Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites

The aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N a...

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Main Authors: Hongchao Ma, Xiaohong Cheng, Chun Ma, Xiaoli Dong, Xinxin Zhang, Mang Xue, Xiufang Zhang, Yinghuan Fu
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/625024
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author Hongchao Ma
Xiaohong Cheng
Chun Ma
Xiaoli Dong
Xinxin Zhang
Mang Xue
Xiufang Zhang
Yinghuan Fu
author_facet Hongchao Ma
Xiaohong Cheng
Chun Ma
Xiaoli Dong
Xinxin Zhang
Mang Xue
Xiufang Zhang
Yinghuan Fu
author_sort Hongchao Ma
collection DOAJ
description The aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N and S source in this work. Anthraquinone dye (reactive brilliant blue KNR) is employed as the model contaminants to evaluate the photocatalytic activity of as-synthesized samples under sunlight illumination. The N-doped ZnO/ZnS synthesized by this method shows better photocatalytic activity as compared to that of pure ZnO. The enhanced photocatalytic activity of the N-doped ZnO/ZnS composites may be related to the existence of N doping, ZnS/ZnO heterostructure, and covered abundant carbon species on the photocatalyst surface, which causing high absorption efficiency of light, efficient separation of electron-hole pairs, and quick surface reaction in doped ZnO.
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institution Kabale University
issn 1110-662X
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publishDate 2013-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-54d004b7858a407fb00e78fe7b4df4b22025-02-03T01:11:26ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/625024625024Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS CompositesHongchao Ma0Xiaohong Cheng1Chun Ma2Xiaoli Dong3Xinxin Zhang4Mang Xue5Xiufang Zhang6Yinghuan Fu7School of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaSchool of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian, Liaoning 116034, ChinaThe aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N and S source in this work. Anthraquinone dye (reactive brilliant blue KNR) is employed as the model contaminants to evaluate the photocatalytic activity of as-synthesized samples under sunlight illumination. The N-doped ZnO/ZnS synthesized by this method shows better photocatalytic activity as compared to that of pure ZnO. The enhanced photocatalytic activity of the N-doped ZnO/ZnS composites may be related to the existence of N doping, ZnS/ZnO heterostructure, and covered abundant carbon species on the photocatalyst surface, which causing high absorption efficiency of light, efficient separation of electron-hole pairs, and quick surface reaction in doped ZnO.http://dx.doi.org/10.1155/2013/625024
spellingShingle Hongchao Ma
Xiaohong Cheng
Chun Ma
Xiaoli Dong
Xinxin Zhang
Mang Xue
Xiufang Zhang
Yinghuan Fu
Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
International Journal of Photoenergy
title Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
title_full Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
title_fullStr Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
title_full_unstemmed Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
title_short Synthesis, Characterization, and Photocatalytic Activity of N-Doped ZnO/ZnS Composites
title_sort synthesis characterization and photocatalytic activity of n doped zno zns composites
url http://dx.doi.org/10.1155/2013/625024
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