The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase.
In this work reactions of the hexaammine ruthenium(II) - [Ru(NH3)6]Cl2 and “ruthenium red” -[Ru3O2(NH3)14]Cl6 • 4Н2О chlorides in the water alkaline solution at 190˚С (autoclave) and in the solid phase are investigated. The mechanism of restoration of the ruthenium ion by inside sphere ammonia up to...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2008-06-01
|
| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1503 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850027726643134464 |
|---|---|
| author | E. V. Fesik V. V. Grebnev G. D. Malchikov |
| author_facet | E. V. Fesik V. V. Grebnev G. D. Malchikov |
| author_sort | E. V. Fesik |
| collection | DOAJ |
| description | In this work reactions of the hexaammine ruthenium(II) - [Ru(NH3)6]Cl2 and “ruthenium red” -[Ru3O2(NH3)14]Cl6 • 4Н2О chlorides in the water alkaline solution at 190˚С (autoclave) and in the solid phase are investigated. The mechanism of restoration of the ruthenium ion by inside sphere ammonia up to the metal condition is offered. |
| format | Article |
| id | doaj-art-56a00f84fbf44bd6bfeb6b50df37f328 |
| institution | DOAJ |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2008-06-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-56a00f84fbf44bd6bfeb6b50df37f3282025-08-20T03:00:03ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752008-06-013373771498The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase.E. V. Fesik0V. V. Grebnev1G. D. Malchikov2Самарский государственный аэрокосмический университет им. акад. С.П. КоролеваСамарский государственный аэрокосмический университет им. акад. С.П. КоролеваСамарский государственный аэрокосмический университет им. акад. С.П. КоролеваIn this work reactions of the hexaammine ruthenium(II) - [Ru(NH3)6]Cl2 and “ruthenium red” -[Ru3O2(NH3)14]Cl6 • 4Н2О chlorides in the water alkaline solution at 190˚С (autoclave) and in the solid phase are investigated. The mechanism of restoration of the ruthenium ion by inside sphere ammonia up to the metal condition is offered.https://www.finechem-mirea.ru/jour/article/view/1503 |
| spellingShingle | E. V. Fesik V. V. Grebnev G. D. Malchikov The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase. Тонкие химические технологии |
| title | The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase. |
| title_full | The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase. |
| title_fullStr | The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase. |
| title_full_unstemmed | The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase. |
| title_short | The thermolysis of ruthenium(II, III) ammine complexes in water solutions at the increased temperatures and the solid phase. |
| title_sort | thermolysis of ruthenium ii iii ammine complexes in water solutions at the increased temperatures and the solid phase |
| url | https://www.finechem-mirea.ru/jour/article/view/1503 |
| work_keys_str_mv | AT evfesik thethermolysisofrutheniumiiiiiamminecomplexesinwatersolutionsattheincreasedtemperaturesandthesolidphase AT vvgrebnev thethermolysisofrutheniumiiiiiamminecomplexesinwatersolutionsattheincreasedtemperaturesandthesolidphase AT gdmalchikov thethermolysisofrutheniumiiiiiamminecomplexesinwatersolutionsattheincreasedtemperaturesandthesolidphase AT evfesik thermolysisofrutheniumiiiiiamminecomplexesinwatersolutionsattheincreasedtemperaturesandthesolidphase AT vvgrebnev thermolysisofrutheniumiiiiiamminecomplexesinwatersolutionsattheincreasedtemperaturesandthesolidphase AT gdmalchikov thermolysisofrutheniumiiiiiamminecomplexesinwatersolutionsattheincreasedtemperaturesandthesolidphase |