Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline

In this research, salbutamol sulphate (SAS) has been determined by a simple, rapid and sensitive spectrophotometric method. Salbutamol sulphate in this method is based on the coupling of SAS with diazotized ρ- bromoaniline reagent in alkaline medium of Triton X-100 (Tx) to form an orange azo dye whi...

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Main Author: Tamathir et al.
Format: Article
Language:English
Published: University of Baghdad, College of Science for Women 2019-09-01
Series:مجلة بغداد للعلوم
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Online Access:http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/3941
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author Tamathir et al.
author_facet Tamathir et al.
author_sort Tamathir et al.
collection DOAJ
description In this research, salbutamol sulphate (SAS) has been determined by a simple, rapid and sensitive spectrophotometric method. Salbutamol sulphate in this method is based on the coupling of SAS with diazotized ρ- bromoaniline reagent in alkaline medium of Triton X-100 (Tx) to form an orange azo dye which is stable and water-soluble. The azo dye is exhibiting maximum absorption at 441 nm. A 10 - 800 µg of SAS is obeyed of Beer's law in a final volume of 20 ml, i.e., 0.5- 40 ppm with ε, the molar absorptivity of 48558 L.mol-1.cm-1 and Sandell's sensitivity index of 0.01188 µg.cm-2. This new method does not need solvent extraction or temperature control which is well applied to determine SAS in different types of pharmaceutical preparations.
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publisher University of Baghdad, College of Science for Women
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series مجلة بغداد للعلوم
spelling doaj-art-53f97d47fac34ff1b9ad266e3f9f898d2025-08-20T03:56:19ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862019-09-0116310.21123/bsj.16.3.610Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoanilineTamathir et al.In this research, salbutamol sulphate (SAS) has been determined by a simple, rapid and sensitive spectrophotometric method. Salbutamol sulphate in this method is based on the coupling of SAS with diazotized ρ- bromoaniline reagent in alkaline medium of Triton X-100 (Tx) to form an orange azo dye which is stable and water-soluble. The azo dye is exhibiting maximum absorption at 441 nm. A 10 - 800 µg of SAS is obeyed of Beer's law in a final volume of 20 ml, i.e., 0.5- 40 ppm with ε, the molar absorptivity of 48558 L.mol-1.cm-1 and Sandell's sensitivity index of 0.01188 µg.cm-2. This new method does not need solvent extraction or temperature control which is well applied to determine SAS in different types of pharmaceutical preparations.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/3941Azo dye, diazotization coupling reaction, pharmaceuticals determination, spectrophotometric method, Triton X-100.
spellingShingle Tamathir et al.
Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline
مجلة بغداد للعلوم
Azo dye, diazotization coupling reaction, pharmaceuticals determination, spectrophotometric method, Triton X-100.
title Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline
title_full Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline
title_fullStr Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline
title_full_unstemmed Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline
title_short Spectrophotometric Assay of Salbutamol Sulphate in Pharmaceutical Preparations by Coupling with Diazotized ρ-bromoaniline
title_sort spectrophotometric assay of salbutamol sulphate in pharmaceutical preparations by coupling with diazotized ρ bromoaniline
topic Azo dye, diazotization coupling reaction, pharmaceuticals determination, spectrophotometric method, Triton X-100.
url http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/3941
work_keys_str_mv AT tamathiretal spectrophotometricassayofsalbutamolsulphateinpharmaceuticalpreparationsbycouplingwithdiazotizedrbromoaniline