Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock

Hydrogen production is essential in the transition to sustainable energy. This study examines two hydrogen production routes, steam methane reforming (SMR) and chemical looping reforming (CLR), both using raw natural gas as feedstock. SMR, the most commonly used industrial process, involves reacting...

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Main Authors: Salmi Mohd Yunus, Suzana Yusup, Siti Sorfina Johari, Nurfanizan Mohd Afandi, Abreeza Manap, Hassan Mohamed
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Hydrogen
Subjects:
Online Access:https://www.mdpi.com/2673-4141/5/4/40
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author Salmi Mohd Yunus
Suzana Yusup
Siti Sorfina Johari
Nurfanizan Mohd Afandi
Abreeza Manap
Hassan Mohamed
author_facet Salmi Mohd Yunus
Suzana Yusup
Siti Sorfina Johari
Nurfanizan Mohd Afandi
Abreeza Manap
Hassan Mohamed
author_sort Salmi Mohd Yunus
collection DOAJ
description Hydrogen production is essential in the transition to sustainable energy. This study examines two hydrogen production routes, steam methane reforming (SMR) and chemical looping reforming (CLR), both using raw natural gas as feedstock. SMR, the most commonly used industrial process, involves reacting methane with steam to produce hydrogen, carbon monoxide, and carbon dioxide. In contrast, CLR uses a metal oxide as an oxygen carrier to facilitate hydrogen production without generating additional carbon dioxide. Simulations conducted using Aspen HYSYS analyzed each method’s performance and energy consumption. The results show that SMR achieved 99.98% hydrogen purity, whereas CLR produced 99.97% purity. An energy analysis revealed that CLR requires 31% less energy than SMR, likely due to the absence of low- and high-temperature water–gas shift units. Overall, the findings suggest that CLR offers substantial advantages over SMR, including lower energy consumption and the production of cleaner hydrogen, free from carbon dioxide generated during the water–gas shift process.
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issn 2673-4141
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publishDate 2024-10-01
publisher MDPI AG
record_format Article
series Hydrogen
spelling doaj-art-56441e1aa2b049769f40e9875254c6942025-08-20T02:53:41ZengMDPI AGHydrogen2673-41412024-10-015476177510.3390/hydrogen5040040Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as FeedstockSalmi Mohd Yunus0Suzana Yusup1Siti Sorfina Johari2Nurfanizan Mohd Afandi3Abreeza Manap4Hassan Mohamed5Materials Engineering and Testing Group, TNB Research Sdn Bhd, Kawasan Institusi Penyelidikan, No. 1 Lorong Ayer Itam, Kajang 43000, Selangor, MalaysiaGeneration Unit, TNB Research Sdn Bhd, Kawasan Institusi Penyelidikan, No. 1 Lorong Ayer Itam, Kajang 43000, Selangor, MalaysiaMaterials Engineering and Testing Group, TNB Research Sdn Bhd, Kawasan Institusi Penyelidikan, No. 1 Lorong Ayer Itam, Kajang 43000, Selangor, MalaysiaDepartment of Mechanical Engineering, College of Engineering, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Selangor, MalaysiaDepartment of Mechanical Engineering, College of Engineering, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Selangor, MalaysiaDepartment of Mechanical Engineering, College of Engineering, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Selangor, MalaysiaHydrogen production is essential in the transition to sustainable energy. This study examines two hydrogen production routes, steam methane reforming (SMR) and chemical looping reforming (CLR), both using raw natural gas as feedstock. SMR, the most commonly used industrial process, involves reacting methane with steam to produce hydrogen, carbon monoxide, and carbon dioxide. In contrast, CLR uses a metal oxide as an oxygen carrier to facilitate hydrogen production without generating additional carbon dioxide. Simulations conducted using Aspen HYSYS analyzed each method’s performance and energy consumption. The results show that SMR achieved 99.98% hydrogen purity, whereas CLR produced 99.97% purity. An energy analysis revealed that CLR requires 31% less energy than SMR, likely due to the absence of low- and high-temperature water–gas shift units. Overall, the findings suggest that CLR offers substantial advantages over SMR, including lower energy consumption and the production of cleaner hydrogen, free from carbon dioxide generated during the water–gas shift process.https://www.mdpi.com/2673-4141/5/4/40steam methane reformingchemical looping reforminghydrogen productionfeedstock purificationnatural gas
spellingShingle Salmi Mohd Yunus
Suzana Yusup
Siti Sorfina Johari
Nurfanizan Mohd Afandi
Abreeza Manap
Hassan Mohamed
Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock
Hydrogen
steam methane reforming
chemical looping reforming
hydrogen production
feedstock purification
natural gas
title Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock
title_full Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock
title_fullStr Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock
title_full_unstemmed Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock
title_short Comparative Hydrogen Production Routes via Steam Methane Reforming and Chemical Looping Reforming of Natural Gas as Feedstock
title_sort comparative hydrogen production routes via steam methane reforming and chemical looping reforming of natural gas as feedstock
topic steam methane reforming
chemical looping reforming
hydrogen production
feedstock purification
natural gas
url https://www.mdpi.com/2673-4141/5/4/40
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