Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films

Foamed poly(lactic acid) films reinforced with micro-crystalline cellulose (MCC), were uniaxially stretched to different ratios. At 10% (weight) loading MCC particles gave an approximately 3.5 times improvement in stiffness over unreinforced foams. X-ray tomography and image analysis showed that mos...

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Main Authors: S. Hussain, A. R. Dickson
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2019-01-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0009316&mi=cd
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author S. Hussain
A. R. Dickson
author_facet S. Hussain
A. R. Dickson
author_sort S. Hussain
collection DOAJ
description Foamed poly(lactic acid) films reinforced with micro-crystalline cellulose (MCC), were uniaxially stretched to different ratios. At 10% (weight) loading MCC particles gave an approximately 3.5 times improvement in stiffness over unreinforced foams. X-ray tomography and image analysis showed that most MCC particles had low aspect ratios, were randomly oriented and well distributed. Stretching did not change the orientation of the MCC particles. Increases in stiffness with stretching were due to the alignment of the foam cell walls. Electron microscopy and image analysis showed that the foam cells were elongated and the walls aligned in the stretch direction. There was a good fit between measured stiffness and micro-mechanical modelling based on a variation of the Mori-Tanaka model for reinforcing particles randomly oriented in 3 dimensions.
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publisher Budapest University of Technology and Economics
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series eXPRESS Polymer Letters
spelling doaj-art-54e0439b0a8b4492bcde58e005af14a12025-08-20T03:58:25ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2019-01-01131182610.3144/expresspolymlett.2019.3Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) filmsS. HussainA. R. DicksonFoamed poly(lactic acid) films reinforced with micro-crystalline cellulose (MCC), were uniaxially stretched to different ratios. At 10% (weight) loading MCC particles gave an approximately 3.5 times improvement in stiffness over unreinforced foams. X-ray tomography and image analysis showed that most MCC particles had low aspect ratios, were randomly oriented and well distributed. Stretching did not change the orientation of the MCC particles. Increases in stiffness with stretching were due to the alignment of the foam cell walls. Electron microscopy and image analysis showed that the foam cells were elongated and the walls aligned in the stretch direction. There was a good fit between measured stiffness and micro-mechanical modelling based on a variation of the Mori-Tanaka model for reinforcing particles randomly oriented in 3 dimensions.http://www.expresspolymlett.com/letolt.php?file=EPL-0009316&mi=cdMechanical propertiesPLA foamX-ray tomographyReinforcementsModelling and simulation
spellingShingle S. Hussain
A. R. Dickson
Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films
eXPRESS Polymer Letters
Mechanical properties
PLA foam
X-ray tomography
Reinforcements
Modelling and simulation
title Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films
title_full Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films
title_fullStr Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films
title_full_unstemmed Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films
title_short Improving and predicting the mechanical properties of foamed and stretched composite poly(lactic acid) films
title_sort improving and predicting the mechanical properties of foamed and stretched composite poly lactic acid films
topic Mechanical properties
PLA foam
X-ray tomography
Reinforcements
Modelling and simulation
url http://www.expresspolymlett.com/letolt.php?file=EPL-0009316&mi=cd
work_keys_str_mv AT shussain improvingandpredictingthemechanicalpropertiesoffoamedandstretchedcompositepolylacticacidfilms
AT ardickson improvingandpredictingthemechanicalpropertiesoffoamedandstretchedcompositepolylacticacidfilms