Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2
In this study, we developed nano accelerators with a broad range by utilizing the interaction between tetraethyl orthosilicate (TEOS) and tripolyphosphate (TPP), followed by attaching poly(ionic liquids) to the click-modified ligand of fibrous phosphosilicate (FPS). This process led to the uniform d...
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| Format: | Article |
| Language: | English |
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Elsevier
2024-12-01
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| Series: | Journal of CO2 Utilization |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2212982024003135 |
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| author | Naser Monavari Rahele Zhiani Malihesadat Hosseiny Susan Khosroyar Zohreh Ebrahimi Mina Moradi |
| author_facet | Naser Monavari Rahele Zhiani Malihesadat Hosseiny Susan Khosroyar Zohreh Ebrahimi Mina Moradi |
| author_sort | Naser Monavari |
| collection | DOAJ |
| description | In this study, we developed nano accelerators with a broad range by utilizing the interaction between tetraethyl orthosilicate (TEOS) and tripolyphosphate (TPP), followed by attaching poly(ionic liquids) to the click-modified ligand of fibrous phosphosilicate (FPS). This process led to the uniform distribution of poly(ionic liquids) without any aggregation, forming PILs-FPS. This material was then applied as a green catalyst for producing cyclic carbonate from limonene epoxide and CO2 under eco-friendly conditions. Subsequently, we synthesized a polymer from the natural cyclic carbonate obtained. The reaction between CO2 and highly substituted epoxides from sustainable sources like waste limonene produced novel bio-based cyclic carbonates. The reaction took place under mild, solvent-free conditions using PILs-FPS as the catalyst. The fibrous FPS structures enhanced adsorption capacity and facilitated the recovery of the catalyst without significant loss of activity. The products were easily separated from the environmentally conscious setting, and the catalyst was reused multiple times without a notable decrease in performance or selectivity. |
| format | Article |
| id | doaj-art-54cd88f24f5f4bce841b3eab590dc7e1 |
| institution | OA Journals |
| issn | 2212-9839 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of CO2 Utilization |
| spelling | doaj-art-54cd88f24f5f4bce841b3eab590dc7e12025-08-20T02:37:24ZengElsevierJournal of CO2 Utilization2212-98392024-12-019010297810.1016/j.jcou.2024.102978Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2Naser Monavari0Rahele Zhiani1Malihesadat Hosseiny2Susan Khosroyar3Zohreh Ebrahimi4Mina Moradi5Department of Chemical Engineering, Neyshabur Branch, Islamic Azad University, Neyshabur, IranDepartment of chemistry, Neyshabur Branch, Islamic Azad University, Iran; Advanced Research Center for Chemistry, Biochemistry and Nanomaterial, Neyshabur Branch, Islamic Azad University, Iran; New materials Technology and Processing Reserearch Center, Neyshabur Branch, Islamic Azad University, Iran; Corresponding author at: Department of chemistry, Neyshabur Branch, Islamic Azad University, Iran.Department of chemistry, Neyshabur Branch, Islamic Azad University, Iran; Advanced Research Center for Chemistry, Biochemistry and Nanomaterial, Neyshabur Branch, Islamic Azad University, IranDepartment of Chemical Engineering, Quchan Branch, Islamic Azad University, Quchan, IranDepartment of chemistry, Neyshabur Branch, Islamic Azad University, Iran; Advanced Research Center for Chemistry, Biochemistry and Nanomaterial, Neyshabur Branch, Islamic Azad University, IranDepartment of chemistry, Neyshabur Branch, Islamic Azad University, IranIn this study, we developed nano accelerators with a broad range by utilizing the interaction between tetraethyl orthosilicate (TEOS) and tripolyphosphate (TPP), followed by attaching poly(ionic liquids) to the click-modified ligand of fibrous phosphosilicate (FPS). This process led to the uniform distribution of poly(ionic liquids) without any aggregation, forming PILs-FPS. This material was then applied as a green catalyst for producing cyclic carbonate from limonene epoxide and CO2 under eco-friendly conditions. Subsequently, we synthesized a polymer from the natural cyclic carbonate obtained. The reaction between CO2 and highly substituted epoxides from sustainable sources like waste limonene produced novel bio-based cyclic carbonates. The reaction took place under mild, solvent-free conditions using PILs-FPS as the catalyst. The fibrous FPS structures enhanced adsorption capacity and facilitated the recovery of the catalyst without significant loss of activity. The products were easily separated from the environmentally conscious setting, and the catalyst was reused multiple times without a notable decrease in performance or selectivity.http://www.sciencedirect.com/science/article/pii/S2212982024003135NanoacceleratorGreen chemistryIonic liquidCyclic carbonateLimonene epoxide |
| spellingShingle | Naser Monavari Rahele Zhiani Malihesadat Hosseiny Susan Khosroyar Zohreh Ebrahimi Mina Moradi Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2 Journal of CO2 Utilization Nanoaccelerator Green chemistry Ionic liquid Cyclic carbonate Limonene epoxide |
| title | Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2 |
| title_full | Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2 |
| title_fullStr | Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2 |
| title_full_unstemmed | Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2 |
| title_short | Fibrous phosphosilicate with highly dispersed poly(ionic liquids) as a nanocatalyst for production of biopolymer from limonene epoxide and CO2 |
| title_sort | fibrous phosphosilicate with highly dispersed poly ionic liquids as a nanocatalyst for production of biopolymer from limonene epoxide and co2 |
| topic | Nanoaccelerator Green chemistry Ionic liquid Cyclic carbonate Limonene epoxide |
| url | http://www.sciencedirect.com/science/article/pii/S2212982024003135 |
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