Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique

Zinc oxide (ZnO) exhibits piezoelectric properties due to its asymmetric structure, making it suitable for piezoelectric devices. This experiment deposited Fe-doped ZnO films on silicon substrates using a dual-target magnetron co-sputtering system. The films achieved a high c-axis orientation, and t...

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Main Authors: Ya-Chih Cheng, Sanjaya Brahma, Sean Wu, Jow-Lay Huang, Alex C. H. Lee
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Condensed Matter
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Online Access:https://www.mdpi.com/2410-3896/10/1/6
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author Ya-Chih Cheng
Sanjaya Brahma
Sean Wu
Jow-Lay Huang
Alex C. H. Lee
author_facet Ya-Chih Cheng
Sanjaya Brahma
Sean Wu
Jow-Lay Huang
Alex C. H. Lee
author_sort Ya-Chih Cheng
collection DOAJ
description Zinc oxide (ZnO) exhibits piezoelectric properties due to its asymmetric structure, making it suitable for piezoelectric devices. This experiment deposited Fe-doped ZnO films on silicon substrates using a dual-target magnetron co-sputtering system. The films achieved a high c-axis orientation, and the piezoelectric coefficient of the film reached its optimal value of 44.35 pC/N when doped with 0.5 at% of Fe. This value is approximately three times that of undoped ZnO films with a piezoelectric coefficient of 13.04 pC/N. The study utilized a diffractometer, scanning electron microscopy, transmission electron microscopy, and atomic force microscopy to evaluate the crystal structure evolution of the zinc oxide films and employed X-ray photoelectron spectroscopy to assess the valence state of the Fe ions.
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publishDate 2025-01-01
publisher MDPI AG
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series Condensed Matter
spelling doaj-art-5447dc0986664a60adfa690eaa58fa482025-08-20T02:11:18ZengMDPI AGCondensed Matter2410-38962025-01-01101610.3390/condmat10010006Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering TechniqueYa-Chih Cheng0Sanjaya Brahma1Sean Wu2Jow-Lay Huang3Alex C. H. Lee4Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Semiconductor Engineering, Lunghwa University of Science and Technology, Taoyuan 333326, TaiwanDepartment of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Mechanical Engineering, National Chin-Yi University of Technology, Taichung 411030, TaiwanZinc oxide (ZnO) exhibits piezoelectric properties due to its asymmetric structure, making it suitable for piezoelectric devices. This experiment deposited Fe-doped ZnO films on silicon substrates using a dual-target magnetron co-sputtering system. The films achieved a high c-axis orientation, and the piezoelectric coefficient of the film reached its optimal value of 44.35 pC/N when doped with 0.5 at% of Fe. This value is approximately three times that of undoped ZnO films with a piezoelectric coefficient of 13.04 pC/N. The study utilized a diffractometer, scanning electron microscopy, transmission electron microscopy, and atomic force microscopy to evaluate the crystal structure evolution of the zinc oxide films and employed X-ray photoelectron spectroscopy to assess the valence state of the Fe ions.https://www.mdpi.com/2410-3896/10/1/6ZnOFe dopantpiezoelectric filmcrystal structure
spellingShingle Ya-Chih Cheng
Sanjaya Brahma
Sean Wu
Jow-Lay Huang
Alex C. H. Lee
Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique
Condensed Matter
ZnO
Fe dopant
piezoelectric film
crystal structure
title Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique
title_full Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique
title_fullStr Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique
title_full_unstemmed Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique
title_short Crystal Structure Evolution of Piezoelectric Fe-Doped ZnO Film by Magnetron Co-Sputtering Technique
title_sort crystal structure evolution of piezoelectric fe doped zno film by magnetron co sputtering technique
topic ZnO
Fe dopant
piezoelectric film
crystal structure
url https://www.mdpi.com/2410-3896/10/1/6
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AT seanwu crystalstructureevolutionofpiezoelectricfedopedznofilmbymagnetroncosputteringtechnique
AT jowlayhuang crystalstructureevolutionofpiezoelectricfedopedznofilmbymagnetroncosputteringtechnique
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