Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts

Waste plastics pose significant environmental risks due to their non-biodegradable nature and accumulation in the environment. The pandemic has exacerbated this issue by increasing the production of plastic medical waste such as surgical masks. This study developed Ni/Al-MOF-derived catalysts for py...

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Main Authors: Wenfei Cai, Reeti Kumar, Zhi Zhu, Sunita Varjani, Zhong-Ting Hu, Jonathan Woon-Chung Wong, Jun Zhao
Format: Article
Language:English
Published: Elsevier 2024-01-01
Series:Next Sustainability
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949823624000369
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author Wenfei Cai
Reeti Kumar
Zhi Zhu
Sunita Varjani
Zhong-Ting Hu
Jonathan Woon-Chung Wong
Jun Zhao
author_facet Wenfei Cai
Reeti Kumar
Zhi Zhu
Sunita Varjani
Zhong-Ting Hu
Jonathan Woon-Chung Wong
Jun Zhao
author_sort Wenfei Cai
collection DOAJ
description Waste plastics pose significant environmental risks due to their non-biodegradable nature and accumulation in the environment. The pandemic has exacerbated this issue by increasing the production of plastic medical waste such as surgical masks. This study developed Ni/Al-MOF-derived catalysts for pyrolysis, an effective plastic waste utilization technology. By optimizing conditions, the study successfully converted waste surgical masks, made primarily of polypropylene, into gasoline or diesel range chemicals. The oil yield from polypropylene waste reached 72.8 % using Ni/Al-MOF-derived catalysts with 5 % Ni loading at 450°C, while surgical masks yielded 58.9 % oil under the same conditions. Catalyst characterization revealed a high surface area and evenly distributed Ni particles in MOF-derived Al2O3, maximizing catalytic performance. This catalyst provides a promising solution for converting waste surgical masks into liquid fuels, reducing the environmental impact of plastic products, and promoting plastic waste recycling.
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series Next Sustainability
spelling doaj-art-557da08fa790405eabfa3a54568b57fb2025-08-20T02:38:38ZengElsevierNext Sustainability2949-82362024-01-01410005910.1016/j.nxsust.2024.100059Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalystsWenfei Cai0Reeti Kumar1Zhi Zhu2Sunita Varjani3Zhong-Ting Hu4Jonathan Woon-Chung Wong5Jun Zhao6Department of Biology, Hong Kong Baptist University, Hong Kong Special Administrative RegionDepartment of Biology, Hong Kong Baptist University, Hong Kong Special Administrative RegionDepartment of Biology, Hong Kong Baptist University, Hong Kong Special Administrative RegionSchool of Energy and Environment, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong Special Administrative RegionCollege of Environment, Zhejiang University of Technology, Hangzhou 310014, ChinaDepartment of Biology, Hong Kong Baptist University, Hong Kong Special Administrative RegionDepartment of Biology, Hong Kong Baptist University, Hong Kong Special Administrative Region; Institute of Advanced Materials, Hong Kong Baptist University, Kowloon Tong, Hong Kong Special Administrative Region; Corresponding author at: Department of Biology, Hong Kong Baptist University, Hong Kong Special Administrative RegionWaste plastics pose significant environmental risks due to their non-biodegradable nature and accumulation in the environment. The pandemic has exacerbated this issue by increasing the production of plastic medical waste such as surgical masks. This study developed Ni/Al-MOF-derived catalysts for pyrolysis, an effective plastic waste utilization technology. By optimizing conditions, the study successfully converted waste surgical masks, made primarily of polypropylene, into gasoline or diesel range chemicals. The oil yield from polypropylene waste reached 72.8 % using Ni/Al-MOF-derived catalysts with 5 % Ni loading at 450°C, while surgical masks yielded 58.9 % oil under the same conditions. Catalyst characterization revealed a high surface area and evenly distributed Ni particles in MOF-derived Al2O3, maximizing catalytic performance. This catalyst provides a promising solution for converting waste surgical masks into liquid fuels, reducing the environmental impact of plastic products, and promoting plastic waste recycling.http://www.sciencedirect.com/science/article/pii/S2949823624000369Plastic wasteWaste surgical masksRecyclingPyrolysisFuel
spellingShingle Wenfei Cai
Reeti Kumar
Zhi Zhu
Sunita Varjani
Zhong-Ting Hu
Jonathan Woon-Chung Wong
Jun Zhao
Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts
Next Sustainability
Plastic waste
Waste surgical masks
Recycling
Pyrolysis
Fuel
title Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts
title_full Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts
title_fullStr Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts
title_full_unstemmed Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts
title_short Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts
title_sort catalytic pyrolysis of polypropylene waste for liquid fuels production using ni al mof derived catalysts
topic Plastic waste
Waste surgical masks
Recycling
Pyrolysis
Fuel
url http://www.sciencedirect.com/science/article/pii/S2949823624000369
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