CHARACTERIZATION OF HIGH-SILICA MORDENITE OBTAINED BY DIRECT SYNTHESIS

Three high-silica mordenite zeolites differing in SiO440, ratio were prepared by direct synthesis without using any template. The products Si02/A120, ratio is influenced by the starting gel composition. This ratio is increased upon ion-exchange with NH,Cl and subsequent calcination to prepare proton...

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Bibliographic Details
Format: Article
Language:English
Published: University of Tehran 1998-06-01
Series:Journal of Sciences, Islamic Republic of Iran
Online Access:https://jsciences.ut.ac.ir/article_31468_b52852e42743d9b7f886653d167fdaeb.pdf
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Summary:Three high-silica mordenite zeolites differing in SiO440, ratio were prepared by direct synthesis without using any template. The products Si02/A120, ratio is influenced by the starting gel composition. This ratio is increased upon ion-exchange with NH,Cl and subsequent calcination to prepare protonic mordenite. The protonic mordenites with Si02/A1203ra tios of 14.6,29.2 and 34.6 were characterized by X-ray diffraction, energy dispersive X-ray microprobe analysis, scanning electron microscopy and thermogravimetric analysis. Catalytic cracking of n-hexane was studied as a measure of catalytic activity of protonic mordenites. Catalytic activities are expressed as conversion percent of n-hexane. Catalysts with higher Si02/A1,03 were found to be more active
ISSN:1016-1104
2345-6914