Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
The aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N a...
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Format: | Article |
Language: | English |
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Wiley
2013-01-01
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Series: | International Journal of Photoenergy |
Online Access: | http://dx.doi.org/10.1155/2013/625024 |
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author | Hongchao Ma Xiaohong Cheng Chun Ma Xiaoli Dong Xinxin Zhang Mang Xue Xiufang Zhang Yinghuan Fu |
author_facet | Hongchao Ma Xiaohong Cheng Chun Ma Xiaoli Dong Xinxin Zhang Mang Xue Xiufang Zhang Yinghuan Fu |
author_sort | Hongchao Ma |
collection | DOAJ |
description | The aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N and S source in this work. Anthraquinone dye (reactive brilliant blue KNR) is employed as the model contaminants to evaluate the photocatalytic activity of as-synthesized samples under sunlight illumination. The N-doped ZnO/ZnS synthesized by this method shows better photocatalytic activity as compared to that of pure ZnO. The enhanced photocatalytic activity of the N-doped ZnO/ZnS composites may be related to the existence of N doping, ZnS/ZnO heterostructure, and covered abundant carbon species on the photocatalyst surface, which causing high absorption efficiency of light, efficient separation of electron-hole pairs, and quick surface reaction in doped ZnO. |
format | Article |
id | doaj-art-54d004b7858a407fb00e78fe7b4df4b2 |
institution | Kabale University |
issn | 1110-662X 1687-529X |
language | English |
publishDate | 2013-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Photoenergy |
spelling | doaj-art-54d004b7858a407fb00e78fe7b4df4b22025-02-03T01:11:26ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/625024625024Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS CompositesHongchao Ma0Xiaohong Cheng1Chun Ma2Xiaoli Dong3Xinxin Zhang4Mang Xue5Xiufang Zhang6Yinghuan Fu7School of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaThe aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N and S source in this work. Anthraquinone dye (reactive brilliant blue KNR) is employed as the model contaminants to evaluate the photocatalytic activity of as-synthesized samples under sunlight illumination. The N-doped ZnO/ZnS synthesized by this method shows better photocatalytic activity as compared to that of pure ZnO. The enhanced photocatalytic activity of the N-doped ZnO/ZnS composites may be related to the existence of N doping, ZnS/ZnO heterostructure, and covered abundant carbon species on the photocatalyst surface, which causing high absorption efficiency of light, efficient separation of electron-hole pairs, and quick surface reaction in doped ZnO.http://dx.doi.org/10.1155/2013/625024 |
spellingShingle | Hongchao Ma Xiaohong Cheng Chun Ma Xiaoli Dong Xinxin Zhang Mang Xue Xiufang Zhang Yinghuan Fu Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites International Journal of Photoenergy |
title | Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites |
title_full | Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites |
title_fullStr | Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites |
title_full_unstemmed | Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites |
title_short | Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites |
title_sort | synthesis characterization and photocatalytic activity of n doped zno zns composites |
url | http://dx.doi.org/10.1155/2013/625024 |
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