A TMO-ZnO Heterojunction-Based Sensor for Transformer Defect Detection: A DFT Study

The gas adsorption and sensing properties of a transition metal oxide (TMO)-ZnO heterojunction-based sensor for H<sub>2</sub>, CO, and C<sub>2</sub>H<sub>4</sub> are analyzed. It is found that CuO, Ag<sub>2</sub>O, and Cu<sub>2</sub>O stabl...

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Bibliographic Details
Main Authors: Jingyi Yan, Weiju Dai, Dexu Zou, Haoruo Sun, Chao Tang, Yingang Gui
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/11/856
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Summary:The gas adsorption and sensing properties of a transition metal oxide (TMO)-ZnO heterojunction-based sensor for H<sub>2</sub>, CO, and C<sub>2</sub>H<sub>4</sub> are analyzed. It is found that CuO, Ag<sub>2</sub>O, and Cu<sub>2</sub>O stably composite onto the surface of ZnO by forming heterojunctions, which helps to improve the gas sensing and selectivity of the sensor. The adsorption results show that CuO-ZnO shows physical adsorption for H<sub>2</sub> and good gas sensing performance for CO and C<sub>2</sub>H<sub>4</sub>, while Ag<sub>2</sub>O-ZnO and Cu<sub>2</sub>O-ZnO have significant responses for H<sub>2</sub>, CO, and C<sub>2</sub>H<sub>4</sub>. In addition, the introduction of the TMO-ZnO heterojunction structure can effectively avoid the sensor poisoning phenomenon, as the gas adsorption process does not destroy the original geometric configuration of the heterojunction. This study lays a theoretical foundation for preparing TMO-ZnO heterojunction-based sensors for transformer defect detection and energy efficiency analysis.
ISSN:2079-4991