different oxygenated species. CuL2O2+ is less reactive than CuL3O2+ by many powers of...
Saved in:
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1969-11-01
|
| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/8806 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849311366896156672 |
|---|---|
| author | A. Zuberbühler |
| author_facet | A. Zuberbühler |
| author_sort | A. Zuberbühler |
| collection | DOAJ |
| description |
The autoxidation of cuprous complexes with monodentate nitrogeneous bases (L) has been studied spectrophotometric-ally and by following the O2-consumption with an oxygen sensor. The proposed mechanism includes two different oxygenated species. CuL2O2+ is less reactive than CuL3O2+ by many powers of magnitude which is explained by the fact that CuL2O2+ has a coordination number of 3, specific for CuI, whereas CuL3O2+ may gain quasiplanar, CuII specific, symmetry by molecular vibration.
|
| format | Article |
| id | doaj-art-572b029b3a5f426faa700ab024e6f5b7 |
| institution | Kabale University |
| issn | 0009-4293 2673-2424 |
| language | deu |
| publishDate | 1969-11-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj-art-572b029b3a5f426faa700ab024e6f5b72025-08-20T03:53:27ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241969-11-01231110.2533/chimia.1969.416Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen StickstoffligandenA. Zuberbühler0Institut für anorganische Chemie der Universität Basel The autoxidation of cuprous complexes with monodentate nitrogeneous bases (L) has been studied spectrophotometric-ally and by following the O2-consumption with an oxygen sensor. The proposed mechanism includes two different oxygenated species. CuL2O2+ is less reactive than CuL3O2+ by many powers of magnitude which is explained by the fact that CuL2O2+ has a coordination number of 3, specific for CuI, whereas CuL3O2+ may gain quasiplanar, CuII specific, symmetry by molecular vibration. https://www.chimia.ch/chimia/article/view/8806 |
| spellingShingle | A. Zuberbühler Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden CHIMIA |
| title | Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden |
| title_full | Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden |
| title_fullStr | Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden |
| title_full_unstemmed | Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden |
| title_short | Autoxidation von CuI-Komplexen, II: Mechanismus der Autoxidation von Komplexen mit einzähnigen Stickstoffliganden |
| title_sort | autoxidation von cui komplexen ii mechanismus der autoxidation von komplexen mit einzahnigen stickstoffliganden |
| url | https://www.chimia.ch/chimia/article/view/8806 |
| work_keys_str_mv | AT azuberbuhler autoxidationvoncuikomplexeniimechanismusderautoxidationvonkomplexenmiteinzahnigenstickstoffliganden |