Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current

The hydrophilic surface of fumed nanosilica was modified to a hydrophobic surface by treating it with a trimethyl silane coupling agent, and epoxy nanocomposites were prepared by mixing the modified nanosilica (0 phr, 1 phr, 3 phr, 5 phr, and 7 phr) in an epoxy matrix, where the unit phr means the p...

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Main Author: Jae-Jun Park
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2021/6671681
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author Jae-Jun Park
author_facet Jae-Jun Park
author_sort Jae-Jun Park
collection DOAJ
description The hydrophilic surface of fumed nanosilica was modified to a hydrophobic surface by treating it with a trimethyl silane coupling agent, and epoxy nanocomposites were prepared by mixing the modified nanosilica (0 phr, 1 phr, 3 phr, 5 phr, and 7 phr) in an epoxy matrix, where the unit phr means the parts per one hundred grams of epoxy base resin. To apply the nanocomposites to heavy electrical equipment, the effects of the modified nanosilica on the long-term treeing phenomena and the partial discharge (PD) resistance were studied under high voltage alternating current (HVAC) conditions. The bonding of trimethyl silane on the nanosilica surface was confirmed by the appearance of new peaks for the CH2 and CH3 groups in Fourier-transform infrared spectroscopy analysis. To observe the even dispersion of the modified nanosilica particles in the epoxy matrix, a transmission electron microscope was employed, and it was found that 1 phr of the modified nanosilica was uniformly dispersed; however, as the nanosilica content was increased, its aggregation became somewhat severe. The longest HVAC treeing breakdown time was found in an epoxy nanocomposite with 1 phr of alkyl-modified nanosilica, and the time was 17,412 min, which was 143.9 times longer than the 121 min required for a neat epoxy system. In a nanocomposite with 5 phr of modified nanosilica, PD resistance was found to be 12.5 times higher than that of the neat epoxy system.
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spelling doaj-art-55dbc44e82cd4b75869a669d6c21ea082025-08-20T02:04:55ZengWileyInternational Journal of Polymer Science1687-94221687-94302021-01-01202110.1155/2021/66716816671681Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating CurrentJae-Jun Park0Department of Electrical and Electronic Engineering, Joongbu University, 305 Dongheon-ro, Deogyang-gu, Goyang-si, Gyeonggi-do 10279, Republic of KoreaThe hydrophilic surface of fumed nanosilica was modified to a hydrophobic surface by treating it with a trimethyl silane coupling agent, and epoxy nanocomposites were prepared by mixing the modified nanosilica (0 phr, 1 phr, 3 phr, 5 phr, and 7 phr) in an epoxy matrix, where the unit phr means the parts per one hundred grams of epoxy base resin. To apply the nanocomposites to heavy electrical equipment, the effects of the modified nanosilica on the long-term treeing phenomena and the partial discharge (PD) resistance were studied under high voltage alternating current (HVAC) conditions. The bonding of trimethyl silane on the nanosilica surface was confirmed by the appearance of new peaks for the CH2 and CH3 groups in Fourier-transform infrared spectroscopy analysis. To observe the even dispersion of the modified nanosilica particles in the epoxy matrix, a transmission electron microscope was employed, and it was found that 1 phr of the modified nanosilica was uniformly dispersed; however, as the nanosilica content was increased, its aggregation became somewhat severe. The longest HVAC treeing breakdown time was found in an epoxy nanocomposite with 1 phr of alkyl-modified nanosilica, and the time was 17,412 min, which was 143.9 times longer than the 121 min required for a neat epoxy system. In a nanocomposite with 5 phr of modified nanosilica, PD resistance was found to be 12.5 times higher than that of the neat epoxy system.http://dx.doi.org/10.1155/2021/6671681
spellingShingle Jae-Jun Park
Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current
International Journal of Polymer Science
title Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current
title_full Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current
title_fullStr Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current
title_full_unstemmed Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current
title_short Electrical Treeing and Partial Discharge Characteristics of Epoxy/Silica Nanocomposite under Alternating Current
title_sort electrical treeing and partial discharge characteristics of epoxy silica nanocomposite under alternating current
url http://dx.doi.org/10.1155/2021/6671681
work_keys_str_mv AT jaejunpark electricaltreeingandpartialdischargecharacteristicsofepoxysilicananocompositeunderalternatingcurrent